File name: Pandora114s1_BuenosAires_20180924_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T045050.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180924_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180924 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180924T094555.0Z 6841.406887 297 1 32.00 2 89.75 90.46 92.29 261.46 0.00 1 0.00 1 0 15 1.112e-01 1.056e-01 9.598e-02 9.324e-02 4.028982e+03 6.096386e+03 2.756633e+02 -6.000000e+00 6.081732e+03 282.91 -2.00 20.00 -2.00 505.33 0.00e+00 2.336794e-03 2.571207e-03 3.819303e-05 -6.000000e+00 3.082995e-03 282.91 -2.00 20.00 -2.00 500.15 0.00e+00 1.921831e+00 1.859214e+00 3.553276e-02 -6.000000e+00 2.185621e+00 228.10 -2.00 3.16 -2.00 501.80 0.00e+00 20.097 0.076 489.00 513.00 1 9.5423e+00 1.4240e-01 3.0940e-02 -6.0000e+00 1.6731e-01 1.0246e-01 3.6216e-02 1.8571e-03 -6.0000e+00 4.3830e-02 6.5605e-06 1.2923e-02 8.8371e-03 1.8246e-05 -6.0000e+00 1.0953e-02 2.7759e-02 -2.7347e-04 12 8 8 10 0 0 -23.32 21.49 -0.19 0.02776 0.11740 8 2 1 4 0 4000.000 25.58 20.00 21.49 3982 -1509 -6081 22621 -27965 14652 752 3755 -5151 11362 -3657 -20454 19866 -7659 1254 13613 2695 -192 -7854 5775 -12225 32011 -5042 16346 4906 -6333 13976 153 15025 -17250 -107 7765 -1818 16554 1445 25479 -6007 8841 6542 1815 6842 -6698 -582 -11475 -51 -3560 -2445 -1482 -8112 -1103 -3308 12632 27 1790 11373 -10688 -3907 -5905 8658 4249 9687 5172 7407 8713 -3955 16602 -1769 10091 3672 1226 29083 -4594 15999 10253 6868 -6650 -7246 19278 -20338 6255 -20334 -4435 -3816 5066 19215 -2501 5494 -13549 2330 864 8697 5589 -11091 18241 -5144 13452 -12397 26828 21942 2940 -11548 -10049 1787 -7370 11055 5991 2633 25999 -15625 3363 -9560 2838 25158 2456 680 1451 3230 -154 16961 -13326 4680 1939 -4257 3431 2086 -6041 -12423 5970 16 8437 -1909 297 -1026 -5976 24099 -6765 -76 -1691 -12958 5943 7475 6782 -6046 -633 3304 -9141 1622 -4949 -5415 709 399 25769 -11975 3769 -1557 -6788 19493 -40893 14252 850 4118 -6120 11274 -4154 -27106 17378 -8750 1310 12708 2868 -216 -9044 6258 -14823 26749 -5714 15039 5081 -7332 13114 162 13366 -20600 -106 7191 -1906 14928 1550 21579 -6917 8673 6498 1880 6753 -7631 -631 -14053 -56 -4078 -2756 -1634 -9391 -1162 -3467 11007 26 1723 10186 -12308 -4309 -6728 8546 4375 9444 5294 7446 8654 -4434 14971 -1887 9407 3603 1218 21619 -4758 13550 9308 6528 -7253 -7859 15740 -22770 5679 -22533 -4485 -3618 4722 15688 -2401 4896 -14628 2143 805 7502 5012 -11911 14796 -5289 11372 -13313 19003 15918 2519 -11213 -9529 1521 -7073 9156 5373 2467 19158 -17226 3035 -9829 2610 18826 2343 668 1426 3137 -156 14533 -15453 4491 1883 -4329 3195 1966 -6212 -13696 5490 16 7566 -1897 288 -1003 -6042 17758 -6724 -70 -1623 -14211 5499 6917 6392 -6527 -650 3284 -9730 1552 -5028 -5444 