File name: Pandora114s1_BuenosAires_20181029_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T051407.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20181029_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20181029 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181029T090101.0Z 6876.375706 268 1 32.00 2 89.75 106.27 59.28 339.81 0.00 1 0.00 1 0 22 1.250e-01 1.166e-01 1.015e-01 9.725e-02 9.441696e+03 6.992589e+03 8.099810e+02 -6.000000e+00 6.876788e+03 284.52 -2.00 20.00 -2.00 505.23 0.00e+00 1.945146e-03 2.661112e-03 5.514289e-05 -6.000000e+00 3.474984e-03 284.52 -2.00 20.00 -2.00 499.87 0.00e+00 7.570378e-01 1.950147e+00 4.628853e-02 -6.000000e+00 2.443002e+00 228.78 -2.00 3.16 -2.00 501.53 0.00e+00 20.061 0.076 489.00 513.00 1 9.6927e+00 1.4951e-01 3.0996e-02 -6.0000e+00 1.8729e-01 1.4991e-01 3.7791e-02 2.1695e-03 -6.0000e+00 4.8734e-02 6.1476e-06 3.1555e-02 9.1212e-03 5.7412e-05 -6.0000e+00 1.2278e-02 7.6467e-02 -2.0819e-04 12 8 8 10 0 0 -30.84 22.21 9.22 0.07647 0.29534 8 2 1 4 0 4000.000 26.21 20.00 22.21 15730 6281 -13870 3801 -5210 19189 -873 1233 2027 -4187 -7280 -19140 660 12452 3571 15228 -8628 4846 345 -7900 7029 3219 -1503 -14032 9245 5539 17609 38344 -1942 -17227 1272 6427 -12207 9697 13743 9404 -9203 -582 -730 -12315 22229 3164 13541 7160 15821 4159 -7619 19349 -15141 -2683 -17785 9403 -2726 -17187 7414 -13678 18393 -11720 17392 7678 4420 9013 4399 -163 -12220 18088 11700 -6 17159 -3859 7843 -10447 8750 6137 4812 10453 -763 -2644 -1278 -10512 -8281 3814 -9049 3759 -4254 -5787 15735 -8220 16501 -6928 12099 1353 1088 8335 -6800 171 -7298 17475 -8690 1758 7480 -181 22998 650 3080 -5769 4489 687 -13507 34108 13168 19597 -17286 15076 19771 -16393 11405 -5203 -4386 -16591 12479 3256 -7572 -5058 -20071 7340 2164 26629 -1964 6877 11833 -8992 19281 -3819 22905 2324 22572 15241 -24742 593 -13305 6680 -11043 29868 -3373 911 3408 -12083 17879 9201 27820 12101 -17631 14565 6586 -18227 4270 -6491 18814 -1040 1419 2277 -4932 -8724 -25542 719 12123 3866 15034 -10308 5112 381 -9488 7281 3478 -1710 -18101 9400 5773 15890 27291 -2024 -20910 1309 6494 -15282 9860 13362 9442 -10995 -632 -794 -15104 19494 3398 13252 7508 15181 4440 -9006 17091 -18377 -2797 -21135 8485 -2823 -21189 7350 -17036 16714 -14374 15915 7758 4635 9050 4613 -177 -14755 15863 10780 -7 14612 -4021 7277 -11751 8230 5967 4709 9499 -761 -2655 -1259 -10646 -8239 3386 -9219 3404 -4207 -5826 12749 -8423 13173 -7017 10236 1289 1043 7349 -6806 155 -6913 12597 -7973 1435 5793 -156 16305 600 2844 -5843 4065 639 -14404 22759 10983 15528 -19979 12664 15901 -19045 10124 -5487 -4573 -19275 10632 2987 -7669 -5002 -23198 6472 2011 19354 -1896 6064 9870 -9108 14473 -3572 16375 2063 16675 12349 -28579 572 -14025 6168 -11517 