File name: Pandora114s1_BuenosAires_20180516_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T033158.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v3d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180516_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180516 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180516T104701.0Z 6710.449317 474 1 32.00 2 89.76 66.35 100.89 75.59 0.00 1 0.00 1 0 15 1.992e-01 1.694e-01 1.583e-01 1.473e-01 3.809647e+03 9.435695e+03 6.808096e+01 -6.000000e+00 1.095362e+04 284.63 -2.00 20.00 -2.00 505.32 0.00e+00 6.998743e-03 4.017595e-03 3.800208e-04 -6.000000e+00 5.543765e-03 284.63 -2.00 20.00 -2.00 500.36 0.00e+00 1.588033e+00 2.953669e+00 8.785269e-02 -6.000000e+00 3.881086e+00 224.68 -2.00 3.16 -2.00 501.97 0.00e+00 20.111 0.076 489.00 513.00 1 9.9340e+00 2.2635e-01 3.2776e-02 -6.0000e+00 2.9759e-01 8.9059e-02 5.8105e-02 2.0872e-03 -6.0000e+00 7.7587e-02 4.1449e-06 -7.8543e-03 1.4404e-02 1.4102e-04 -6.0000e+00 1.9588e-02 1.8888e-01 -1.0487e-03 12 9 8 11 8 0 94.20 21.01 13.27 0.18888 0.13440 8 2 1 4 0 4000.000 25.17 20.23 21.01 1873 -280 16447 16286 36561 -24939 9889 -18191 12284 242 6198 50770 -15128 20518 -5656 17427 -1552 20734 4713 7047 12472 -25926 4705 -14725 -459 6655 -6003 34658 -23490 14570 1427 -8020 39898 -23432 8116 -9671 3513 4560 8324 19092 -4595 32822 -5970 28445 -6933 15912 4889 -1649 34820 -8664 28386 9167 -6360 -13316 1172 19466 1440 11387 -13953 4379 -27081 -1563 17559 -13966 34759 -10722 27038 51214 9156 2156 7624 41763 -9462 13795 -1665 -3287 -5903 -8067 19434 -13848 20767 -8757 6617 180 -28771 14596 -14620 33316 -22216 21742 13564 -3004 31095 -351 35611 -14121 38015 -11859 12792 8251 -13951 -8077 -4396 42441 21740 4139 -9116 -1588 16501 -10732 52969 -10732 20363 -9324 10727 28339 -11140 37460 -11120 -152 1401 36296 13680 -21430 21868 -9232 7365 -9346 -22401 56644 -19376 33436 -8029 31297 -13609 17810 29571 -10429 -3144 -1215 5921 4543 5517 -1705 -7780 16331 -14501 46485 -3712 3932 15935 -13867 -305 1777 -277 14251 14616 27531 -35502 10098 -24770 12291 270 6394 32994 -18726 17567 -6243 15280 -1665 18180 4959 6852 12351 -35195 4711 -18005 -490 6663 -6820 26027 -30984 12765 1387 -8494 26505 -30230 7892 -11453 3653 4654 8094 16543 -5043 24964 -6782 23279 -8211 15167 5225 -1873 27154 -10260 22683 8649 -6858 -15257 1174 16680 1526 11182 -17866 4679 -39631 -1776 16567 -18152 27776 -13420 22907 33529 8991 2242 7414 28548 -10750 12484 -1779 -3608 -6650 -8592 16465 -15124 16995 -9011 5853 171 -36616 12120 -16363 23154 -26870 16877 11386 -2983 22172 -348 25071 -16441 26078 -13166 10853 7150 -14733 -7873 -4087 24900 16090 3773 -9709 -1576 13554 -11431 29642 -11431 16174 -10183 9779 21998 -12971 27049 -13149 -162 1467 26536 12348 -27080 17764 -10249 6980 -10545 -28913 33233 -22879 24747 -8458 23446 -14798 14789 21619 -11390 -3235 -1250 5772 4551 5202 -1739 -8460 14012 -17000 31468 -3879 3741 13130 -15079 -288 SO 20180516T105109.0Z 6710.452188 478 1 32.00 2 88.98 65.76 100.11 75.06 0.00 1 0.00 1 0 36 1.096e-01 1.041e-01 1.054e-01 1.027e-01 5.951093e+03 6.903442e+03 5.784087e+01 -6.000000e+00 6.031101e+03 284.63 -2.00 20.00 -2.00 505.42 0.00e+00 -1.167373e-03 2.859993e-03 1.275686e-04 -6.000000e+00 3.049138e-03 284.63 -2.00 20.00 -2.00 500.54 0.00e+00 2.640083e+00 1.993824e+00 1.460732e-01 -6.000000e+00 2.121638e+00 224.68 -2.00 3.16 -2.00 502.15 0.00e+00 18.594 0.060 489.00 513.00 1 9.8357e+00 1.5280e-01 3.0195e-02 -6.0000e+00 1.6290e-01 2.2712e-02 3.8472e-02 2.7257e-03 -6.0000e+00 4.2084e-02 6.0531e-06 1.9753e-03 9.6019e-03 6.7084e-05 -6.0000e+00 1.0739e-02 -6.5967e-02 9.7554e-04 12 9 8 11 8 0 77.84 21.02 1.02 -0.06597 -0.05227 8 2 1 4 0 4000.000 25.17 19.56 21.02 8807 3081 -5929 4039 -5977 37226 -8441 -3135 -15374 -8836 4620 -8087 8358 12437 -69 -9272 7511 6679 -3946 39610 8317 -2637 9568 7295 -3960 -8328 -2445 1692 418 -3492 6698 -1217 -1500 16555 -10466 24438 1043 499 -589 -15947 8247 -20042 12757 -3906 -4940 -6004 1890 -704 6655 -3758 -28 11328 -2361 6274 6611 -12488 12735 759 -4173 10108 -2537 14845 -5412 -5954 8968 22805 -595 6823 -1274 4522 2873 -6815 10001 -3338 15782 2071 10070 7475 -5850 17960 -11662 4392 -9644 -773 19907 -4967 -5455 -18650 15770 4026 -13288 10914 -7662 2631 -20499 5443 -3634 3897 7303 -2096 -2156 662 17686 2083 7142 16172 1353 10898 -2370 8722 -6797 -5635 -2982 9216 -1024 -3531 9724 14669 21975 4202 -6847 20361 -16056 -856 -22769 -6293 5523 -1879 7855 16232 8481 514 20610 -19006 -3541 23169 -5001 -6670 -15490 6391 -6859 3183 5396 -6443 18002 -13889 14674 14078 3772 6697 1331 5373 -9386 7473 2858 -6224 3949 -6619 27302 -9892 -3494 -19235 -10229 4617 -9071 7872 11178 -70 -10534 7398 6819 -4568 29904 8612 -2849 9837 7197 -4385 -9613 -2641 1726 421 -3562 6113 -1217 -1550 14776 -12502 20664 1105 526 -621 -19477 7914 -25690 11900 -4352 -5603 -6890 1992 -751 6475 -3959 -28 9730 -2298 5642 6078 -14331 11623 790 -4565 9564 -2724 13449 -6029 -6673 8606 18824 -611 6410 -1282 4249 2719 -7089 8859 -3427 13557 2043 9055 6772 -5968 14342 -12521 4038 -9647 -715 16164 -4906 -5457 -21355 12799 3673 -14463 9407 -8050 2516 -24633 4966 -3543 3432 6065 -1872 -1899 566 13018 1861 6335 13532 1327 9668 -2371 7737 -7056 -5849 -3058 8466 -1050 -3732 9054 13105 18388 4203 -7582 16910 -18890 -856 -28363 -6692 5246 -1927 7314 13889 7843 514 16727 -22600 -3565 17784 -5129 -7092 -18419 6232 -7768 3304 5534 -7058 16535 -16612 13207 12671 3708 6266 1292 4995 -10226 SO 20180516T105511.0Z 6710.454988 482 1 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