File name: Pandora114s1_BuenosAires_20180524_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T034751.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v3d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180524_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180524 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180524T105249.0Z 6718.453345 455 1 32.00 2 89.77 64.28 145.13 210.24 0.00 1 0.00 1 0 43 1.027e-01 9.662e-02 1.067e-01 1.028e-01 -3.880760e+03 6.091961e+03 1.708677e+02 -6.000000e+00 5.639889e+03 284.22 -2.00 20.00 -2.00 505.19 0.00e+00 1.425447e-03 2.815931e-03 4.416662e-05 -6.000000e+00 2.864003e-03 284.22 -2.00 20.00 -2.00 499.66 0.00e+00 4.889385e+00 2.088590e+00 6.383092e-02 -6.000000e+00 2.020227e+00 224.54 -2.00 3.16 -2.00 501.36 0.00e+00 20.131 0.076 489.00 513.00 1 9.4293e+00 1.6053e-01 3.1170e-02 -6.0000e+00 1.5456e-01 8.9553e-02 4.1430e-02 1.9071e-03 -6.0000e+00 4.0831e-02 6.0593e-06 2.7829e-02 9.8730e-03 3.5609e-05 -6.0000e+00 1.0113e-02 2.0286e-01 -1.8972e-03 12 8 8 10 0 0 -4.86 21.13 26.00 0.20286 0.39589 8 2 1 4 0 4000.000 25.28 19.70 21.13 -42 9638 9911 -5616 20495 14138 631 4042 -4349 2647 -4891 3154 -14175 8986 -3778 3543 -326 -5639 -1983 1370 -22391 -10234 1392 -1637 -293 8444 673 3506 3774 -9691 -3053 16866 7389 7202 6837 -4537 3776 6227 25589 -4957 1869 2050 -11685 -11169 -1795 -7498 5568 -8324 9709 -2623 16275 15403 24166 1637 10498 -16871 5019 63 10245 -7555 3210 -3314 4923 6635 3755 4192 -1469 25235 -11848 -2026 -5143 -903 14199 -18732 14717 -3806 576 -2726 -8106 -2055 1448 -15143 4638 26263 -3836 -1186 575 -1318 6369 -11410 12907 6458 -345 -11333 1726 -4841 17781 2349 819 -18049 4778 12520 24716 203 -3890 21546 14679 7056 17736 -14268 22198 -4209 -7332 -8993 -14312 14469 9371 19931 -7294 1810 21461 -965 -5804 338 -8813 -2466 3975 775 -8654 -8110 -6173 10560 -5062 -9655 -10077 -4135 12518 -8282 9487 2481 14539 9019 -11687 7198 3891 -9875 1077 13111 -2529 6082 564 14195 1527 -44 9508 10063 -6834 19628 14660 754 4656 -5027 3012 -5523 3475 -17148 8576 -4113 3643 -357 -6670 -2292 1538 -31903 -12931 1571 -1914 -339 8909 759 3770 3931 -11268 -3303 15189 7548 7600 7352 -5458 4137 6570 22013 -5764 2035 2245 -14842 -14262 -2099 -9272 5987 -10125 9657 -2873 14329 13354 19002 1628 9807 -21316 5195 69 10121 -8886 3387 -3741 5128 6778 3911 4283 -1462 20182 -12691 -1940 -5023 -842 11452 -21245 12054 -3741 533 -2559 -7917 -1877 1277 -15838 4004 18367 -3649 -1106 529 -1237 5538 -11862 10572 5696 -331 -12282 1653 -4941 14340 2176 754 -19560 4034 9703 17130 184 -3774 16426 11931 6091 13522 -14833 16084 -4031 -7391 -9406 -16052 12308 8443 16200 -7767 1745 16767 -931 -5814 317 -8571 -2267 3441 694 -8519 -7935 -5930 8579 -4772 -9390 -9681 -3703 9502 -7858 7708 2207 11640 7701 -12336 