File name: Pandora114s1_BuenosAires_20180711_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T040721.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180711_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180711 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180711T110542.0Z 6766.462292 458 1 32.00 2 89.77 62.67 72.18 47.74 0.00 1 0.00 1 0 15 8.930e-02 8.494e-02 7.804e-02 7.659e-02 3.718815e+03 4.721236e+03 3.170748e+02 -6.000000e+00 4.873709e+03 282.40 -2.00 20.00 -2.00 505.28 0.00e+00 -3.566469e-04 2.071413e-03 7.224174e-05 -6.000000e+00 2.471872e-03 282.40 -2.00 20.00 -2.00 500.39 0.00e+00 7.111034e-01 1.489485e+00 1.447195e-01 -6.000000e+00 1.738371e+00 224.94 -2.00 3.16 -2.00 502.00 0.00e+00 20.174 0.077 489.00 513.00 1 9.4285e+00 1.1405e-01 3.2757e-02 -6.0000e+00 1.3326e-01 9.5238e-02 2.9325e-02 2.6481e-03 -6.0000e+00 3.4610e-02 8.3272e-06 -5.5544e-04 7.2349e-03 7.0825e-05 -6.0000e+00 8.7701e-03 -2.0953e-02 4.6413e-04 12 8 8 10 0 0 -231.45 20.63 15.00 -0.02095 -0.02481 8 2 1 4 0 4000.000 24.86 20.00 20.63 -5344 3440 -1378 -2492 -4444 2566 -9680 4506 -2788 -4016 8749 -6247 7323 -5498 1844 2713 -10813 1300 -5015 4606 -1321 7044 11898 -2875 -6936 -6094 25683 6687 8496 -3941 -6707 -7803 -1141 6790 -4350 -4261 -2487 3929 4224 1448 19343 347 12960 -3144 12436 -3978 7938 18536 -15445 15848 -2609 15075 4184 -5204 -3754 -8269 1104 -9196 6192 2619 -3604 -998 -2804 13270 3324 3830 5898 16863 8895 -14400 4108 10066 24925 -2435 -6179 -1183 -2354 5549 -14846 -4632 1759 -1954 -1163 -14261 -1107 -5665 14170 -14787 -727 4694 -12279 25829 -4167 15539 -2792 2529 2232 -7573 -501 -17142 9708 9886 12507 -37 907 4890 1733 18442 -10862 -3315 -5943 15314 11397 -835 5904 -4796 7130 4382 12252 3743 1677 6795 -5450 -9355 -11476 15071 5295 2151 -1557 -8772 -5022 -9027 8554 10828 8182 22 -3882 5667 1815 12424 -26 8819 -11423 12316 5229 -5979 5603 -10887 -5253 -14630 6403 7190 -6057 -5358 3246 -1411 -2659 -4957 2725 -11782 4784 -3170 -4565 8632 -7068 7147 -6043 1879 2580 -12013 1314 -5522 4656 -1422 6980 11254 -3166 -7984 -6953 21208 6593 8036 -4102 -7049 -8318 -1165 6626 -4877 -4819 -2751 4031 4270 1492 16650 363 12064 -3478 11887 -4500 7945 16512 -19015 13959 -2690 12674 3853 -5261 -3814 -9063 1133 -10631 6167 2700 -3951 -1068 -3073 12419 3427 3891 5785 14600 8236 -16647 3906 8967 19210 -2499 -6262 -1149 -2297 4921 -15881 -4433 1576 -1824 -1086 -15322 -1054 -5715 11834 -16581 -709 4339 -13481 19511 -4301 13342 -2895 2468 2147 -7852 -472 -18659 7925 7978 9917 -34 864 4634 1724 15489 -12078 -3375 -6190 13005 10214 -858 5734 -5221 6925 4400 11440 3811 1731 6568 -5856 -10315 -12869 13011 5068 2129 -1506 -9103 -5012 -9368 7403 9037 6901 20 -3651 4905 1667 10479 -25 7945 -12711 10877 4987 -6415 5369 -12259 -5521 -16538 5740 6319 -6098 SO 20180711T110943.0Z 6766.465081 462 1 32.00 2 89.04 62.10 71.59 47.00 0.00 1 0.00 1 0 22 1.426e-02 1.422e-02 1.553e-02 1.546e-02 8.608276e+03 1.035413e+03 5.499120e+02 -6.000000e+00 7.780087e+02 282.40 -2.00 20.00 -2.00 505.42 0.00e+00 2.786542e-03 4.203046e-04 1.550283e-04 -6.000000e+00 3.946211e-04 282.40 -2.00 20.00 -2.00 500.86 0.00e+00 1.549590e+00 2.968366e-01 7.286382e-02 -6.000000e+00 2.776128e-01 224.94 -2.00 3.16 -2.00 502.39 0.00e+00 18.762 0.062 489.00 513.00 1 7.8554e+00 2.2664e-02 2.9200e-02 -6.0000e+00 2.1279e-02 5.3116e-03 5.7240e-03 2.2301e-03 -6.0000e+00 5.5304e-03 4.4268e-05 1.3678e-03 1.4463e-03 7.9377e-05 -6.0000e+00 1.4001e-03 6.8371e-02 -1.1327e-04 12 8 8 10 0 0 -26.54 20.63 3.54 0.06837 0.07786 8 2 1 4 0 4000.000 24.86 20.00 20.63 -1461 -1474 -2032 275 2158 -552 1745 988 538 609 -2879 1027 -293 -225 -3162 -1461 -1406 -1141 -460 648 178 -1476 2702 607 2964 -1244 643 2 -1063 -379 -1615 1052 -822 -738 -653 3339 2564 -490 -117 680 -57 -1442 -1737 3495 22 1307 745 2335 1447 -1684 727 -250 30 838 -470 -555 2676 2325 -1946 731 -2542 -109 -894 41 1983 -608 3145 -1525 -1082 -939 -430 1113 -1539 -1375 -710 -163 917 1270 -1158 1744 54 -4556 -979 -1341 -366 1035 -683 1057 539 140 -3414 3036 342 1060 2174 1399 -290 -828 -1666 1079 -98 -2506 494 709 965 -124 -672 277 -468 -1069 -843 244 1259 -75 1442 611 -908 754 -809 920 -1452 1725 798 377 -642 -721 2152 869 1680 -2022 528 712 -7 198 -1774 -1452 -680 1458 -285 81 224 -673 1607 41 35 892 467 1404 -758 -2203 -1608 -1533 -75 -1300 -1354 -1945 265 2093 -562 1758 1007 546 610 -2947 998 -285 -218 -3144 -1444 -1330 -1106 -451 635 176 -1486 2621 605 2906 -1274 643 2 -1042 -359 -1527 976 -798 -741 -673 3334 2567 -501 -118 677 -57 -1487 -1820 3526 24 1372 785 2397 1476 -1736 712 -242 29 793 -461 -563 2703 2394 -2101 768 -2764 -116 -967 45 2085 -649 3191 -1598 -1116 -956 -432 1094 -1469 -1328 -691 -158 875 1187 -1092 1583 50 -4407 -920 -1276 -349 983 -665 1014 519 135 -3412 2867 336 1049 2134 1367 -282 -787 -1553 957 -87 -2246 435 642 909 -123 -682 278 -470 -1070 -843 245 1271 -77 1491 642 -974 804 -885 995 -1513 1818 834 391 -633 -715 2092 860 1653 -2067 527 709 -7 194 -1752 -1420 -662 1410 -287 83 233 -716 1689 44 38 963 508 1507 -821 -2374 -1691 -1598 -77 SO 20180711T111348.0Z 6766.467917 466 1 31.99 2 88.30 61.51 71.01 46.25 0.00 1 0.00 1 0 29 1.454e-02 1.444e-02 1.419e-02 1.414e-02 8.583993e+03 9.443331e+02 6.402176e+02 -6.000000e+00 7.937456e+02 282.40 -2.00 20.00 -2.00 505.38 0.00e+00 2.904883e-03 3.845857e-04 1.471508e-04 -6.000000e+00 4.025933e-04 282.40 -2.00 20.00 -2.00 500.71 0.00e+00 8.434800e-01 2.717974e-01 5.148755e-02 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