File name: Pandora114s1_BuenosAires_20180730_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T040908.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180730_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180730 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180730T105455.0Z 6785.454803 341 1 32.00 2 89.76 67.21 71.69 268.57 0.00 1 0.00 1 0 29 1.107e-01 1.021e-01 1.118e-01 1.076e-01 1.105998e+04 7.652441e+03 5.927448e+02 -6.000000e+00 6.033536e+03 282.16 -2.00 20.00 -2.00 505.12 0.00e+00 -4.440740e-03 2.889680e-03 2.215747e-04 -6.000000e+00 3.063565e-03 282.16 -2.00 20.00 -2.00 499.82 0.00e+00 -1.431644e+00 2.169276e+00 9.420526e-02 -6.000000e+00 2.169418e+00 225.74 -2.00 3.16 -2.00 501.45 0.00e+00 20.163 0.077 489.00 513.00 1 9.9902e+00 1.6514e-01 3.2299e-02 -6.0000e+00 1.6607e-01 1.9080e-01 4.3520e-02 2.5160e-03 -6.0000e+00 4.3493e-02 5.7943e-06 4.1118e-03 9.3728e-03 8.7480e-05 -6.0000e+00 1.0893e-02 1.9794e-01 -1.2954e-03 12 8 8 10 0 0 97.88 20.41 11.06 0.19794 0.22646 8 2 1 4 0 4000.000 24.65 20.00 20.41 -7450 19411 -3168 27946 -2608 -7375 16637 3272 7524 5015 4329 -6026 15475 -1934 -7390 -4661 2625 -9583 515 15001 14582 11109 -7606 3924 -394 -7789 -2120 7375 -13457 2778 7164 20466 -5308 12778 1298 3529 -6110 -7906 -6375 -8713 -6298 1934 -9326 3880 10719 24452 -5806 -12821 3319 336 10337 6638 -13435 -10611 9674 -12361 -9024 -4261 68 21983 4308 2372 9090 8616 -3169 4604 -11751 11905 -1088 -8830 10095 2667 32761 -15074 7318 -1690 7719 -9797 4974 -11502 -5240 30185 23 -16620 -5764 3326 2486 -23638 17643 -4800 19939 -8839 -1620 1169 -6118 -2721 6161 21408 -18045 4012 -10372 11554 19972 -8022 4802 -10485 2267 -9447 -11425 16914 -4573 10747 7814 16691 16874 -1782 20568 7987 -9371 -4988 10868 9488 -6809 20009 -7799 6491 4542 21254 -3293 -7627 5065 -7841 14927 1794 -4218 -12757 -3258 7696 -7074 -1640 7201 4962 -4133 14439 -2620 -10312 21975 2095 -992 1990 15793 5645 -5931 -8307 16964 -3580 23792 -3085 -9335 16797 3796 8333 5630 4827 -7354 15040 -2068 -8315 -5146 2751 -11658 579 14767 14458 11404 -9414 4332 -454 -9640 -2460 7675 -16843 2871 6952 17414 -5971 12399 1452 3896 -7389 -9618 -7531 -10416 -7307 2067 -11214 4120 10703 21321 -6817 -15957 3454 352 9522 6161 -14927 -11415 8639 -14168 -10279 -4704 73 18704 4362 2451 8821 8421 -3477 4630 -13717 10799 -1109 -9023 9015 2551 23267 -16397 6464 -1649 6819 -10140 4361 -11753 -5009 20297 21 -18187 -5738 3070 2344 -29140 14422 -4905 15904 -9440 -1623 1148 -6453 -2727 5483 15806 -19152 3332 -9778 8683 13956 -7668 4242 -11336 2226 -10524 -12880 14160 -4703 9494 7160 14084 14239 -1809 16677 7372 -10378 -5327 9887 8631 -7137 15697 -7969 5734 4102 16253 -3024 -7287 4243 -7443 11207 1514 -3716 -12110 -2810 6016 -6539 -1465 5987 