File name: Pandora114s1_BuenosAires_20180902_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042850.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180902_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180902 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180902T101649.0Z 6819.428345 308 1 32.01 2 89.75 80.28 53.72 339.26 0.00 1 0.00 1 0 15 9.443e-02 8.858e-02 8.101e-02 7.894e-02 -2.408939e+03 4.518392e+03 4.366450e+01 -6.000000e+00 5.154062e+03 282.30 -2.00 20.00 -2.00 505.23 0.00e+00 1.405161e-03 2.142983e-03 1.080031e-04 -6.000000e+00 2.615233e-03 282.30 -2.00 20.00 -2.00 500.08 0.00e+00 3.206688e+00 1.583956e+00 5.724906e-02 -6.000000e+00 1.849571e+00 227.29 -2.00 3.16 -2.00 501.70 0.00e+00 20.122 0.076 489.00 513.00 1 9.2885e+00 1.2136e-01 3.1259e-02 -6.0000e+00 1.4162e-01 9.7062e-02 3.1785e-02 1.9370e-03 -6.0000e+00 3.7026e-02 7.8948e-06 6.9684e-04 7.5190e-03 4.0813e-05 -6.0000e+00 9.3016e-03 2.1515e-02 7.8459e-04 12 9 8 11 8 0 -715.78 20.72 8.83 0.02152 0.02635 8 2 1 4 0 4000.000 24.96 19.99 20.72 -5605 4134 -11730 9219 -507 3452 2572 1206 11802 -2991 6201 2276 3329 9425 5576 11753 19496 8930 -10184 4343 -3153 8114 -3469 9006 -137 -13256 -1743 -4894 -3119 4307 -10630 -4459 -7656 9679 2449 4503 518 -2603 3218 -8286 1458 -12532 -2605 -11589 12685 9357 -903 -3447 -10996 10910 12647 -1012 8360 -3526 -5551 -2772 12791 -11379 7284 1495 4093 12303 -244 1370 -10714 12380 -4808 -10494 12506 -7854 19541 3041 -1326 6907 -5781 -2967 -10031 3522 -5025 3756 -5130 11578 5274 1610 11420 -11832 -1220 -10844 -4087 3906 -1169 -2468 -2429 -7412 5020 20651 -3972 -5875 8574 -10077 20661 -16934 5807 -5561 14710 4989 -9197 17933 -9034 8825 -2707 1075 4097 789 21251 -4682 -424 -7178 24873 7397 336 -2505 -17056 4080 2558 1127 -3037 -6293 7660 -9642 18424 -958 3447 22638 -8237 10204 -4059 3542 -8095 15180 -13931 21176 8228 -13157 -3287 21486 11311 -7780 -2181 10317 -9414 15306 900000 -6010 4158 -14261 9323 -577 3834 2900 1373 11936 -3454 6443 2428 3477 9219 5701 11496 18101 8798 -12292 4547 -3562 8203 -3954 9105 -152 -16682 -1933 -5478 -3331 4176 -11953 -4807 -8806 9635 2653 4761 564 -2886 3336 -9616 1542 -15384 -2929 -14406 12431 9460 -1001 -3858 -12988 10073 11155 -1002 7503 -3619 -5984 -2989 12008 -13675 7251 1573 4201 11676 -263 1449 -12655 11430 -5183 -11800 11030 -8386 15723 2886 -1327 6449 -6172 -2870 -10234 3288 -4738 3233 -4837 9294 4539 1448 9388 -12358 -1151 -11274 -3973 3513 -1114 -2411 -2408 -7814 4685 16377 -3975 -5881 7255 -10038 14886 -17769 4942 -5458 12092 4560 -9606 14048 -9130 7425 -2579 1003 3784 767 17058 -4913 -428 -7774 19484 6832 328 -2483 -19382 3748 2400 1079 -3040 -6512 6889 -9697 14878 -881 3183 16967 -7797 8487 -3925 3237 -7995 12846 -15026 17203 7190 -14311 -3261 16721 9730 -8002 -2074 8452 -9254 11773 900000 SO 20180902T102048.0Z 6819.431111 312 1 32.01 2 88.94 79.71 54.02 338.17 0.00 1 0.00 1 0 15 2.718e-02 2.691e-02 2.482e-02 2.470e-02 1.092483e+04 1.723117e+03 7.457882e+02 -6.000000e+00 1.483163e+03 282.30 -2.00 20.00 -2.00 505.40 0.00e+00 3.663614e-03 6.743133e-04 2.041173e-04 -6.000000e+00 7.517899e-04 282.30 -2.00 20.00 -2.00 500.69 0.00e+00 1.853551e+00 4.820477e-01 7.651948e-02 -6.000000e+00 5.306383e-01 227.29 -2.00 3.16 -2.00 502.26 0.00e+00 18.509 0.059 489.00 513.00 1 8.3620e+00 3.6945e-02 2.9045e-02 -6.0000e+00 4.0662e-02 2.1661e-02 9.2556e-03 2.3568e-03 -6.0000e+00 1.0569e-02 2.6494e-05 9.3782e-04 2.2912e-03 1.0359e-04 -6.0000e+00 2.6688e-03 9.9962e-03 2.6800e-04 12 8 8 10 0 0 87.52 20.71 0.64 0.01000 0.01650 8 2 1 4 0 4000.000 24.96 19.99 20.71 -9133 1172 -1728 -670 1996 -159 1451 516 2548 1324 3136 -174 136 -1533 477 1266 1491 1773 -2910 -2310 -841 -483 3180 2468 4693 -5176 1787 10340 1689 -1459 -4310 -2769 1101 3328 -617 -2678 -838 -1996 -1770 1410 4208 3118 -1685 -939 8 -1680 -578 931 569 1002 -3251 -2852 -2158 -432 2760 -138 -1815 1847 1015 -1736 613 2090 504 942 -2065 2979 -278 -1660 -265 -31 -4250 -745 -2514 -1193 -3861 1547 3421 2570 -2836 2457 1761 -2824 4080 -1521 4684 3169 -620 -636 -1707 1608 -655 -778 376 -428 5684 -2172 -147 -2131 -1797 310 5095 -1044 -39 -1596 -5302 528 -325 -1573 3150 -5848 1835 -2722 -1457 1903 -1014 1015 486 3148 2359 4953 1942 -699 -3477 -86 -1559 -719 4208 -1160 2892 -2268 2291 -580 5818 747 -4477 -2587 -3060 3429 178 1419 1527 -3736 7 -1791 4462 -2340 1133 4579 -4559 1043 -4265 3040 122 -8829 1053 -1657 -656 1949 -162 1473 531 2550 1322 3032 -171 132 -1502 457 1216 1459 1774 -3113 -2479 -892 -512 3259 2565 4802 -5855 1878 9845 1712 -1484 -4438 -2824 1109 3183 -630 -2816 -861 -2053 -1800 1383 4024 3042 -1749 -982 8 -1802 -612 962 581 998 -3291 -2805 -2076 -410 2593 -138 -1895 1889 1052 -1849 639 2153 531 991 -2231 3028 -287 -1715 -267 -30 -4353 -732 -2526 -1197 -4031 1538 3307 2461 -2819 2293 1649 -2773 3759 -1494 4365 3030 -620 -637 -1722 1562 -650 -778 377 -438 5478 -2232 -144 -1945 -1688 278 4286 -871 -33 -1395 -5028 492 -312 -1532 2902 -5846 1701 -2674 -1438 1843 -1021 1008 488 3106 2375 4895 1971 -718 -3610 -85 -1556 -716 4021 -1176 2825 -2335 2255 -588 5492 731 -4558 -2568 -3063 3267 179 1437 1570 -4107 8 -1969 4638 -2616 1224 4760 -4844 1089 -4353 3030 119 SO 20180902T102452.0Z 6819.433935 316 1 32.01 2 88.12 79.13 54.34 337.06 0.00 1 0.00 1 0 22 8.276e-03 8.253e-03 4.810e-03 4.789e-03 1.255167e+04 3.393943e+02 8.359127e+02 -6.000000e+00 4.515234e+02 282.30 -2.00 20.00 -2.00 505.41 0.00e+00 4.472559e-03 1.301408e-04 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