File name: Pandora114s1_BuenosAires_20190208_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T054132.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190208_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190208 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190208T092650.0Z 6978.393634 367 1 32.01 2 89.76 108.17 124.70 126.66 0.00 1 0.00 1 0 29 1.471e-01 1.373e-01 1.330e-01 1.260e-01 -3.124599e+03 7.573961e+03 1.419647e+02 -6.000000e+00 8.231737e+03 288.83 -2.00 20.00 -2.00 505.24 0.00e+00 3.494970e-03 3.440556e-03 9.215028e-05 -6.000000e+00 4.139743e-03 288.83 -2.00 20.00 -2.00 499.81 0.00e+00 4.009935e+00 2.536955e+00 1.238363e-01 -6.000000e+00 2.886507e+00 229.69 -2.00 3.16 -2.00 501.49 0.00e+00 19.943 0.074 489.00 513.00 1 9.9581e+00 1.9479e-01 3.1846e-02 -6.0000e+00 2.2145e-01 1.0849e-01 4.9634e-02 2.4914e-03 -6.0000e+00 5.7894e-02 3.7574e-06 2.3203e-02 1.2098e-02 5.1473e-05 -6.0000e+00 1.4493e-02 7.9356e-03 -4.5446e-04 12 8 8 10 0 0 -3.25 23.09 16.96 0.00794 0.16888 8 2 1 4 0 4000.000 26.94 20.00 23.09 900000 -7807 38479 -11046 4918 -10810 -365 5268 -13267 4683 22259 -13815 -6634 839 2079 7810 7914 -16287 17551 -4588 10864 -10566 929 9190 1210 -13806 -4291 5556 7126 19113 21996 -5621 19457 19020 12042 8852 -5865 901 -6851 -8318 12589 1840 -5189 3411 20147 -277 -14115 -2396 8141 26587 -6934 -14732 14256 6691 -32993 9584 18508 1511 -7639 21137 -7400 2339 10748 -10961 -5152 5105 8410 -16677 13048 15408 -7300 -8234 -3523 -12636 17029 49242 27941 22888 15957 5345 6805 6962 36200 774 3052 1917 -14254 -835 7823 19251 8777 6718 28750 9587 2282 -11135 35885 -6323 9214 -12974 7965 -8731 3183 274 25395 -23778 6343 5245 -7379 15303 10089 2873 -18050 -27819 16274 1923 448 20140 5929 4620 -29908 13375 -13884 16991 1584 3925 -4407 15724 -791 -23781 34597 9406 -335 10521 -14813 18913 7539 15989 24051 -7793 -3030 20801 15681 14151 5885 1636 522 -2764 8013 5699 -23637 -1695 -21629 7852 900000 -8884 28512 -13836 5380 -14112 -434 5948 -17906 5205 20420 -17914 -7901 917 2237 7992 8238 -22125 17339 -5707 11596 -13049 1098 10053 1344 -17845 -5017 5810 7158 16523 18109 -6109 16820 17068 11897 9110 -6953 987 -8009 -9793 12023 1969 -6024 3679 18578 -314 -18361 -2742 8244 21889 -7764 -17344 12324 6225 -46450 9074 16457 1617 -8994 18620 -8651 2485 10530 -13356 -5896 5211 8171 -20458 11709 13320 -7813 -8813 -3597 -14252 14441 30406 21164 17902 13137 4841 6051 6191 24141 740 2865 1831 -15072 -774 6642 15533 7384 5808 21539 8288 2149 -12033 24097 -6393 7823 -13419 6517 -8289 2678 241 17837 -27897 5532 4575 -7176 11694 8099 2506 -19784 -34355 13189 1825 435 16167 5491 4315 -39013 11150 -15003 13377 1455 3545 -4354 12743 -757 -28634 23233 8131 -318 8851 -15778 14160 6285 12341 17450 -7940 -2994 16377 13071 12015 5450 1591 516 -2817 7236 5147 -26272 -1490 -23254 6388 SO 20190208T093049.0Z 6978.396400 371 1 32.00 2 88.98 107.61 124.08 125.79 0.00 1 0.00 1 0 22 8.449e-02 8.120e-02 7.223e-02 7.033e-02 8.224311e+01 4.141497e+03 4.410926e+01 -6.000000e+00 4.725877e+03 288.83 -2.00 20.00 -2.00 505.18 0.00e+00 5.951304e-03 1.929643e-03 2.720867e-04 -6.000000e+00 2.377087e-03 288.83 -2.00 20.00 -2.00 499.85 0.00e+00 3.119372e+00 1.404653e+00 4.761865e-02 -6.000000e+00 1.658563e+00 229.69 -2.00 3.16 -2.00 501.48 0.00e+00 18.448 0.059 489.00 513.00 1 9.6072e+00 1.0760e-01 2.8635e-02 -6.0000e+00 1.2722e-01 1.0358e-01 2.8217e-02 1.6360e-03 -6.0000e+00 3.3301e-02 6.8968e-06 9.7639e-03 6.6896e-03 1.0664e-04 -6.0000e+00 8.3249e-03 4.2792e-02 -7.3345e-04 12 8 8 10 0 0 31.29 23.10 2.98 0.04279 0.11052 8 2 1 4 0 4000.000 26.94 20.00 23.10 900000 -4854 443 -6314 14965 -5248 6302 -5987 463 6792 9226 9871 -2911 8423 -2677 5201 -431 -9117 14003 -4707 15350 2587 10215 -415 10716 -6760 7785 3723 -19648 3538 7450 -14158 -2921 -442 5982 -5471 -442 5208 4036 -4994 -1788 632 -4619 -2863 -8807 -3830 11752 1549 -5892 2534 8250 -10207 2039 -9931 8243 5528 -2125 6999 -8130 13852 -2866 -5733 9263 -6189 8872 -5054 11260 -8329 11203 59 3645 1403 576 8265 -669 1301 -1508 -3872 9578 -9204 -2720 -5346 9143 -7936 3442 1555 -9043 -10793 -4855 8982 -1893 5228 4477 8810 -1205 2100 10990 -14421 23034 -2534 -4148 9734 -12742 2336 1117 24012 -3289 -16 -3717 -5260 -393 -17362 14274 -3322 6727 680 -14427 6521 4369 16608 -40 16828 3207 11376 -7429 -40 12126 -457 -1839 -10843 -7622 -3853 9873 3626 -4913 2343 -4544 15810 -12593 -839 -3784 -10546 15615 185 21716 9970 -2470 1625 -2636 1487 -7314 16184 5652 -1904 900000 -5258 469 -7399 14589 -6409 6982 -7576 549 7491 9767 10207 -3144 8585 -2818 5043 -445 -10474 13064 -5386 14461 2770 10139 -460 10686 -8077 8050 3986 -26185 3642 7155 -16591 -3074 -465 6103 -6411 -496 5481 4247 -5691 -1964 680 -5286 -3262 -10806 -4524 11936 1737 -7040 2737 8228 -11915 2052 -11090 7690 5411 -2315 7140 -9788 13431 -3280 -6744 9408 -6906 9092 -5553 11074 -9186 10657 58 3408 1324 543 7229 -646 1244 -1487 -3870 8211 -9358 -2566 -5159 7642 -7898 3070 1420 -9234 -11253 -4769 7662 -1794 4617 4012 7667 -1178 2009 9611 -16092 17367 -2413 -3914 7800 -12572 1983 977 17173 -3160 -15 -3571 -5053 -356 -18625 11315 -3206 6000 657 -16410 6068 4179 14096 -40 14065 3026 9753 -7618 -38 10292 -417 -1708 -11036 -7511 -3656 8167 3176 -4622 2014 -4127 11668 -12459 -752 -3559 -10776 12410 173 16379 8490 -2393 1516 -2555 1362 -7147 12206 4675 -1706 SO 20190208T093452.0Z 6978.399213 375 1 32.00 2 88.18 107.04 123.43 124.92 0.00 1 0.00 1 0 22 5.230e-02 5.048e-02 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