File name: Pandora114s1_BuenosAires_20190406_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T060414.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190406_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190406 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190406T101543.0Z 7035.427581 433 1 32.01 2 89.72 82.00 101.41 89.56 0.00 1 0.00 1 0 15 7.849e-02 7.370e-02 7.182e-02 7.036e-02 3.531740e+03 4.574807e+03 2.471389e+01 -6.000000e+00 4.360371e+03 287.15 -2.00 20.00 -2.00 505.30 0.00e+00 -1.030631e-03 1.929050e-03 8.899755e-05 -6.000000e+00 2.197114e-03 287.15 -2.00 20.00 -2.00 500.13 0.00e+00 3.581109e+00 1.389536e+00 7.185582e-02 -6.000000e+00 1.525306e+00 226.76 -2.00 3.16 -2.00 501.77 0.00e+00 19.969 0.075 489.00 513.00 1 9.4179e+00 1.0645e-01 3.1050e-02 -6.0000e+00 1.1717e-01 5.3086e-02 2.7048e-02 2.0253e-03 -6.0000e+00 3.0302e-02 7.1097e-06 1.8845e-03 6.5451e-03 3.0531e-05 -6.0000e+00 7.7063e-03 3.1732e-02 -2.8605e-04 12 9 8 11 8 0 -13.79 21.15 11.57 0.03173 0.04480 8 2 1 4 0 4000.000 25.39 20.00 21.15 -9112 3624 -4861 906 -8355 6794 4618 -4550 -6570 8737 2428 -1110 2663 -1203 1237 9472 -5313 -4759 -289 -5640 5493 11760 -4159 1884 2321 7458 -6399 -5459 3113 -5675 6061 4538 14073 -7206 6975 -9509 15332 -3196 5276 9964 -4784 1355 7147 557 16165 -8784 -676 59 1778 -10542 -1942 -9417 1888 2531 6041 1777 2905 -6277 -2409 -2583 4980 -7951 1867 4007 7749 9150 8002 5000 1537 178 2221 2995 6819 -90 -3913 -9858 -7700 -8229 -3995 -7932 22842 -3743 14264 3015 -10702 8894 -656 5832 5743 -2079 -3491 292 -3951 -6661 22812 -9740 12121 -8086 1531 -3724 -3720 20535 338 -5415 9480 -1733 -10746 -12419 16914 9032 -12160 -11233 17608 7404 -8687 19961 11565 13091 10832 -147 1710 -259 17413 -2798 3082 -764 2886 -7261 -4899 -4379 4294 240 -12107 -1967 12116 -4665 1584 -5840 -3953 64 546 1079 2495 3507 -708 2510 1571 3597 -1520 8585 -14823 -2260 -3698 7675 -9563 3392 -5101 928 -9674 6929 4915 -5381 -7964 9040 2644 -1235 2821 -1310 1217 8581 -5644 -5143 -307 -6458 5683 11465 -4762 2036 2508 7683 -7563 -6352 3279 -6367 5881 4403 12491 -8119 7056 -11631 14736 -3674 5507 9806 -5412 1440 7197 605 15165 -10664 -758 65 1913 -12604 -2081 -10566 1840 2409 5556 1741 2899 -7044 -2637 -2839 5061 -9178 1958 4128 7697 8921 7801 4943 1548 179 2165 2865 6240 -83 -3796 -10286 -7901 -8408 -3841 -7797 16348 -3485 11131 2651 -10889 7516 -616 5180 5125 -2008 -3416 276 -3917 -6863 17703 -10498 10399 -8331 1400 -3500 -3416 14519 290 -4973 7725 -1644 -11536 -13760 13928 7944 -13054 -11913 14120 6671 -9325 16265 10321 11570 9854 -150 1717 -263 14639 -2834 2910 -748 2738 -7218 -4771 -4246 3815 222 -12674 -1852 9783 -4392 1389 -5522 -3721 59 514 1029 2379 3345 -710 2454 1562 3517 -1560 7873 -16842 -2219 -3646 