6317 3553 -10424 1022 10962 -2430 5230 502 10943 1349 SO 20180524T105649.0Z 6718.456123 459 1 32.00 2 89.03 63.70 145.51 208.69 0.00 1 0.00 1 0 15 5.802e-02 5.665e-02 5.784e-02 5.712e-02 7.937636e+03 3.896461e+03 4.523433e+02 -6.000000e+00 3.186869e+03 284.22 -2.00 20.00 -2.00 505.31 0.00e+00 9.086901e-04 1.558549e-03 4.450601e-05 -6.000000e+00 1.612959e-03 284.22 -2.00 20.00 -2.00 500.33 0.00e+00 5.877175e-01 1.120217e+00 7.233447e-02 -6.000000e+00 1.128018e+00 224.54 -2.00 3.16 -2.00 501.93 0.00e+00 18.706 0.061 489.00 513.00 1 9.3330e+00 8.5451e-02 2.8820e-02 -6.0000e+00 8.6523e-02 8.8938e-02 2.2071e-02 2.1586e-03 -6.0000e+00 2.2483e-02 1.1191e-05 -1.1608e-03 5.3189e-03 3.5455e-05 -6.0000e+00 5.6989e-03 7.3880e-02 -1.7216e-04 12 8 8 10 0 0 91.97 21.12 1.96 0.07388 0.06583 8 2 1 4 0 4000.000 25.28 20.40 21.12 -2022 -2474 4088 -1452 -3360 -8516 2224 6008 -364 -3421 -616 15899 3161 -4538 -4840 -8639 -2075 -917 -1226 -538 4350 -1192 -5017 2268 7047 3452 3997 -1831 -1031 4201 -4002 2212 9219 1249 5075 -5534 -1359 -2440 -4261 -916 -2029 9892 -413 806 -7054 1336 1788 -242 5979 -2255 783 -7269 -2590 8311 2627 2297 2535 -4438 -10342 -6293 3867 4174 7987 4281 2969 -764 9051 -1679 -1920 5471 4021 1862 -7246 1801 4360 -760 10257 -977 5636 -2282 3843 -6750 1227 -2009 -579 2812 -1033 8716 -6560 -2699 6859 16720 5538 -11332 983 -6929 6819 227 -249 2043 3791 7855 -3626 -5684 8956 4011 -4315 4653 -1308 1784 5132 -7727 837 -3303 2408 15594 8032 -5929 -5048 -7631 2648 -5968 -1581 -8464 3797 6667 3239 -10172 7725 6882 7090 4024 -4540 1022 -12057 -1565 -3014 -2855 -486 -6563 1770 -8601 -5403 6988 4800 9133 -3740 1697 -11955 1949 15051 11439 2027 -1997 -2523 4038 -1562 -3776 -9599 2446 6391 -383 -3664 -632 14623 3043 -4675 -4986 -9319 -2137 -959 -1314 -578 4465 -1295 -5674 2396 7128 3621 4147 -1989 -1085 4077 -4138 2155 8568 1300 5228 -6403 -1501 -2696 -4740 -978 -2188 9526 -445 870 -8320 1456 1935 -264 6047 -2424 795 -7787 -2600 7475 2550 2306 2611 -4986 -12390 -7234 4012 4330 8019 4194 2940 -778 8783 -1675 -1895 4958 3658 1720 -7353 1689 4043 -747 8973 -940 4990 -2164 3416 -6684 1129 -1926 -553 2627 -1012 7777 -6817 -2691 6216 13807 5174 -12688 977 -7370 6180 214 -229 1794 3210 6321 -3299 -5429 7709 3775 -4514 4461 -1319 1723 4777 -8247 832 -3467 2410 13750 7673 -6556 -5253 -8193 2714 -6191 -1541 -8696 3426 5862 2966 -10686 6792 6096 6257 3658 -4470 939 -12428 -1438 -2809 -2689 -456 -6678 1684 -9206 -5658 6513 4600 8421 -3929 1682 -13425 1868 12391 9644 1883 SO 20180524T110052.0Z 6718.458935 463 1 32.00 2 88.28 63.12 145.87 207.11 0.00 1 0.00 1 0 22 1.092e-02 1.082e-02 1.104e-02 1.099e-02 1.385986e+04 7.911952e+02 9.435649e+02 -6.000000e+00 5.998352e+02 284.22 -2.00 20.00 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