File name: Pandora114s1_BuenosAires_20181015_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T045015.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20181015_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20181015 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181015T091718.0Z 6862.387014 386 1 32.00 2 89.75 100.24 124.64 172.01 0.00 1 0.00 1 0 29 2.785e-01 2.184e-01 2.640e-01 2.316e-01 -2.852686e+03 1.318663e+04 3.742637e+02 -6.000000e+00 1.528721e+04 283.81 -2.00 20.00 -2.00 505.38 0.00e+00 -3.069223e-03 6.295355e-03 2.660828e-04 -6.000000e+00 7.740525e-03 283.81 -2.00 20.00 -2.00 500.33 0.00e+00 4.992674e+00 4.510632e+00 1.639330e-01 -6.000000e+00 5.476075e+00 228.57 -2.00 3.16 -2.00 502.00 0.00e+00 20.077 0.076 489.00 513.00 1 1.0308e+01 3.4651e-01 3.3577e-02 -6.0000e+00 4.1931e-01 1.4401e-03 8.8859e-02 2.8192e-03 -6.0000e+00 1.0983e-01 2.5162e-06 1.6531e-02 2.2225e-02 1.0359e-04 -6.0000e+00 2.7442e-02 -5.8235e-02 2.3760e-04 12 8 8 10 0 0 83.02 21.69 20.88 -0.05823 0.05643 8 2 1 4 0 4000.000 25.79 20.01 21.69 -9013 31666 10918 19312 7718 11444 12742 -855 9288 -3937 -32376 23610 30681 11248 -31201 60929 43532 15395 74225 -1281 -20732 4951 -13199 -2640 30426 5639 10867 29674 9829 24586 12980 48207 -21590 -25948 5636 -14619 9553 -21197 30561 -13816 -11453 22901 34854 -85 -18171 6123 12873 -1717 24640 -33620 5536 34366 20746 23287 52539 -8547 14655 15660 1677 41883 -16068 -17024 -13042 22590 10143 -7239 63188 -18186 42633 -23086 14040 -16788 -3479 -12019 17131 -2135 47215 25530 4215 -12940 5421 20414 17572 1552 25356 -14753 14432 52143 22512 -9987 -5292 40451 2637 16328 39120 62077 4271 -27971 29840 -23041 45725 42918 12189 10206 -7058 20788 -630 8373 -14046 42324 -7370 11492 -376 -33909 70647 -6977 8665 -24364 -14342 52141 -27009 12215 46423 52892 20995 -17696 3377 -21568 -4586 -15793 8170 31707 29285 11011 6552 50962 -22554 -19567 16883 55833 -13950 660 16909 32328 -3091 -10345 36477 9601 43995 30695 -17972 103001 -9465 -9355 22596 9916 16599 7635 11136 12399 -957 9339 -4470 -48307 19911 23883 10580 -45036 35572 31064 14981 40928 -1516 -29925 5541 -17767 -3211 26646 6310 11456 25506 10042 21133 12420 32836 -28431 -36919 5972 -19030 9689 -28877 26268 -17148 -13868 19759 26906 -94 -24205 6395 12470 -1897 20513 -48853 5279 23929 16329 17976 31015 -9573 13310 14222 1751 29162 -19943 -21388 -15792 19148 9672 -8108 34432 -22021 27749 -28654 11901 -19313 -3529 -13462 14521 -2198 29302 19322 3892 -14102 4924 16068 14363 1504 19574 -17195 12671 31570 18401 -11338 -5767 28165 2715 14829 28423 35706 4331 -36120 22584 -27138 28377 27284 10032 8835 -7512 17110 -644 7724 -15946 27027 -7739 10111 -378 -48600 36091 -7821 8361 -32845 -17503 32556 -36794 11093 29645 31524 17280 -21596 3354 -27545 -4946 -19049 7768 23847 22441 10000 6137 30374 -28165 -24156 14854 34069 -17421 721 15836 26149 -3597 -13065 28988 9946 31840 24828 -23208 39464 -11283 SO 20181015T092118.1Z 6862.389792 390 1 32.12 2 88.94 99.67 124.52 170.94 0.00 1 0.00 1 0 29 3.214e-02 3.140e-02 3.150e-02 3.127e-02 1.758865e+04 2.295640e+03 1.179702e+03 -6.000000e+00 1.764377e+03 283.81 -2.00 20.00 -2.00 505.49 0.00e+00 4.972111e-03 8.660772e-04 2.591470e-04 -6.000000e+00 8.925585e-04 283.81 -2.00 20.00 -2.00 501.02 0.00e+00 1.293111e+00 6.014872e-01 1.164705e-01 -6.000000e+00 6.292178e-01 228.57 -2.00 3.16 -2.00 502.53 0.00e+00 18.468 0.059 489.00 513.00 1 8.6506e+00 4.6276e-02 3.0141e-02 -6.0000e+00 4.8221e-02 -2.0578e-02 1.1315e-02 3.2408e-03 -6.0000e+00 1.2562e-02 2.0306e-05 7.0545e-03 2.7602e-03 1.4445e-04 -6.0000e+00 3.1608e-03 2.1635e-02 6.8266e-05 12 8 8 10 0 0 85.56 21.68 5.89 0.02163 0.07057 8 2 1 4 0 4000.000 25.79 20.03 21.68 -5425 -424 4578 -3322 -2139 -2270 2674 1300 2596 6295 -3687 -647 -2808 -3702 -2080 -2373 -1411 -4080 5336 1985 4374 475 2316 6362 -1166 4099 -255 -492 -4840 -3009 -1119 -211 3019 -1693 287 -1459 -1245 5692 1037 -3824 4215 -2693 1037 3657 5343 -1672 542 1294 5473 -1192 -1947 -2166 -4389 -310 -4177 888 5931 -2486 5289 3636 -4376 1339 4468 131 4030 2413 -1097 -7019 2423 1772 -2646 -71 -1402 -4229 -1651 -3775 6273 -1289 -4962 -2796 -3145 -237 530 202 -3282 -1401 5688 2220 1046 -1985 5603 2330 1000 -1546 193 -503 -3462 975 5898 -4718 4825 -6612 -2353 -1169 -2847 2625 1020 -2789 2396 23 -2018 -6552 2483 2958 -2137 185 -374 -254 6234 -1207 4930 -234 -202 953 -1087 1387 -304 9597 2295 5005 -573 219 4809 -413 -3091 -1507 -4436 897 2861 2569 1984 732 -1196 -379 -2397 407 1261 -1539 -2478 -1637 188 -1115 -2771 -4755 -366 3891 -3150 -2055 -2227 2524 1246 2435 5608 -3579 -602 -2639 -3487 -1929 -2235 -1346 -4102 4972 1926 4156 471 2267 6031 -1201 4012 -260 -494 -4954 -2945 -1063 -201 2868 -1747 297 -1547 -1310 5536 1049 -4055 4151 -2877 1084 3789 5168 -1746 552 1296 5524 -1181 -1895 -2066 -4237 -290 -4169 871 5680 -2629 5198 3636 -4752 1383 4502 138 4076 2455 -1139 -7624 2367 1724 -2667 -70 -1399 -4399 -1695 -3970 5900 -1284 -5047 -2759 -3102 -227 508 196 -3332 -1412 5372 2169 1028 -1997 5216 2259 996 -1597 195 -499 -3415 887 4959 -4320 3956 -6054 -2100 -1072 -2633 2404 973 -2775 2250 22 -1983 -6840 2408 2891 -2211 188 -384 -264 6182 -1303 4995 -246 -208 953 -1106 1385 -312 8980 2321 4936 -599 227 4717 -421 -3198 -1532 -4686 915 2924 2681 2118 804 -1356 -431 -2796 463 1421 -1773 -2846 -1833 204 -1220 -3117 SO 20181015T092523.1Z 6862.392628 394 1 32.12 2 88.11 99.10 124.39 169.84 0.00 1 0.00 1 0 29 1.004e-02 9.866e-03 6.681e-03 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