File name: Pandora114s1_BuenosAires_20180918_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042853.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180918_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180918 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180918T095427.0Z 6835.412813 367 1 32.01 2 89.75 87.63 123.51 196.44 0.00 1 0.00 1 0 71 1.259e-01 1.198e-01 1.128e-01 1.090e-01 1.582023e+04 8.185947e+03 1.857470e+03 -6.000000e+00 6.882179e+03 282.65 -2.00 20.00 -2.00 505.34 0.00e+00 6.018660e-03 2.965240e-03 3.769687e-04 -6.000000e+00 3.486546e-03 282.65 -2.00 20.00 -2.00 500.31 0.00e+00 1.351880e+00 2.155518e+00 1.163168e-01 -6.000000e+00 2.461690e+00 227.96 -2.00 3.16 -2.00 501.90 0.00e+00 20.107 0.076 489.00 513.00 1 9.6632e+00 1.6537e-01 3.2919e-02 -6.0000e+00 1.8863e-01 7.8655e-02 4.1223e-02 1.7937e-03 -6.0000e+00 4.9066e-02 5.6023e-06 2.5072e-02 9.9293e-03 2.0974e-04 -6.0000e+00 1.2372e-02 3.1957e-02 9.7207e-05 12 8 8 10 0 0 98.47 22.00 1.77 0.03196 0.20586 8 2 1 4 0 4000.000 26.00 20.00 22.00 4247 7619 -943 39015 6598 5163 9358 13592 8775 14436 -4513 3074 -2868 -9078 -6456 -8987 7406 2941 -6180 1319 -545 -11625 11628 9940 -4016 -8573 -1228 18088 5666 -1907 -12166 -1005 -7687 12959 -9947 13851 6775 -5033 7429 2387 6513 -10870 674 457 13996 -16889 -14176 -2572 -928 -6233 -21332 22223 26076 5078 15811 -7425 20854 849 13330 -19571 1599 3424 8233 4837 -1731 10356 7379 -19345 10110 -19882 14252 -19589 16864 -11518 30697 -10081 -11415 11874 10184 22584 -17266 12761 11842 2809 5101 4624 16777 -151 9528 3335 1259 -5641 -12436 12491 -8850 10428 -258 1584 9565 1039 -1768 -28724 4771 1660 6136 -10968 13954 5311 -12329 -12227 -4801 3013 9238 1943 12499 12442 16772 -14809 4246 -4883 1062 33023 -15124 13256 -18075 19637 2753 14043 -11757 977 -15028 -5057 14196 5374 26548 -5815 3458 19056 4176 33257 9731 23582 -9037 6986 -9099 -8258 15826 15729 7898 -6316 -10177 -8329 6714 4050 7266 -1007 28576 6796 5436 9425 12963 8636 13217 -4924 3072 -3020 -10181 -7142 -10422 7458 3141 -7261 1439 -608 -13576 11622 10162 -4404 -9767 -1276 15070 5205 -1874 -13428 -1024 -8649 12089 -11688 12723 6610 -5484 7141 2430 6446 -13005 730 501 13455 -22009 -17766 -2820 -978 -6746 -26279 17566 20054 4954 14298 -8671 18562 925 12814 -26200 1742 3682 8442 5097 -1922 10029 7251 -24520 9431 -24776 12585 -24411 14771 -13533 23608 -11486 -12925 10484 9065 17690 -20163 11086 10456 2740 4904 4198 14336 -142 8617 3006 1169 -5687 -13533 10507 -8981 8424 -224 1311 7152 832 -1452 -31449 3886 1463 5366 -11569 11458 4716 -13005 -12978 -4807 2836 8264 1880 10931 10964 14332 -17597 4195 -5249 1057 23369 -17064 11239 -21116 15862 2647 12094 -13107 959 -17256 -5199 11847 4843 19318 -5900 3255 15647 4042 24422 9159 