File name: Pandora114s1_BuenosAires_20190503_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T062517.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190503_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190503 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190503T103652.0Z 7062.442269 424 1 32.01 2 89.73 70.68 72.10 69.81 0.00 1 0.00 1 0 47 2.065e-01 1.756e-01 1.552e-01 1.416e-01 2.627765e+04 1.194276e+04 1.654602e+03 -6.000000e+00 1.140188e+04 285.50 -2.00 20.00 -2.00 505.33 0.00e+00 2.782811e-04 3.898310e-03 7.669511e-05 -6.000000e+00 5.756717e-03 285.50 -2.00 20.00 -2.00 499.96 0.00e+00 2.615369e-01 2.822660e+00 5.340929e-02 -6.000000e+00 3.999365e+00 225.33 -2.00 3.16 -2.00 501.62 0.00e+00 20.040 0.075 489.00 513.00 1 1.0279e+01 2.1700e-01 3.1174e-02 -6.0000e+00 3.0724e-01 1.1578e-01 5.3555e-02 2.7823e-03 -6.0000e+00 7.9183e-02 3.4516e-06 2.5754e-02 1.1945e-02 1.3701e-04 -6.0000e+00 2.0256e-02 1.2289e-02 5.0793e-05 12 9 8 11 8 0 96.16 21.82 7.01 0.01229 0.19093 8 2 1 4 0 4000.000 25.90 20.00 21.82 33086 19073 23301 16000 -10631 11676 -19505 3723 -5929 23853 12959 26923 30706 -9898 35859 -31040 20238 -11374 1962 5809 4159 17289 -14983 -1602 1797 16750 -4681 22732 -3968 -7014 16416 -26359 19565 19463 18796 2981 -22045 4193 20462 -2940 16517 3441 5455 -24186 71286 -17771 13333 -1432 -5165 15909 -28476 18505 1655 11039 27046 7168 5403 4288 2467 -15796 16331 13896 11403 4909 -22073 7979 -4211 3974 33728 -121 10559 -19622 -3351 -10314 12848 -10032 46156 -8976 -10541 -4479 18418 24543 -998 4019 -4566 29184 -10640 -922 36892 -34561 9548 -11460 -7445 24401 40717 18092 -8100 12381 -16947 8078 -26417 27280 32463 18124 14036 -27203 26470 17613 7628 -11394 -5096 53115 -14103 25891 -9299 12110 18000 -6279 1566 4998 30426 -14802 26415 -2223 1952 4429 5983 3454 761 18626 -14181 14433 9815 -14616 64546 -25415 53155 -29461 9933 -8239 -3259 9958 -2751 26327 -7988 22090 -8062 10617 11117 -13479 68768 8833 13047 5451 24279 16644 20102 15231 -13494 12041 -27659 4172 -7232 21288 12722 22693 24663 -11876 27380 -47094 18864 -14888 2277 6510 4743 17316 -20801 -1954 2121 16942 -5416 19566 -4334 -7725 14282 -35861 17384 17833 17570 3256 -30604 4424 18180 -3293 15287 3662 5756 -34696 39586 -24013 13081 -1604 -5879 14283 -38742 15414 1623 10013 21527 7165 5601 4525 2649 -20321 15265 13375 11293 5179 -30235 7976 -4676 4009 24973 -124 9675 -24335 -3566 -11932 11891 -11606 29903 -9886 -11610 -4601 15000 18854 -998 3868 -4860 22418 -11448 -955 25950 -46181 8749 -12230 -7687 19422 26756 14233 -7379 8809 -15734 5748 -26360 16096 18872 12895 11083 -33989 19752 14365 6818 -12259 -5173 30417 -15908 19545 -9925 10403 14681 -6646 1562 4857 22704 -16954 19482 -2141 1796 3997 5347 3177 720 14706 -15504 11772 8261 -15471 