22065 -3272 843 3038 -12331 13233 7326 18407 9499 -18982 SO 20181029T090508.0Z 6876.378565 272 1 32.01 2 88.94 105.69 59.57 338.79 0.00 1 0.00 1 0 22 8.705e-02 8.215e-02 7.076e-02 6.869e-02 5.743922e+03 4.725409e+03 2.685555e+02 -6.000000e+00 4.791571e+03 284.52 -2.00 20.00 -2.00 505.26 0.00e+00 1.180637e-03 1.871416e-03 5.265805e-05 -6.000000e+00 2.421793e-03 284.52 -2.00 20.00 -2.00 499.90 0.00e+00 2.684998e+00 1.403240e+00 6.578711e-02 -6.000000e+00 1.704399e+00 228.78 -2.00 3.16 -2.00 501.55 0.00e+00 18.450 0.059 489.00 513.00 1 9.4474e+00 1.0772e-01 2.8225e-02 -6.0000e+00 1.3065e-01 9.4126e-02 2.7519e-02 1.9679e-03 -6.0000e+00 3.4037e-02 8.8187e-06 -1.1272e-03 6.4087e-03 2.1312e-05 -6.0000e+00 8.5626e-03 -1.4380e-02 2.7283e-04 12 9 8 11 8 0 -74.97 22.21 0.21 -0.01438 -0.02220 8 2 1 4 0 4000.000 26.21 20.00 22.21 -14302 18832 -15732 3612 -4573 7807 -16705 6844 14192 978 10987 -1096 11125 4426 -3125 -453 -10614 11448 3483 7286 -1124 11684 2341 4394 -1632 -3078 2426 -13163 -2098 -2162 -5267 1787 -12712 5142 4221 -5610 -7037 7 3712 2761 -1259 -874 7652 -2065 11605 -3223 919 13702 2036 11362 -4473 -4000 414 6852 14796 2294 5555 5151 2309 4285 1892 -4550 2358 909 -185 -3994 -9057 -193 -9536 -4263 8571 2886 7103 -3055 4050 -12463 -2830 4417 -2090 -2051 -3078 10997 -323 4116 6401 -12079 38740 96 14994 -16018 7496 14394 -2592 389 -11794 20773 -1596 5072 -12833 8426 20378 -9818 9359 -1275 1031 -2976 7984 12646 -5881 -2003 -5644 6887 -6562 7382 6650 -8504 9286 -10915 9677 -11251 5633 12268 -5976 13978 -7025 13474 -2753 -1922 -8888 5351 9970 7030 8066 -543 -2588 -13901 507 -4379 -5873 6486 1855 6845 -868 1956 -6422 1421 -5949 -12938 -1604 -3921 9373 14841 1015 -16646 16121 -19672 3839 -5410 8335 -23138 7537 14470 1125 11255 -1249 11075 4661 -3296 -467 -12339 10945 3690 7522 -1267 11590 2554 4714 -1868 -3579 2657 -16662 -2326 -2330 -5721 1805 -15121 5286 4510 -6698 -8497 8 3932 2925 -1384 -962 7797 -2345 11617 -3761 1028 13347 2194 10914 -4899 -4237 411 6336 12818 2317 5585 5295 2457 4463 2013 -5168 2508 983 -202 -4482 -10530 -202 -10786 -4516 7887 2785 6568 -2957 3945 -13531 -2775 3959 -1961 -1899 -2862 8885 -294 3603 5522 -12657 24617 90 12115 -17593 6498 11690 -2520 371 -12805 16172 -1525 4418 -13015 6737 14150 -9090 7168 -1110 911 -2843 6988 10590 -5865 -1897 -5510 5970 -6600 6555 6017 -9018 8284 -11988 8715 -12547 5286 10635 -6110 11529 -7095 11113 -2688 -1868 -8730 4841 8601 5875 6645 -482 -2306 -13709 432 -3954 -5490 5471 1668 5937 -821 1813 -6511 1339 -6055 -14092 -1544 -3789 7759 11462 900 SO 20181029T090910.0Z 6876.381366 276 1 32.00 2 88.14 105.12 59.87 337.79 0.00 1 0.00 1 0 15 5.999e-02 5.798e-02 5.432e-02 5.307e-02 2.800402e+03 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