File name: Pandora114s1_BuenosAires_20190508_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T062526.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190508_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190508 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190508T104047.0Z 7067.444988 463 1 32.01 2 89.74 68.92 129.86 88.71 0.00 1 0.00 1 0 54 1.389e-01 1.208e-01 1.264e-01 1.204e-01 2.782775e+03 7.749436e+03 2.758012e+02 -6.000000e+00 7.653929e+03 285.16 -2.00 20.00 -2.00 504.99 0.00e+00 7.471191e-03 3.327246e-03 4.160628e-04 -6.000000e+00 3.954283e-03 285.16 -2.00 20.00 -2.00 499.51 0.00e+00 -3.684419e-01 2.509750e+00 9.206664e-02 -6.000000e+00 2.822027e+00 225.08 -2.00 3.16 -2.00 501.15 0.00e+00 20.058 0.076 489.00 513.00 1 1.0108e+01 1.9201e-01 3.2876e-02 -6.0000e+00 2.1365e-01 2.1000e-01 5.0852e-02 1.9710e-03 -6.0000e+00 5.9624e-02 4.1282e-06 4.6828e-02 1.1550e-02 1.5020e-04 -6.0000e+00 1.3895e-02 7.1912e-02 -3.8869e-03 12 8 8 10 0 0 76.97 21.44 3.69 0.07191 0.39673 8 2 1 4 0 4000.000 25.58 19.99 21.44 900000 900000 900000 900000 635 1397 -3341 -7474 4588 10726 -5617 1567 1773 -25064 16748 749 -3785 16476 9151 14489 -745 18938 -13820 5150 3738 -8965 29976 -10546 79502 3051 -13534 -3023 1917 494 5179 6644 -6480 -3676 18260 2176 -2609 10265 -15407 7044 -9483 -5298 -3845 3331 35 7291 3021 12653 23226 10007 8718 -8991 19781 11081 -5503 -1252 7736 -10126 3318 11799 -3676 24386 5082 -31993 6671 17052 -4576 -7995 17208 13419 18353 -5451 -7883 12106 4633 19269 -18455 -13947 -4641 -1005 -1578 -10086 17011 -7663 16250 -6974 -12789 -1725 -8052 32312 2104 -3121 -20879 3579 -11424 10081 3769 3732 2849 -9067 -5661 24443 -2906 3268 -21394 8064 18650 -10121 46088 18744 989 -1653 -11251 24845 10698 3431 11883 -1724 8501 12202 14765 16693 -337 11038 -8800 14751 13174 -1498 -7613 1929 16919 1482 -4170 7811 -12681 -2335 -16399 5993 7522 -12086 -4888 -11011 14215 -5050 1966 5854 -6561 1588 -5729 643 900000 900000 900000 900000 712 1601 -4109 -9760 5373 11839 -7241 1849 2047 -34689 16086 778 -4077 14510 8779 13445 -820 17275 -17497 5386 3968 -10856 24750 -13103 40011 3263 -16709 -3257 1915 497 5049 6583 -7542 -4220 16800 2327 -2892 9928 -19263 7090 -11410 -6208 -4505 3668 39 7683 3278 12238 19725 9443 8158 -9968 16644 10456 -6317 -1408 8030 -12581 3600 11784 -4307 21669 5475 -46463 6924 15688 -5145 -9179 15155 12135 15731 -5586 -8368 10621 4371 15484 -21224 -15114 -4550 -948 -1500 -10484 13544 -7852 13178 -7147 -13859 -1666 -8252 22153 1970 -3130 -25397 3430 -12633 8844 3445 3329 2499 -8757 -5217 16758 -2678 2915 -24919 7015 14436 -10297 26502 14233 911 -1596 -12192 19048 9543 3313 10600 -1766 7834 10705 12409 13537 -320 9358 -9147 12179 11071 -1372 -7396 1699 13595 1295 -3790 6564 -12142 -2009 -16385 4865 6107 -12076 -4579 -11001 11047 -4765 1733 4955 -6237 1366 -5167 531 SO 20190508T104450.0Z 7067.447801 467 1 32.01 2 88.96 68.34 129.07 88.18 0.00 1 0.00 1 0 22 1.132e-01 1.040e-01 1.013e-01 9.762e-02 1.274222e+03 5.861053e+03 1.623917e+02 -6.000000e+00 6.239707e+03 285.16 -2.00 20.00 -2.00 505.19 0.00e+00 -6.603715e-04 2.652944e-03 1.282624e-04 -6.000000e+00 3.155035e-03 285.16 -2.00 20.00 -2.00 499.91 0.00e+00 1.349040e+00 1.923731e+00 4.295132e-02 -6.000000e+00 2.202332e+00 225.08 -2.00 3.16 -2.00 501.56 0.00e+00 18.525 0.059 489.00 513.00 1 1.0106e+01 1.4765e-01 2.8191e-02 -6.0000e+00 1.6902e-01 1.2419e-01 3.8139e-02 1.7033e-03 -6.0000e+00 4.3838e-02 5.1285e-06 1.2376e-02 9.1922e-03 4.4919e-05 -6.0000e+00 1.1118e-02 1.0902e-01 -9.0645e-04 12 8 8 10 0 0 78.51 21.44 5.60 0.10902 0.19487 8 2 1 4 0 4000.000 25.58 20.00 21.44 5347 4700 -21903 19683 -9897 6376 -2235 2010 3594 -7799 5344 -8457 16061 3406 3452 7783 10065 4768 -11042 27087 -3851 -1555 -9059 -1789 5490 -1396 3869 -5678 4392 -2699 13547 11602 -13650 8256 -3073 29691 -1099 7904 4139 -11079 1915 -18554 3958 4940 4106 4043 -4643 9772 -7633 12071 -7340 -7372 -5527 -113 12026 -5670 20601 -7103 15431 -8621 6417 1456 -8540 11638 -13178 20501 -3792 -3074 -2129 -13285 25254 -1092 6782 3535 7623 5332 7153 -2737 3837 13955 -3904 28211 -10557 8373 9993 -10127 -3203 -11383 26657 -1036 6131 8630 2376 -11016 -14312 11852 4158 10967 -7255 4315 -2577 -945 2965 -16041 18306 13645 3707 20391 -989 -9608 -4743 19946 -2075 -9298 -9595 -4705 -4661 -2479 18393 -750 4742 -7154 -7681 8092 -8234 4075 6533 15829 2289 -11453 5086 -6161 26494 -19569 26300 -4629 25630 2736 11349 -8372 -12130 -957 22165 26584 7938 -5325 12925 -9794 -14292 3149 5236 1335 -6624 -4471 5117 4626 -29046 17760 -12313 6886 -2674 2322 4078 -9810 5808 -10406 15261 3632 3657 7399 9504 4867 -13527 22985 -4472 -1766 -11097 -2043 5850 -1594 4172 -6666 4567 -2927 12187 10585 -16286 8165 -3510 24816 -1248 8119 4357 -13430 2028 -24150 4142 5169 4375 4334 -5422 9789 -8961 11398 -8195 -7996 -5747 -110 10512 -6077 17481 -8112 14177 -10066 6428 1533 -9971 11137 -16143 17789 -4137 -3275 -2214 -15257 19496 -1087 6231 3383 7101 4816 6332 -2636 3397 11018 -3666 19237 -10671 7061 8368 -10480 -3123 -12119 19452 -997 5500 7588 2245 -12058 -16351 10421 3905 9447 -7333 3794 -2374 -842 2536 -16887 14125 11427 3503 16344 -970 -10114 -4710 15509 -2035 -9955 -10445 -4925 -4907 -2565 15512 -767 4567 -7659 -8132 7212 -8570 3753 5901 13066 2163 -11670 4380 -5931 19492 -21261 18878 -4196 18090 2295 8881 -8154 -12497 -895 16596 19156 6926 -5336 10842 -10311 -15609 2836 4510 1173 -6264 -4178 SO 20190508T104856.0Z 7067.450648 471 1 32.01 2 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