File name: Pandora114s1_BuenosAires_20180826_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042921.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180826_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180826 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180826T102602.0Z 6812.434745 316 1 32.00 2 89.75 77.23 89.60 255.34 0.00 1 0.00 1 0 15 6.664e-02 6.692e-02 7.178e-02 7.056e-02 8.982417e+03 4.913188e+03 8.465769e+02 -6.000000e+00 3.632382e+03 282.19 -2.00 20.00 -2.00 505.27 0.00e+00 8.008138e-04 1.915086e-03 1.502076e-05 -6.000000e+00 1.842988e-03 282.19 -2.00 20.00 -2.00 500.13 0.00e+00 1.316798e+00 1.409953e+00 8.504355e-03 -6.000000e+00 1.304848e+00 226.97 -2.00 3.16 -2.00 501.75 0.00e+00 20.133 0.076 489.00 513.00 1 9.2921e+00 1.0757e-01 3.0923e-02 -6.0000e+00 9.9918e-02 1.0977e-01 2.7746e-02 1.8814e-03 -6.0000e+00 2.6099e-02 8.9514e-06 -1.6525e-03 6.4637e-03 8.5130e-05 -6.0000e+00 6.5541e-03 1.5935e-01 -9.0236e-04 12 8 8 10 0 0 87.04 20.62 7.17 0.15935 0.14789 8 2 1 4 0 4000.000 24.86 20.00 20.62 4059 1491 -18276 4998 181 2740 -518 9428 176 2871 -4205 -3900 -8543 -6666 -5002 -6592 10215 1136 2572 6461 -2154 13833 11157 2655 -7004 -130 9816 6467 2983 -4653 12006 -7950 4928 -8463 9343 4926 -2794 1932 713 -1060 -15047 -935 12015 -2991 5197 -11660 2256 10093 -7039 -9106 3403 5242 -1995 3960 11869 6824 -5687 2110 -6285 598 1679 -299 13621 -3648 1156 1151 152 10831 -3776 262 -12323 3307 43 47 72 6044 1961 4503 -6399 7109 4537 -3022 -2086 5760 -6575 5896 794 -539 8251 1344 12152 -822 -9611 -6366 2767 12760 8041 12187 -7150 3049 -4895 -6245 10521 5299 1349 -6943 -2768 -2812 4903 -405 -7525 2128 10500 3376 -2213 -2119 -17300 3519 7104 1736 11064 -4414 -2940 -6411 -2885 6139 1666 2116 -7944 -2558 2072 -1567 9501 -7763 14824 -4148 69 1446 -7616 2235 5318 6330 1772 10616 -2949 -2827 -8394 2144 6401 -6616 1682 -3334 1698 3890 1503 -21657 5186 202 2843 -564 9347 190 2992 -4634 -4226 -9571 -7254 -5327 -7173 9561 1194 2727 6673 -2433 13330 11060 2877 -8396 -146 9912 6679 3122 -5106 10905 -8797 4885 -9912 9434 5270 -3220 2103 776 -1163 -18940 -1026 11689 -3420 5535 -14784 2486 10192 -8308 -10748 3451 5076 -2033 3779 10617 6607 -6425 2247 -7332 651 1804 -308 12247 -3911 1179 1164 153 9644 -3836 252 -13317 3030 41 45 70 5565 1873 4127 -6417 6146 4001 -2874 -1975 5080 -6622 5301 758 -524 7347 1278 10348 -800 -10303 -6687 2667 11032 7126 10061 -6954 2610 -4444 -5669 8095 4398 1213 -7083 -2788 -2856 4578 -394 -7807 2015 9259 3239 -2267 -2180 -19567 3453 6786 1659 10235 -4436 -2858 -6338 -2723 5295 1511 1920 -7983 -2435 1879 -1472 7963 -7643 11458 -3830 61 1271 -7467 2027 4760 5691 1687 9329 -2988 -2875 -9049 2076 5886 -6810 1560 -3201 1548 SO 20180826T103002.0Z 6812.437523 