4279 -3949 11557 -2503 -10685 16497 1911 -923 1766 11954 4659 -5483 SO 20180730T105854.0Z 6785.457569 345 1 32.00 2 89.01 66.65 72.50 268.03 0.00 1 0.00 1 0 15 1.222e-01 1.125e-01 9.797e-02 9.434e-02 -1.605588e+03 5.403082e+03 4.502230e+02 -6.000000e+00 6.659993e+03 282.16 -2.00 20.00 -2.00 505.21 0.00e+00 3.639358e-03 2.494460e-03 2.598373e-04 -6.000000e+00 3.383459e-03 282.16 -2.00 20.00 -2.00 499.94 0.00e+00 1.934234e+00 1.873447e+00 5.314638e-02 -6.000000e+00 2.398544e+00 225.74 -2.00 3.16 -2.00 501.58 0.00e+00 18.691 0.061 489.00 513.00 1 9.7187e+00 1.4258e-01 2.9059e-02 -6.0000e+00 1.8356e-01 1.2494e-01 3.7385e-02 1.6138e-03 -6.0000e+00 4.8158e-02 6.6347e-06 2.2783e-02 9.0370e-03 1.0912e-04 -6.0000e+00 1.2036e-02 5.4474e-02 -5.3114e-04 12 8 8 10 0 0 90.60 20.42 8.92 0.05447 0.21251 8 2 1 4 0 4000.000 24.65 19.99 20.42 22831 -3992 8366 -9640 -4941 -2473 -4724 7851 7667 7860 2617 -4110 17199 -1744 21425 -7271 -968 -9272 5753 16034 -21588 3171 -10966 11387 -3478 1629 -5022 7171 20300 -9900 5965 -2686 8445 568 -9424 16849 -10823 26503 -8735 10334 -3955 6382 -5902 -2563 19725 9450 21483 9495 6805 -9101 -4006 -1901 -4246 8611 -10159 5371 1288 -13539 7228 -15273 14133 -13717 9113 -5475 3115 -7908 -6887 15033 -9683 24241 950 7287 14281 -7781 13520 -9155 34569 -17440 -8083 19673 -9556 642 -15729 9792 20649 9734 14904 -11862 7908 6005 13347 -16473 6191 6296 -16072 10006 -2358 14221 -12251 -3674 17005 -8494 20253 -8008 13597 -12162 -4456 -7763 -6368 -2719 -12370 15798 722 8891 12960 3242 10584 16056 23476 -11517 16121 3534 21429 -7304 -4578 -1619 -7546 11993 -668 18018 -4884 -1154 -1114 -9823 3563 -10113 20799 -3400 -5480 -3226 -17544 18352 -1671 26269 -4248 4261 -5084 -8374 17142 -16841 32209 4316 10317 18852 -4456 8510 -12035 -6005 -2973 -5836 8505 8204 8256 2852 -4724 15791 -1924 18822 -8069 -1032 -10975 5923 14926 -29281 3362 -13454 11232 -3988 1767 -5759 7118 17145 -11047 5663 -2832 8226 617 -11446 15685 -13145 21895 -10178 9939 -4413 6492 -6877 -2923 18120 9613 19204 9424 6797 -10380 -4224 -1922 -4372 7910 -11586 5398 1374 -16861 7308 -19302 13331 -17167 9102 -6312 3264 -9117 -7728 13346 -10864 19130 937 6738 12414 -8539 12086 -10216 24509 -19152 -7988 15646 -9555 582 -16910 8206 15634 8270 12060 -12547 6856 5311 11031 -18566 5653 5823 -18671 8906 -2344 11753 -12887 -3461 12777 -8199 14867 -8008 11238 -13145 -4430 -7852 -6257 -2562 -12941 12692 689 7965 11310 3148 9604 13827 18725 -12914 13511 3309 16596 -7514 -4604 -1590 -7894 10329 -652 14579 -4968 -1127 -1075 -10162 3172 -10229 15508 -3282 -5511 -3225 -19279 15062 -1582 20042 -4159 3848 -5033 -8473 13148 -17681 20325 3592 8194 SO 20180730T110252.0Z 6785.460324 349 1 32.00 2 88.26 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