File name: Pandora114s1_BuenosAires_20190217_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T054136.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190217_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190217 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190217T093534.0Z 6987.399699 287 1 32.01 2 89.76 104.47 121.83 275.29 0.00 1 0.00 1 0 22 8.470e-02 8.059e-02 7.596e-02 7.392e-02 -6.119716e+02 4.430429e+03 1.922025e+02 -6.000000e+00 4.741586e+03 288.84 -2.00 20.00 -2.00 505.20 0.00e+00 1.575574e-03 2.054304e-03 2.553800e-05 -6.000000e+00 2.384448e-03 288.84 -2.00 20.00 -2.00 499.85 0.00e+00 1.941519e+00 1.507411e+00 4.183577e-02 -6.000000e+00 1.660736e+00 229.46 -2.00 3.16 -2.00 501.51 0.00e+00 19.942 0.074 489.00 513.00 1 9.5956e+00 1.1568e-01 3.0568e-02 -6.0000e+00 1.2744e-01 1.4356e-01 3.0206e-02 1.7460e-03 -6.0000e+00 3.3261e-02 6.5631e-06 -9.6669e-03 7.0123e-03 2.5741e-05 -6.0000e+00 8.3507e-03 -1.0136e-01 9.8121e-04 12 8 8 10 0 0 -17.62 22.65 6.14 -0.10136 -0.16841 8 2 1 4 0 4000.000 26.62 20.00 22.65 -11886 11885 -9280 500 8892 -9574 -345 -7424 11669 -5466 1794 -9653 3342 5818 -5076 5716 -905 9041 -7230 -846 -11692 -911 18985 18062 8574 -8236 -5010 -2674 3467 -3752 -5462 10543 2470 5968 -2322 2628 17016 104 14856 -9433 26844 -8905 6563 -1589 1298 -2027 980 2000 -6298 -12769 -747 -3063 5611 8294 3288 -5628 5862 11098 6310 7241 -2577 5380 -6092 -7392 3266 -721 10494 17853 -960 7818 6538 -7673 -1030 -6609 5521 3281 4420 -226 -10255 6294 -13526 -6581 482 7866 2760 14855 -6276 -2332 5369 938 9524 5535 -11109 5869 984 9281 -471 16088 -2264 7427 2423 -1901 2228 -9536 -6583 5427 -7701 3977 -4837 5637 -5575 5331 17806 837 9679 -4632 1000 -12189 10368 11592 -4712 -6597 -999 4187 -13291 -74 -2931 -5624 5497 12767 3300 -2140 5543 1042 -5995 19477 6126 21863 -7431 -2226 -16166 442 -343 2167 -9151 142 -5599 -10383 19970 -8338 -8489 7299 10160 900000 -13656 10826 -10710 541 9111 -12090 -405 -9490 12380 -6846 2062 -12240 3666 6143 -5517 5550 -944 8691 -8382 -940 -14627 -1025 17515 16838 8822 -10065 -5929 -3074 3701 -4205 -6042 9727 2469 5880 -2569 2844 16110 116 14137 -11299 22173 -10495 6657 -1765 1417 -2311 1089 2193 -7422 -15790 -801 -3270 5339 7532 3129 -5953 5691 10507 6371 7275 -2851 5483 -6974 -8606 3424 -784 10087 15695 -1002 7364 6158 -8228 -1025 -6959 5200 3202 4024 -214 -10541 5387 -13966 -6318 432 6590 2450 11772 -6196 -2228 4765 871 8108 4913 -11721 5288 945 8280 -463 13259 -2205 6424 2150 -1721 1907 -9198 -6290 4744 -7881 3656 -4819 4978 -5428 4635 13788 781 8415 -4719 974 -13633 9296 10289 -4908 -6931 -977 3830 -14324 -69 -2854 -5654 4954 10696 3034 -1952 4677 915 -5570 14641 5188 15742 -6810 -1974 -16812 396 -313 1939 -9204 131 -5489 -10709 15150 -8280 -8249 5910 7881 900000 SO 20190217T093934.0Z 6987.402477 291 1 32.00 2 88.96 103.90 122.61 274.78 0.00 1 0.00 1 0 15 5.619e-02 5.450e-02 5.647e-02 5.535e-02 3.347581e+03 3.592268e+03 1.682509e+02 -6.000000e+00 3.144615e+03 288.84 -2.00 20.00 -2.00 505.16 0.00e+00 8.432618e-04 1.518970e-03 6.228417e-05 -6.000000e+00 1.579321e-03 288.84 -2.00 20.00 -2.00 499.87 0.00e+00 1.661250e+00 1.109147e+00 3.804897e-02 -6.000000e+00 1.092955e+00 229.46 -2.00 3.16 -2.00 501.51 0.00e+00 18.403 0.058 489.00 513.00 1 9.5377e+00 8.5159e-02 2.7799e-02 -6.0000e+00 8.4017e-02 1.2800e-01 2.1935e-02 1.6771e-03 -6.0000e+00 2.1676e-02 8.9025e-06 -3.9543e-04 5.1813e-03 2.4295e-05 -6.0000e+00 5.5148e-03 -3.8113e-02 2.7979e-04 12 8 8 10 0 0 99.76 22.65 9.33 -0.03811 -0.04086 8 2 1 4 0 4000.000 26.62 20.00 22.65 -1604 -2354 6072 -5332 214 -4404 2763 2292 6267 -1419 412 -120 -3201 556 1680 -5084 5530 5373 -3562 -3177 -2978 3269 42 7172 7559 2857 -2065 -1185 5922 -2332 -7858 5473 -4577 889 -4946 1975 -885 -1249 6451 -170 5118 -3648 3148 8990 -6035 4084 115 -5644 -4715 -7726 555 8852 2381 -2953 2187 -1571 -1356 9742 -1098 -5650 1925 -1590 288 7208 -559 10821 -3839 -1497 7132 -4195 1920 6351 89 -5268 6356 -14227 -1745 6698 2202 482 -4481 6918 -8689 -2090 4242 -9779 874 7563 -4847 3985 -5090 -796 -849 4650 8098 -8088 741 12020 -10209 4422 -7974 10639 -1468 2892 -7231 -312 -2573 -4083 4162 -4339 4847 3100 5936 -2708 -198 9644 5882 -3967 5463 8479 1337 -1585 -7757 -732 -9413 7189 -5024 -6547 2293 7468 7255 12572 6538 -6986 -1905 8570 1959 -5469 6215 -4324 -9731 6757 6423 9785 1242 -1311 7563 1695 7941 -1966 -5879 2405 -13466 -4377 -1672 -2500 6096 -6200 243 -4986 3181 2504 6597 -1602 450 -130 -3520 582 1720 -5554 5481 5443 -4047 -3666 -3458 3572 47 7550 7957 3163 -2398 -1355 6213 -2590 -8955 5366 -4984 939 -5726 2187 -1015 -1428 6744 -187 5313 -4131 3348 9106 -7183 4432 131 -6738 -5509 -9139 590 8422 2351 -3023 2128 -1620 -1437 9480 -1207 -6520 2055 -1754 312 7327 -576 10569 -4024 -1508 6482 -4211 1790 5600 83 -5199 5648 -15730 -1710 5974 2017 441 -4270 5865 -8634 -1956 3755 -10049 815 6643 -4833 3636 -5075 -762 -818 4289 7305 -8613 716 10191 -10560 3855 -7680 8335 -1284 2442 -6940 -290 -2521 -4112 3839 -4297 4323 2807 5274 -2663 -193 8601 5486 -4103 5169 7822 1324 -1602 -7725 -710 -9254 6339 -4731 -6290 2020 6246 6067 9952 5488 -6667 -1703 6784 1638 -4923 5038 -3975 -9629 5758 5556 8246 1146 -1247 6614 1574 6895 -1857 -5648 2080 -13497 -4024 SO 20190217T094336.0Z 6987.405278 295 1 32.01 2 88.15 103.34 123.39 274.27 0.00 1 0.00 1 0 20 4.480e-02 4.388e-02 4.206e-02 4.137e-02 4.587013e+03 2.743009e+03 4.206874e+02 -6.000000e+00 2.505904e+03 288.84 -2.00 20.00 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