19522 -10437 6903 -9947 -8925 14158 13860 7382 -6310 -10551 -8583 6075 SO 20180918T095827.0Z 6835.415590 371 1 32.00 2 88.92 87.06 123.72 195.40 0.00 1 0.00 1 0 22 7.500e-02 7.321e-02 7.314e-02 7.188e-02 9.843445e+03 4.959984e+03 8.008386e+02 -6.000000e+00 4.098933e+03 282.65 -2.00 20.00 -2.00 505.27 0.00e+00 -4.459990e-04 1.924570e-03 4.561331e-05 -6.000000e+00 2.077427e-03 282.65 -2.00 20.00 -2.00 500.27 0.00e+00 -2.805850e-02 1.411771e+00 1.753252e-02 -6.000000e+00 1.470246e+00 227.96 -2.00 3.16 -2.00 501.85 0.00e+00 18.460 0.059 489.00 513.00 1 9.6805e+00 1.0738e-01 2.7868e-02 -6.0000e+00 1.1261e-01 9.8409e-02 2.7883e-02 1.7656e-03 -6.0000e+00 2.9384e-02 8.6560e-06 1.0265e-02 6.5145e-03 9.9942e-05 -6.0000e+00 7.3770e-03 -1.5778e-02 2.1070e-04 12 9 8 11 8 0 -121.12 21.99 3.47 -0.01578 0.05542 8 2 1 4 0 4000.000 26.00 20.00 21.99 -2793 8713 -892 1389 -6372 13041 -1224 9693 795 -1038 2708 3333 1207 -11376 15637 5286 3719 -635 -1910 6938 -12909 9125 1086 6035 3547 -7382 4785 -8200 6627 1989 916 3453 -2941 6833 -1386 2006 6193 -5956 -1950 -5973 6690 -1337 -728 -5944 341 -7793 -512 1719 -1867 1591 -10966 15180 4299 -948 4507 -10034 1494 -7253 -704 1800 -838 919 -5883 8907 9838 -4921 -13410 -5323 5989 -7994 7518 1339 2551 13604 1517 -1898 3893 3512 5474 6771 -7269 -7269 7421 -363 -1870 -10619 -2974 -7466 10887 3313 -1560 -3431 13325 6777 2584 6706 3327 2195 -3891 -6022 13025 -10986 18923 -10167 -7182 -5140 415 9413 -13750 4443 -15060 1368 405 3122 1832 -9562 11227 -3502 15935 -560 7847 9407 1908 3594 460 15404 923 5686 -6263 -6069 13586 -8203 6879 -7825 142 -5832 1135 9145 397 -14650 681 9650 -2566 12754 2500 -1355 13561 -14100 13767 -11662 1508 12792 8205 -2783 7981 -929 1454 -7375 12666 -1386 9854 876 -1149 2848 3439 1257 -13339 14008 4966 3633 -665 -2063 6908 -15704 8915 1153 6123 3699 -8565 4877 -9359 6350 1943 895 3325 -3108 6772 -1523 2139 6283 -6742 -2097 -6650 6567 -1432 -783 -6813 370 -9188 -558 1808 -1999 1607 -12207 12692 3958 -927 4276 -11358 1543 -8279 -754 1877 -898 972 -6688 8744 9519 -5455 -15936 -5751 5711 -8674 6922 1308 2480 12013 1532 -1864 3566 3170 4773 5785 -7138 -7170 6372 -341 -1804 -11316 -2959 -7792 9445 3093 -1532 -3460 11501 6297 2492 6084 3033 1962 -3598 -5569 9808 -10498 13665 -10208 -7337 -5342 415 8580 -15621 4168 -17176 1337 405 3066 1831 -10737 10283 -3748 14174 -590 7533 8740 1873 3418 449 13023 906 5333 -6229 -6012 11726 -8261 5901 -7654 126 -5487 1002 8054 367 -16029 650 8519 -2584 11100 2425 -1370 11803 -16070 11697 -12518 1394 10497 7107 SO 20180918T100229.0Z 6835.418391 375 1 32.00 2 88.09 86.49 123.93 194.34 0.00 1 0.00 1 0 15 4.187e-02 4.106e-02 3.965e-02 3.924e-02 9.942389e+03 2.718391e+03 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