File name: Pandora114s1_BuenosAires_20180920_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T044716.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180920_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180920 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180920T095137.0Z 6837.410845 340 1 32.00 2 89.74 88.57 115.84 220.63 0.00 1 0.00 1 0 15 1.329e-01 1.238e-01 1.263e-01 1.209e-01 1.191034e+04 9.024564e+03 6.746690e+02 -6.000000e+00 7.261324e+03 282.74 -2.00 20.00 -2.00 505.35 0.00e+00 -2.317215e-03 3.331349e-03 1.806975e-04 -6.000000e+00 3.684081e-03 282.74 -2.00 20.00 -2.00 499.96 0.00e+00 4.078698e+00 2.437605e+00 1.081587e-01 -6.000000e+00 2.616266e+00 228.01 -2.00 3.16 -2.00 501.63 0.00e+00 20.099 0.076 489.00 513.00 1 9.6935e+00 1.8719e-01 3.2289e-02 -6.0000e+00 2.0019e-01 5.0028e-02 4.7102e-02 2.8196e-03 -6.0000e+00 5.2572e-02 5.0250e-06 7.4319e-03 1.0799e-02 7.0298e-05 -6.0000e+00 1.3093e-02 8.2801e-03 -2.9606e-04 12 8 8 10 0 0 -262.73 21.32 14.01 0.00828 0.05983 8 2 1 4 0 4000.000 25.47 20.00 21.32 -3399 23712 8468 -5578 22613 -10696 -9662 -13422 38645 -6407 356 2253 -430 1003 3067 3797 3367 23280 3331 -7145 13891 -11573 26360 -12918 9449 -14973 -15462 4147 1335 25360 4814 9587 19374 -10964 -10523 -12883 18114 8285 33989 -11569 3889 26699 -10666 7827 5663 17916 3540 9287 -23067 -7033 -1190 -12112 -3405 -1788 15863 8846 -2569 4490 -6651 24448 -8610 11676 209 6516 7839 5296 12832 -4802 3731 1656 7124 19107 -13293 2911 -24909 -1242 1407 9753 7722 -9296 2913 -13075 -8860 15995 12336 -4938 -5388 18973 -2590 14812 -20968 29661 -9059 -1449 13601 -3745 5591 -11683 25571 -1167 22208 -6717 -16710 -7312 -2597 17648 2505 39116 -12509 1926 18758 -26461 4968 -4997 -678 10018 16340 218 5287 930 -1826 4012 22167 5128 7326 5641 23673 -5081 -10636 15882 4527 3698 -4420 12603 -14800 -6134 -6720 -15421 13358 781 7459 -11155 19987 4128 16124 -5469 -11545 5353 -11118 -493 -1560 3891 17077 -3426 18674 8031 -6282 19723 -13315 -12108 -17616 30106 -7758 398 2442 -473 1078 3221 3987 3621 21094 3779 -9136 14469 -14543 24331 -16540 9708 -19644 -20286 4425 1435 20845 4756 9016 16843 -13344 -13140 -16698 17180 8578 26863 -14263 4088 22368 -13066 8042 5997 16850 3833 9395 -31721 -8060 -1251 -13784 -3472 -1780 13414 8249 -2761 4578 -7622 20482 -10003 11074 223 6540 7745 5316 11765 -5162 3627 1623 6532 15403 -14814 2784 -31893 -1267 1390 8710 6896 -9698 2670 -14054 -9173 13021 10529 -5073 -5270 15595 -2475 12643 -23925 21801 -9263 -1385 11186 -3607 4764 -11426 16673 -969 14316 -5723 -15848 -6501 -2309 13469 2301 25215 -13440 1769 14455 -32154 4454 -4999 -653 8685 13317 210 4897 910 -1840 3775 17081 4597 6351 4974 17540 -5044 -11190 12827 4092 3370 -4355 10365 -15791 -5954 -6573 -16682 