File name: Pandora114s1_BuenosAires_20180907_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042830.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180907_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180907 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180907T100958.0Z 6824.423588 408 1 32.00 2 89.75 82.53 74.64 54.15 0.00 1 0.00 1 0 73 1.973e-01 1.742e-01 1.834e-01 1.698e-01 -6.611984e+02 1.013049e+04 7.661449e+02 -6.000000e+00 1.077539e+04 282.39 -2.00 20.00 -2.00 505.31 0.00e+00 2.001460e-03 4.583562e-03 3.480637e-04 -6.000000e+00 5.468706e-03 282.39 -2.00 20.00 -2.00 500.20 0.00e+00 4.242374e+00 3.420799e+00 1.228562e-01 -6.000000e+00 3.879492e+00 227.52 -2.00 3.16 -2.00 501.85 0.00e+00 20.117 0.076 489.00 513.00 1 9.9628e+00 2.6240e-01 3.3046e-02 -6.0000e+00 2.9684e-01 5.8662e-02 6.7446e-02 2.0997e-03 -6.0000e+00 7.7955e-02 3.5555e-06 -9.8694e-03 1.6558e-02 2.1534e-04 -6.0000e+00 1.9448e-02 3.4990e-02 4.7760e-04 12 8 8 10 0 0 89.44 21.69 15.59 0.03499 -0.03347 8 2 1 4 0 4000.000 25.79 20.03 21.69 18947 1743 -22062 26753 -564 29959 5163 3506 -12852 -13211 31583 10306 27548 -6419 5437 485 2400 16761 -19912 4980 8554 13244 -14679 -11490 7818 -22713 16572 4122 50102 -20391 2395 5978 11732 36517 -26223 21354 -8784 24865 5890 10688 15316 -10437 58087 -11818 40626 24624 -10546 17173 12020 -3109 -21696 36579 1238 -2360 -8027 -13871 10690 -4755 22512 -17369 40341 -5526 3997 15405 -5372 11582 -19064 16789 10389 -21763 27763 -18417 3502 -7576 15479 -4686 17890 17420 9184 24367 -622 24226 -16739 -1502 11137 4615 15137 -13667 24985 24893 -3346 9899 -31824 29 -11101 25217 -9210 3917 -26669 8960 18619 37335 26146 19336 57506 3641 -914 8543 25269 -5547 -20622 30588 10690 -3108 5063 -27333 22761 -8607 -407 -11213 52745 17460 -18416 5696 17695 23606 -25682 9670 14610 5322 5362 -19037 28847 -15197 27501 12895 31830 27001 9660 746 -15697 -1307 15750 21102 10075 -16031 -1101 -2240 21556 -10277 -17039 27634 900000 15314 1720 -28581 21940 -623 24925 5585 3875 -16650 -16958 25526 10167 22592 -7324 5493 518 2567 15937 -27926 5504 9150 13537 -19889 -15159 8549 -31495 16546 4298 34538 -25787 2364 5703 10802 27141 -37525 19188 -10621 21239 6011 10315 14102 -12504 35440 -14683 30195 21579 -13103 16002 11600 -3414 -27918 25564 1209 -2382 -8727 -16465 10198 -5380 19479 -22350 29088 -6314 4168 14355 -6138 11049 -24320 14714 9566 -27281 20943 -21861 3341 -8152 13394 -4991 15082 14493 8150 18381 -601 18274 -19126 -1482 9760 4352 12930 -15615 19402 19330 -3452 9005 -41701 30 -12122 20421 -9769 3585 -32450 7455 13748 24021 17674 14278 29903 3332 -884 7463 18395 -5422 -23377 20996 9116 -3103 4739 -35817 18227 -9488 -415 -12710 31267 14527 -21643 5213 14354 18167 -32585 8649 12459 4982 5019 -22769 21301 -17227 20021 10729 21848 19657 8539 737 -18611 -1359 13923 17776 9535 -19840 -1180 -2423 18159 -11649 -20201 20692 900000 SO 20180907T101357.0Z 6824.426354 412 1 32.00 2 88.93 81.96 74.00 53.47 0.00 1 0.00 1 0 22 1.315e-01 1.197e-01 1.182e-01 1.138e-01 -3.911829e+02 6.587361e+03 3.050137e+02 -6.000000e+00 7.179306e+03 282.39 -2.00 20.00 -2.00 505.29 0.00e+00 3.184453e-03 3.081551e-03 1.720508e-04 -6.000000e+00 3.638817e-03 282.39 -2.00 20.00 -2.00 500.25 0.00e+00 2.507251e+00 2.249172e+00 6.888205e-02 -6.000000e+00 2.569673e+00 227.52 -2.00 3.16 -2.00 501.87 0.00e+00 18.491 0.059 489.00 513.00 1 9.9144e+00 1.7229e-01 2.8568e-02 -6.0000e+00 1.9689e-01 7.7483e-02 4.4340e-02 1.7349e-03 -6.0000e+00 5.1213e-02 5.3937e-06 7.8468e-03 1.0861e-02 8.7609e-05 -6.0000e+00 1.2920e-02 2.1904e-02 1.6059e-04 12 9 8 11 8 0 65.45 21.68 13.42 0.02190 0.07633 8 2 1 4 0 4000.000 25.79 20.02 21.68 -5518 -10379 9886 20483 -4914 -1799 7059 12375 -5603 1293 10658 -1582 8937 10721 1946 -17016 1738 19428 13423 6153 -3683 -15013 -3797 -3863 -2130 -1638 11396 -6950 -32 -1235 13041 -5908 -5660 22333 12636 4534 4376 1754 34440 -16568 -11228 17258 -14507 -5118 405 1267 -13990 -3389 -9817 -807 10169 12874 21809 -5324 5555 -13719 9287 -2648 -2558 -1376 12624 -8161 -10914 21600 8076 906 5097 8183 4555 -21130 1474 -9709 24831 6098 23373 -18472 4940 -4423 4891 7575 -4211 4736 25881 10141 -951 19524 1737 -3319 -4113 -7642 12558 3988 -7341 31027 -7953 10171 -14243 9373 -2873 -16957 5125 16653 49372 10619 -15560 -9227 -11208 14149 11801 9320 -7569 -3158 -6021 -1339 2296 8461 12212 -2405 25132 -10582 -14275 16676 -21113 6895 2710 -10297 -3838 -3627 -16328 514 11808 20814 -3228 24643 8424 -10762 12650 9266 -10121 22478 -10006 26572 11407 3060 10130 16035 -1184 20192 15895 -19274 25268 -5378 -22956 -5716 -11663 9376 17956 -5679 -2051 7426 12328 -6609 1401 10363 -1714 8618 10082 2001 -21426 1856 17806 13265 6571 -4345 -18537 -4208 -4310 -2345 -1791 10850 -7807 -33 -1240 11252 -6240 -6147 18937 12031 4687 4492 1827 25617 -20457 -13195 15404 -18020 -5863 443 1376 -17586 -3781 -11464 -841 9228 11108 17033 -5505 5289 -16327 8981 -2915 -2816 -1495 11926 -9531 -13152 18798 7990 950 5042 7730 4404 -26090 1436 -10544 19209 5760 18776 -22534 4704 -4540 4511 6761 -4229 4368 19444 8977 -948 15975 1599 -3217 -4015 -7727 10421 3643 -7627 23771 -8485 9008 -15892 8105 -2745 -18210 4324 12425 26854 8738 -17144 -9715 -12036 11643 9792 7864 -7600 -3083 -6172 -1336 2241 7847 10986 -2516 19979 -11955 -16524 13955 -25470 6251 2570 -11202 -3934 -3718 -19015 506 10375 16692 -3263 18559 7343 -11257 10497 8077 -10940 17869 -11165 20753 10421 3052 9466 14200 -1173 17038 13744 -21757 19030 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