320 1 32.00 2 88.95 76.66 90.38 254.81 0.00 1 0.00 1 0 15 4.635e-02 4.529e-02 4.599e-02 4.542e-02 9.159483e+03 3.122390e+03 3.891680e+02 -6.000000e+00 2.528049e+03 282.19 -2.00 20.00 -2.00 505.25 0.00e+00 -8.206803e-04 1.231073e-03 6.250880e-05 -6.000000e+00 1.281730e-03 282.19 -2.00 20.00 -2.00 500.18 0.00e+00 1.093023e+00 8.976068e-01 1.094371e-01 -6.000000e+00 9.044286e-01 226.97 -2.00 3.16 -2.00 501.80 0.00e+00 18.536 0.060 489.00 513.00 1 9.1068e+00 6.8649e-02 2.9261e-02 -6.0000e+00 6.9308e-02 9.4390e-02 1.7590e-02 2.5634e-03 -6.0000e+00 1.8009e-02 1.4126e-05 -1.1424e-04 4.1369e-03 2.7854e-05 -6.0000e+00 4.5505e-03 1.2130e-02 2.7021e-04 12 8 8 10 0 0 -61.92 20.62 10.25 0.01213 0.01134 8 2 1 4 0 4000.000 24.86 19.98 20.62 -2697 4847 -5787 5398 1557 1311 9085 3117 3443 -2814 -3120 -3324 -2013 -1485 -1113 -3304 -6663 -469 -1032 4078 -4979 2789 -1332 -2780 7589 -4875 7699 -4318 3335 -952 1670 -2226 -641 265 -1942 3964 3950 -464 747 2117 5931 1276 -5022 -4979 339 -1197 233 6820 -1296 9342 2040 -997 -1599 -4222 9043 226 4035 -5430 2757 -1296 1569 -1460 -1820 2752 4079 7081 -2404 -5607 3858 -9126 7828 -5291 -3498 1203 858 -833 -3369 7259 -906 -1937 -2572 3445 2280 -7266 5290 -5697 2318 -6829 611 -1946 -1094 4407 -4733 4986 340 174 -10172 -903 1771 -5505 9360 -5863 1036 2403 6033 -1424 2517 2139 -4942 6382 3347 -225 3880 -980 10947 -1152 8244 -5434 -1341 -5963 -8408 5276 2779 5486 5388 2714 -3773 -6188 8965 -2800 5593 1901 7472 -4160 -1686 4985 -5641 3338 7918 3376 -2721 -4983 -1566 -4129 2020 -6498 9847 5712 111 5077 -5368 -2102 -5435 -2761 4731 -6063 5206 1599 1378 8951 3274 3586 -3082 -3379 -3561 -2103 -1529 -1139 -3490 -7435 -505 -1142 4333 -5807 3013 -1502 -3192 7883 -5729 7928 -4946 3454 -1001 1680 -2338 -679 288 -2213 4293 4256 -516 812 2249 6055 1371 -5797 -5807 379 -1361 260 7043 -1427 9039 2065 -1012 -1604 -4348 8320 234 4131 -6204 2913 -1334 1568 -1507 -1894 2741 3995 6659 -2448 -5803 3585 -9546 6839 -5241 -3416 1135 824 -818 -3365 6402 -852 -1821 -2426 3067 2068 -7318 4754 -5785 2193 -7106 589 -1922 -1071 4107 -4886 4716 337 170 -10726 -841 1562 -5100 7344 -5318 887 2099 5321 -1410 2451 2095 -5143 5859 3157 -221 3714 -996 9929 -1113 7730 -5535 -1323 -6199 -8917 4808 2547 4812 4698 2438 -3636 -6125 7629 -2677 4906 1727 6378 -3932 -1532 4204 -5303 2911 6739 3068 -2671 -5075 -1558 -4249 1968 -6925 8921 5369 109 4653 -5355 -2009 -5394 SO 20180826T103405.0Z 6812.440336 324 1 32.00 2 88.14 76.08 91.17 254.26 0.00 1 0.00 1 0 15 2.687e-02 2.669e-02 2.833e-02 2.814e-02 2.728676e+03 1.725338e+03 6.974946e+01 -6.000000e+00 1.465074e+03 282.19 -2.00 20.00 -2.00 505.28 0.00e+00 1.629226e-03 7.674447e-04 1.053458e-04 -6.000000e+00 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