File name: Pandora114s1_BuenosAires_20180911_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042900.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180911_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180911 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180911T100423.0Z 6828.419711 423 1 32.00 2 89.74 84.36 106.60 101.31 0.00 1 0.00 1 0 26 8.864e-02 8.721e-02 7.908e-02 7.723e-02 1.079300e+04 5.475716e+03 5.461959e+02 -6.000000e+00 4.837523e+03 282.46 -2.00 20.00 -2.00 505.26 0.00e+00 1.423028e-03 2.065750e-03 5.515031e-05 -6.000000e+00 2.453552e-03 282.46 -2.00 20.00 -2.00 500.12 0.00e+00 3.333423e-01 1.532281e+00 8.952359e-02 -6.000000e+00 1.739114e+00 227.71 -2.00 3.16 -2.00 501.73 0.00e+00 20.111 0.076 489.00 513.00 1 9.4562e+00 1.1635e-01 3.1702e-02 -6.0000e+00 1.3314e-01 1.2922e-01 2.9968e-02 2.5076e-03 -6.0000e+00 3.4831e-02 8.0677e-06 9.5281e-03 6.9319e-03 4.0746e-05 -6.0000e+00 8.7189e-03 1.5404e-01 -9.4825e-04 12 8 8 10 0 0 -138.22 21.47 12.54 0.15404 0.22014 8 2 1 4 0 4000.000 25.58 20.01 21.47 -4724 -24357 17044 -12491 -4934 -5825 5400 3482 -3518 20634 -4680 -2788 15951 2579 7835 -5547 5969 -6738 9666 2907 -5169 756 -7822 14337 12580 7846 -2760 9432 -4423 -3473 4806 -6994 7553 -4017 6511 4965 -6209 10912 -3196 10852 -12646 5693 22246 -2689 3666 -5019 17955 -1514 -5085 2780 -1953 -11421 -10021 9243 -3747 -174 2761 -4721 11721 -622 1695 -11901 -668 17872 1243 -8406 -14171 10371 6999 2273 -3665 10863 7590 13797 8011 2183 542 -8440 -3958 5357 5075 8056 -13944 18216 10664 11762 493 8253 -3055 -1578 4392 -1877 -201 -8867 21812 -7501 563 -1617 1292 -9279 -1608 14423 3173 9543 11236 -11213 -11922 -11535 -824 -2291 -3237 8809 1562 15580 -4244 12139 -829 -946 5254 -4365 5108 -4428 12691 -689 -14731 10829 6645 9523 -3774 14282 -845 -2999 14088 -9132 9353 -8111 1041 24 -1840 430 -446 3205 -14622 2013 -13409 7619 4637 -1118 2083 -8582 -2825 -5553 13197 -5006 -32398 15482 -15670 -5869 -6643 5956 3916 -3924 19078 -5125 -2955 14835 2538 7315 -5990 5874 -7719 9561 3095 -5973 824 -9315 13747 12316 8038 -3120 9282 -4866 -3681 4632 -7659 7356 -4541 6769 5262 -7301 10683 -3564 10460 -15444 5833 19534 -3067 3959 -5927 16763 -1696 -5800 2862 -2050 -12853 -10974 8396 -3971 -184 2898 -5408 11416 -685 1822 -13795 -695 16505 1265 -9306 -16359 9839 6358 2140 -3624 9251 6715 11619 7239 2096 523 -8745 -3857 4714 4466 6899 -14976 14306 9132 10072 476 7380 -3050 -1546 4052 -1856 -198 -9607 17337 -7843 527 -1500 1131 -8824 -1392 10576 2642 7720 9356 -12149 -13255 -12771 -811 -2266 -3231 7877 1523 13342 -4457 10855 -847 -975 5145 -4729 5002 -4692 11108 -638 -15611 9478 5741 8014 -3630 11447 -786 -2844 11166 -8987 7538 -7729 908 22 -1712 398 -423 2969 -16343 1919 -14986 6921 4336 -1100 1957 -8789 -2679 -5365 10637 SO 20180911T100822.0Z 6828.422477 427 1 32.01 2 88.93 83.80 105.82 100.73 0.00 1 0.00 1 0 22 3.351e-02 3.284e-02 3.961e-02 3.930e-02 2.795810e+03 2.426919e+03 2.165931e+02 -6.000000e+00 1.829996e+03 282.46 -2.00 20.00 -2.00 505.31 0.00e+00 2.883591e-03 1.065180e-03 1.548528e-04 -6.000000e+00 9.274095e-04 282.46 -2.00 20.00 -2.00 500.35 0.00e+00 3.069176e+00 7.701297e-01 2.969578e-02 -6.000000e+00 6.549576e-01 227.71 -2.00 3.16 -2.00 501.95 0.00e+00 18.477 0.059 489.00 513.00 1 8.7886e+00 5.8850e-02 2.8170e-02 -6.0000e+00 5.0185e-02 4.6127e-02 1.5072e-02 1.6105e-03 -6.0000e+00 1.3053e-02 1.6268e-05 4.5842e-03 3.7204e-03 5.7039e-05 -6.0000e+00 3.2924e-03 7.7791e-03 2.4689e-04 12 8 8 10 0 0 -205.97 21.47 2.95 0.00778 0.03958 8 2 1 4 0 4000.000 25.58 20.00 21.47 -1553 -4587 1478 3051 1799 -4107 -1095 1473 -2748 -820 -1792 -119 4472 -5333 -3113 -705 2255 -472 387 4043 4476 2668 -545 -2484 -1288 4157 -303 57 -1351 -4395 1591 -7431 -3213 3342 2708 3685 -1038 1355 -3197 4532 136 1014 4692 3343 -3695 2555 1643 2817 -3589 -2913 -115 2477 -951 -8541 2192 -934 1786 1874 2346 2903 -200 3743 -1238 472 1571 -2678 -786 291 690 -288 -4611 -2436 4407 -3022 -1590 3363 683 -1185 3461 5364 4908 412 492 1177 -4280 7098 835 4053 3651 -2608 -1394 -3001 -2802 254 6738 -3616 3747 -1740 -1627 -355 -4453 7572 7372 1753 -1683 -1952 -648 -2365 -771 2590 2573 -2545 -2842 832 -4572 7837 -2905 67 -325 4999 -180 -3033 4362 -6958 -2527 3732 -197 -2651 7186 538 5461 -3610 -2660 1143 -4176 -6222 -751 746 -1157 3214 -2603 -977 -1101 593 -5094 3612 2910 3070 8405 948 -1282 -4518 -2030 -1543 -4524 1419 2970 1815 -4483 -1173 1540 -2971 -858 -1864 -120 4261 -5561 -3174 -709 2253 -497 411 4174 4610 2803 -594 -2775 -1429 4366 -331 62 -1430 -4662 1569 -8092 -3449 3477 2900 3928 -1152 1451 -3547 4633 145 1086 4905 3589 -4299 2802 1810 3031 -4046 -3187 -119 2437 -955 -9301 2195 -996 1899 1891 2361 2901 -206 3723 -1299 488 1596 -2805 -795 286 667 -278 -4596 -2364 4011 -2998 -1573 3174 655 -1135 3117 4702 4314 380 456 1091 -4225 6307 794 3738 3375 -2562 -1356 -2992 -2827 252 6295 -3718 3519 -1689 -1540 -324 -4149 6199 6106 1579 -1625 -1941 -642 -2363 -748 2407 2398 -2531 -2888 780 -4590 7015 -2916 65 -322 4690 -176 -3011 3964 -7017 -2440 3408 -188 -2608 6416 513 4962 -3591 -2605 1062 -4031 -6078 -696 691 -1117 3030 -2642 -988 -1123 598 -5472 3577 2908 3048 7790 926 -1255 -4536 -2006 SO 20180911T101226.0Z 6828.425301 431 1 32.01 2 88.10 83.22 105.02 100.15 0.00 1 0.00 1 0 22 7.228e-03 7.138e-03 1.876e-03 1.870e-03 1.276863e+04 1.283911e+02 8.438249e+02 -6.000000e+00 3.947296e+02 282.46 -2.00 20.00 -2.00 505.42 0.00e+00 2.838396e-03 5.094631e-05 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