6789 SO 20190406T101945.0Z 7035.430382 437 1 32.01 2 88.90 81.42 100.61 89.00 0.00 1 0.00 1 0 15 5.462e-02 5.307e-02 4.248e-02 4.201e-02 3.407710e+03 2.646730e+03 8.452560e+01 -6.000000e+00 3.035359e+03 287.15 -2.00 20.00 -2.00 505.28 0.00e+00 1.073394e-03 1.149773e-03 4.294419e-05 -6.000000e+00 1.529027e-03 287.15 -2.00 20.00 -2.00 500.30 0.00e+00 1.716197e+00 8.113988e-01 5.027920e-02 -6.000000e+00 1.060425e+00 226.76 -2.00 3.16 -2.00 501.91 0.00e+00 18.328 0.058 489.00 513.00 1 9.2273e+00 6.2142e-02 2.7796e-02 -6.0000e+00 8.1477e-02 7.3325e-02 1.5881e-02 1.7307e-03 -6.0000e+00 2.1037e-02 1.2161e-05 6.6573e-03 3.9731e-03 1.0418e-05 -6.0000e+00 5.3611e-03 -6.4170e-03 4.0062e-05 12 8 8 10 0 0 -9.04 21.15 2.88 -0.00642 0.03976 8 2 1 4 0 4000.000 25.39 20.00 21.15 -6383 3268 -4246 -424 -1240 5667 1728 -9300 7493 -3273 10488 1196 -6158 1800 -6134 5938 -9288 9195 704 -3256 -959 -308 5539 -2532 967 -4151 4071 160 19032 -1607 -7773 4242 589 7809 1902 -508 2133 -4401 8784 -4683 4086 2502 -5928 -6428 5942 -876 -1255 3043 -831 -6383 427 -262 3190 -2294 9885 -6294 -688 6050 2303 3158 -2846 8931 -3819 3864 6240 -1381 -405 -6971 8110 -5206 -629 -1601 3120 5277 -6466 -164 -5575 5863 7498 952 -1034 -1299 -1338 -8457 10642 -2704 6465 2613 -5047 591 -6410 3363 -6044 6808 -2065 -2025 2708 -2927 3825 -5612 4960 1485 -1743 8139 -3687 3827 -7952 1073 -1879 1692 827 645 -107 -5951 10566 -508 5282 294 -787 1366 -1319 5602 -1826 1480 9796 965 3154 1042 14058 -553 3944 -476 -11207 8230 -9029 -2792 -6032 13157 -11548 4548 1749 -4579 4334 -5793 7940 -2535 -3900 -6350 -158 4045 -1463 6213 -2045 5192 -6610 3134 -4231 -420 -1273 5554 1793 -10877 7405 -3567 9818 1212 -6627 1769 -6484 5575 -10302 8684 742 -3629 -1050 -336 5703 -2837 1051 -4763 4292 174 16825 -1699 -8514 4088 596 7589 2026 -565 2313 -5050 8730 -5271 4196 2617 -6803 -7500 6199 -986 -1419 3275 -917 -7308 446 -268 3074 -2311 8901 -6843 -729 6129 2294 3122 -2982 8321 -4059 3819 6023 -1429 -409 -7410 7306 -5293 -604 -1537 2850 4754 -6640 -160 -5740 5312 6562 877 -966 -1217 -1261 -8620 9039 -2651 5841 2468 -5158 570 -6632 3168 -6316 6343 -2126 -2084 2627 -2946 3515 -5533 4302 1311 -1583 6809 -3587 3585 -8596 1066 -1905 1633 798 626 -106 -6357 9709 -495 4900 288 -786 1340 -1326 5198 -1796 1388 8377 903 2903 984 11681 -532 3621 -457 -11945 7157 -9186 -2631 -5830 10549 -12057 4131 1665 -4714 4126 -6146 7386 -2634 -4128 -6891 -160 3861 -1442 5569 -1981 4729 SO 20190406T102351.0Z 7035.433229 441 1 32.01 2 88.07 80.84 99.80 88.43 0.00 1 0.00 1 0 15 1.289e-02 1.284e-02 9.011e-03 8.977e-03 8.274985e+03 6.142432e+02 5.714082e+02 -6.000000e+00 7.165235e+02 287.15 -2.00 20.00 -2.00 505.39 0.00e+00 2.830768e-03 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