11085 752 6853 -12563 16734 4099 14336 -6079 -12882 5354 -12250 -481 -1512 3527 13576 SO 20180920T095536.0Z 6837.413611 344 1 32.01 2 88.92 88.00 116.35 219.80 0.00 1 0.00 1 0 29 1.053e-01 9.926e-02 9.210e-02 8.956e-02 -8.586959e+03 4.986341e+03 7.688580e+02 -6.000000e+00 5.755712e+03 282.74 -2.00 20.00 -2.00 505.15 0.00e+00 2.997084e-03 2.400536e-03 1.549638e-04 -6.000000e+00 2.918789e-03 282.74 -2.00 20.00 -2.00 500.11 0.00e+00 2.611366e+00 1.802569e+00 4.373847e-02 -6.000000e+00 2.070854e+00 228.01 -2.00 3.16 -2.00 501.70 0.00e+00 18.457 0.059 489.00 513.00 1 9.6990e+00 1.3705e-01 2.8273e-02 -6.0000e+00 1.5849e-01 1.0376e-01 3.6608e-02 1.9295e-03 -6.0000e+00 4.1560e-02 6.8571e-06 -8.6042e-03 8.5700e-03 1.2134e-04 -6.0000e+00 1.0372e-02 1.4958e-01 -1.0542e-03 12 9 8 11 8 0 -130.74 21.33 3.16 0.14958 0.08990 8 2 1 4 0 4000.000 25.47 20.00 21.33 12052 -716 2188 -1062 656 9518 -8544 -4348 -13560 22242 16728 -560 22560 -492 12712 4792 -6477 11977 20361 -7535 -7775 8599 -9084 15588 -3284 5270 3036 -17440 -5393 -6900 8988 8499 -3079 -2907 17233 5722 -146 9281 -12552 -8803 7451 -1041 7037 -8079 -6822 -2737 16941 -1643 4250 -6517 3131 3896 630 -6276 -1061 7009 -149 -1415 13520 -12826 -8601 -5180 2595 -1375 1471 6109 5570 5165 10852 -8464 -10263 14838 8084 -3877 20192 -19812 -1046 3407 -693 20776 -12613 -6642 -12272 -5528 -2632 315 3361 20449 19368 3898 -13 -17521 -1978 -3812 -3563 3662 -7436 23754 -11342 1727 9343 11812 -18041 -3042 1155 6147 10520 -5353 -15257 -275 -643 14334 -5952 -1036 -214 4449 -4010 4569 21163 -5496 32252 -11532 7881 21652 4647 -8759 1647 10431 11848 25841 -4268 8688 -6301 -6676 11452 -12377 12223 -10527 17877 7184 2737 -9088 -11110 3998 7535 7286 -13531 -9608 1022 16150 3873 1720 9856 10579 -722 2209 -1145 716 9728 -10661 -5262 -18025 20501 16048 -628 19804 -537 12036 4571 -6975 10934 17517 -8731 -9100 8555 -10792 14505 -3710 5490 3234 -22658 -6122 -7753 8363 7809 -3189 -3079 15431 5894 -161 9234 -15353 -10252 7326 -1115 7001 -9456 -7985 -3107 15863 -1846 4452 -7475 3189 3830 623 -6538 -1049 6522 -153 -1515 12660 -15688 -10068 -5851 2718 -1505 1567 6185 5607 5139 10035 -9362 -11412 12678 7333 -3723 16425 -22827 -1004 3103 -647 15389 -12941 -6414 -12591 -5338 -2483 290 3024 15595 14983 3529 -13 -19802 -1931 -3848 -3656 3556 -8160 19158 -12943 1706 8355 10045 -20292 -2937 1084 5599 9292 -5522 -17077 -259 -600 11482 -5911 -1000 -210 4272 -4268 4512 17765 -6001 23889 -13034 7221 17106 4334 -9371 1599 9329 10466 19849 -4165 7448 -6279 -6653 9403 -12655 10193 -10274 14026 6010 2445 -9291 -11703 3633 6614 6433 -14813 -10170 971 13010 3440 1519 7889 SO 20180920T095941.0Z 6837.416447 348 1 32.01 2 88.08 87.42 116.87 218.94 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