30803 -29990 29056 -37577 8705 -8793 -3365 9159 -2912 21015 -9010 18400 -9024 9765 10032 -14420 34011 7971 11434 4941 SO 20190503T104108.0Z 7062.445232 428 1 32.01 2 88.91 70.07 71.31 69.11 0.00 1 0.00 1 0 22 1.380e-01 1.304e-01 1.135e-01 1.084e-01 -3.423521e+03 6.139425e+03 3.006038e+01 -6.000000e+00 7.614075e+03 285.50 -2.00 20.00 -2.00 505.14 0.00e+00 -3.064646e-03 2.932782e-03 1.030354e-04 -6.000000e+00 3.850330e-03 285.50 -2.00 20.00 -2.00 499.95 0.00e+00 1.651172e+00 2.156063e+00 7.721294e-02 -6.000000e+00 2.697460e+00 225.33 -2.00 3.16 -2.00 501.58 0.00e+00 18.381 0.058 489.00 513.00 1 1.0251e+01 1.6502e-01 2.8302e-02 -6.0000e+00 2.0675e-01 1.2440e-01 4.3830e-02 1.9563e-03 -6.0000e+00 5.4112e-02 4.5981e-06 -6.1030e-03 1.0293e-02 2.9088e-05 -6.0000e+00 1.3578e-02 1.5444e-01 -1.3934e-03 12 8 8 10 0 0 99.71 21.82 5.67 0.15444 0.11211 8 2 1 4 0 4000.000 25.90 20.01 21.82 900000 -4903 4850 3316 -18171 38892 9922 25762 -4990 6062 6666 -9860 11857 -10106 6480 9387 5114 16999 -9944 12273 -14448 23114 -3314 15789 1739 -16371 1383 -13569 25541 13129 11169 -10169 -5091 18175 -25336 3207 4635 10969 -8700 19686 774 5866 8385 -9878 22177 -7147 18891 5969 -13151 -8848 -18222 -4075 10645 11060 1796 5160 23075 3700 -3521 -9914 6452 18946 3789 13455 -22370 8554 -15217 5293 -2547 -6743 -567 -15527 7593 -8680 242 10700 -2672 10849 -1992 14431 -18921 16512 -5221 18961 8209 -578 7137 -7292 3193 -3164 9358 15146 11025 14208 -16421 21458 -9879 6002 -375 -6424 14986 -13849 31030 -16081 6217 -10479 14480 20747 1273 14373 -28500 35305 -258 -6107 -8437 224 -2366 -12976 16486 -22564 4390 8563 -237 29625 -1155 33015 4204 12803 -8454 7011 5366 -5842 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16865 1666 1990 -11675 SO 20190503T104523.0Z 7062.448183 432 1 32.04 2 88.09 69.45 70.52 68.40 0.00 1 0.00 1 0 15 1.206e-01 1.196e-01 9.662e-02 9.253e-02 5.538978e+03 6.420945e+03 5.949476e+02 -6.000000e+00 6.656692e+03 285.50 -2.00 20.00 -2.00 505.25 0.00e+00 2.643168e-04 2.546394e-03 6.970472e-05 -6.000000e+00 3.360877e-03 285.50 -2.00 20.00 -2.00 499.76 0.00e+00 2.953827e+00 1.887267e+00 2.046380e-02 -6.000000e+00 2.335723e+00 225.33 -2.00 3.16 -2.00 501.43 0.00e+00 16.244 0.040 489.00 513.00 1 1.0238e+01 1.4485e-01 2.4070e-02 -6.0000e+00 1.7942e-01 9.0102e-02 3.7268e-02 1.5105e-03 -6.0000e+00 4.6258e-02 5.3971e-06 -1.9419e-02 8.4504e-03 5.2031e-05 -6.0000e+00 1.1827e-02 -2.0760e-02 2.2492e-04 12 9 8 11 8 0 74.36 21.82 7.53 -0.02076 -0.15546 8 2 1 4 0 4000.000 25.90 20.00 21.82 -178 -13452 -85 -9096 -4670 3996 9393 6580 15762 -739 1343 3911 -4204 11904 8738 17629 3245 1762 -2993 -6251 10186 4193 7776 6122 -4426 6653 -3223 -2840 -42855 5311 2239 23459 6987 3690 -5795 -4585 11872 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