656 363 18010 -12297 SO 20180924T094955.0Z 6841.409664 301 1 32.01 2 88.92 89.89 93.08 260.92 0.00 1 0.00 1 0 15 5.829e-02 5.510e-02 6.473e-02 6.374e-02 2.869737e+03 3.958718e+03 1.415221e+02 -6.000000e+00 3.189553e+03 282.91 -2.00 20.00 -2.00 505.24 0.00e+00 -8.119729e-04 1.715788e-03 4.259571e-05 -6.000000e+00 1.614706e-03 282.91 -2.00 20.00 -2.00 500.18 0.00e+00 8.339611e-01 1.264725e+00 3.504118e-02 -6.000000e+00 1.137343e+00 228.10 -2.00 3.16 -2.00 501.79 0.00e+00 18.448 0.059 489.00 513.00 1 9.5201e+00 9.6215e-02 2.7911e-02 -6.0000e+00 8.7189e-02 1.0830e-01 2.5306e-02 1.6535e-03 -6.0000e+00 2.2619e-02 9.7629e-06 -4.5646e-03 6.0454e-03 1.5498e-05 -6.0000e+00 5.7186e-03 -1.0758e-02 4.9552e-04 12 8 8 10 0 0 -14.69 21.48 8.17 -0.01076 -0.04242 8 2 1 4 0 4000.000 25.58 20.01 21.48 4468 3242 742 -4163 7959 2418 -104 2873 -6710 6235 5225 137 -2755 4173 -6929 -4262 -2367 4326 -4001 6973 -4343 -2033 -5225 3019 -2364 -4965 3526 -3078 2845 2827 -1706 12326 830 3754 2974 1002 3707 1810 -229 10740 -2260 -4210 -8154 -2337 -1010 -3940 -513 -1941 5921 -3081 -2272 1981 -3833 -3347 -8929 -1185 798 2518 3856 -3003 6832 -6387 2118 -7876 6212 4441 5922 1406 -3583 -661 -2169 13244 -3051 -1919 15582 -438 -7720 -1023 6824 6243 162 5810 -8667 -3355 8960 -2380 218 1588 551 -263 8852 -6501 4997 -5230 -1165 219 4305 1280 -8703 342 -9157 14513 18764 5579 2775 -13367 1859 3318 -1156 -1769 -1536 -8207 -313 -843 -102 7021 -4173 4362 4473 692 -1888 6907 -3889 -1009 -771 4426 6185 -9999 4663 -812 9812 35 16005 -8380 -11158 -10900 -896 1825 1315 -629 -5082 -4527 5653 -1575 3217 3783 5667 15868 7012 -645 3075 -8877 -246 4187 3154 765 -4645 8063 2644 -118 3193 -8175 6594 5503 150 -3061 4283 -7389 -4456 -2475 4342 -4466 7058 -4939 -2261 -6007 3207 -2659 -5729 3716 -3423 2915 2814 -1741 10936 844 3831 3147 1094 3922 1930 -247 10244 -2448 -4665 -9477 -2589 -1114 -4497 -564 -2142 5943 -3311 -2356 1915 -3848 -3332 -9559 -1209 821 2590 3935 -3277 6744 -7210 2205 -9087 6210 4477 5797 1417 -3747 -664 -2186 11364 -2895 -1821 13435 -420 -7899 -963 5836 5314 146 4969 -8630 -3197 7628 -2295 207 1494 525 -253 7777 -6703 4645 -5453 -1174 217 4018 1204 -8837 310 -8940 11051 13776 4793 2547 -14928 1815 3187 -1147 -1741 -1499 -8621 -308 -846 -103 6635 -4432 4275 4402 708 -1969 6500 -4010 -997 -755 4130 5700 -10216 4113 -755 8186 32 12471 -8223 -11072 -10656 -790 1583 1169 -583 -5006 -4492 5111 -1539 3015 3545 5228 13181 6288 -611 2747 -8809 -224 SO 20180924T095400.0Z 6841.412500 305 1 32.01 2 88.08 89.31 93.89 260.36 0.00 1 0.00 1 0 15 2.444e-02 2.416e-02 1.939e-02 1.930e-02 6.865920e+03 1.283300e+03 4.849937e+02 -6.000000e+00 1.336889e+03 282.91 -2.00 20.00 -2.00 505.41 0.00e+00 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