File name: Pandora114s1_BuenosAires_20181023_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T045335.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20181023_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20181023 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181023T090736.0Z 6870.380278 277 1 32.01 2 89.75 103.76 96.07 267.77 0.00 1 0.00 1 0 61 1.538e-01 1.337e-01 1.363e-01 1.289e-01 -1.332941e+04 7.548850e+03 7.701001e+02 -6.000000e+00 8.454975e+03 284.21 -2.00 20.00 -2.00 505.26 0.00e+00 -2.860143e-04 3.582059e-03 1.019529e-04 -6.000000e+00 4.275183e-03 284.21 -2.00 20.00 -2.00 499.95 0.00e+00 6.272417e+00 2.657294e+00 5.285116e-02 -6.000000e+00 3.011422e+00 228.69 -2.00 3.16 -2.00 501.64 0.00e+00 20.068 0.076 489.00 513.00 1 9.6424e+00 2.0483e-01 3.1149e-02 -6.0000e+00 2.3080e-01 6.0545e-02 5.2063e-02 2.2189e-03 -6.0000e+00 6.0144e-02 4.6032e-06 -1.4948e-02 1.1840e-02 8.8718e-05 -6.0000e+00 1.5127e-02 2.1050e-02 4.9749e-05 12 8 8 10 0 0 96.72 21.32 11.33 0.02105 -0.08264 8 2 1 4 0 4000.000 25.47 19.98 21.32 17414 -9845 18984 -16752 2629 965 -9162 -4808 -3538 23298 -11701 -3548 -3277 5377 -12880 7776 21019 -9402 1651 -1537 -7004 -1637 -2242 11312 6796 25553 -6351 -8337 9281 3625 -887 11724 17617 -16386 6255 2538 -1090 5185 7162 7484 5694 14842 5721 -12813 4243 4265 24473 -621 21765 1713 -668 -5932 4383 -34914 12229 48708 -7574 14430 6065 25910 -10434 -6398 -4116 13 -789 8681 32225 2341 19150 10721 -10470 3332 2423 4305 -10950 16201 9846 -24640 26011 -9512 -4514 5423 5894 -16447 -17341 14795 -1611 -6928 14446 8081 -5483 3771 -7872 -16298 -9446 6880 18422 60420 -1962 10230 -12009 22692 4286 -2042 -21256 -6321 30950 -23380 5927 -5085 53736 -3132 31360 20943 2502 14116 -11651 6627 17595 -6503 10050 3974 22248 18440 16435 -5037 -2575 6377 -1868 7461 -1852 31437 -2261 -10860 -5047 3987 2171 -11893 17017 -6842 15609 9276 -500 18160 -26252 -116 -10279 14352 -9301 13203 -17114 -11344 32878 14462 -10842 16108 -21018 2800 1071 -11495 -5858 -4279 21451 -15103 -4163 -3787 5630 -16044 7861 18783 -11628 1878 -1845 -8977 -1995 -2753 12151 7157 22389 -7652 -10185 9383 3787 -942 10766 15287 -20432 6430 2780 -1248 5548 7422 7629 5853 13880 5880 -15976 4504 4564 21443 -696 19254 1818 -709 -6447 4173 -48240 10509 29545 -8296 13008 6029 21174 -12219 -7169 -4508 14 -838 8338 24163 2327 15811 9484 -11291 3088 2245 3917 -11716 13376 8709 -30516 19065 -9777 -4373 4752 5164 -18152 -19430 12091 -1561 -6676 12049 7216 -5283 3558 -7896 -18021 -9923 6249 15132 35123 -1999 9130 -13090 17027 3792 -1919 -24512 -6390 21756 -28069 5196 -4860 28012 -2869 20559 15549 2292 11818 -12883 6177 14731 -6882 8890 3672 16870 14419 13110 -5013 -2522 5742 -1830 6659 -1813 22099 -2232 -11666 -5063 3590 1954 -12211 13172 -6863 12821 8279 -497 15060 -34004 -117 -11529 12696 -9818 11679 -18828 -11469 22333 SO 20181023T091138.0Z 6870.383079 281 1 32.00 2 88.94 103.19 96.88 267.23 0.00 1 0.00 1 0 29 1.304e-01 1.212e-01 1.371e-01 1.310e-01 2.462862e+03 8.572334e+03 6.483359e+02 -6.000000e+00 7.171796e+03 284.21 -2.00 20.00 -2.00 505.33 0.00e+00 3.095505e-03 3.600780e-03 2.804874e-04 -6.000000e+00 3.623892e-03 284.21 -2.00 20.00 -2.00 500.05 0.00e+00 5.662089e+00 2.644994e+00 1.011242e-01 -6.000000e+00 2.543015e+00 228.69 -2.00 3.16 -2.00 501.69 0.00e+00 18.473 0.059 489.00 513.00 1 9.8541e+00 2.0414e-01 2.9458e-02 -6.0000e+00 1.9505e-01 2.9126e-02 5.0977e-02 1.9154e-03 -6.0000e+00 5.0555e-02 4.5370e-06 2.2085e-03 1.2600e-02 1.3233e-04 -6.0000e+00 1.2792e-02 -2.1339e-02 5.9764e-04 12 8 8 10 0 0 77.49 21.31 5.49 -0.02134 -0.00602 8 2 1 4 0 4000.000 25.47 20.00 21.31 -1775 4181 -3856 3303 17673 -10640 -10273 8794 23925 -6554 -62 20727 5203 14787 9049 8394 11546 15001 -1915 -5784 -1060 -6899 9290 -12902 7055 -9003 -5346 6399 -8147 9703 -3614 14110 968 -8017 3240 -3287 11950 -18457 -3339 6624 6022 8559 3141 33952 -14277 8755 -4237 -17246 -2170 23628 21789 475 1680 -18368 13683 683 -9338 8274 -24200 8045 30874 -10485 9322 21135 18484 5423 5358 -20040 -9984 -5875 -3868 -3660 -4999 31359 -3774 -7016 3380 -2160 9009 1454 30840 15083 16588 13972 -13861 -14729 -3914 -5627 -4235 -5388 -7740 -3647 -15794 -237 11875 4459 19291 1291 34479 2946 -25441 5949 -16810 17148 10020 -9850 9124 7265 7795 -3259 33751 -2343 -449 -5396 -8777 -2234 -11605 3404 3901 4619 6280 9366 18778 -12028 18246 -21149 10905 7605 31295 13506 -650 4520 1279 6066 -5673 12481 -950 15555 20869 8539 16633 -18488 -13628 12839 4178 -14352 -7879 1336 -1767 -5495 21655 13301 7113 -1791 4104 -4244 3484 16536 -13469 -13099 9277 21509 -7876 -69 18443 5346 13700 8882 8393 11439 14724 -2266 -7162 -1254 -8671 9971 -16238 7309 -10946 -6225 6520 -9347 9055 -3806 12564 1011 -9472 3495 -3799 11766 -24336 -3745 6692 6135 8574 3361 27034 -18580 9070 -4970 -22739 -2416 19825 18096 476 1640 -22016 12183 713 -11033 8288 -33566 8059 24583 -12658 9258 18638 16617 5479 5321 -25222 -11198 -6237 -3974 -3729 -5179 22822 -3942 -7569 3241 -2145 7868 1357 21387 12268 13350 11604 -15309 -15487 -3954 -5781 -4278 -5490 -7580 -3454 -17114 -223 9913 3973 14555 1140 22730 2435 -27363 4631 -16597 12387 8043 -9883 7617 6123 6445 -2982 21402 -2163 -415 -5327 -9088 -2188 -12575 3197 3663 4300 5696 8119 14620 -12647 14206 -24615 9278 6714 21854 11275 -626 4136 1201 5356 -5555 10118 -884 12485 16248 7676 14018 -22408 -15861 11542 4125 -17165 -8854 1362 -1830 -5438 17034 11317 6126 SO 20181023T091543.0Z 6870.385914 285 1 32.00 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