File name: Pandora114s1_BuenosAires_20190603_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T064538.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190603_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190603 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190603T105911.0Z 7093.457766 486 1 32.01 2 89.75 62.36 89.62 65.13 0.00 1 0.00 1 0 15 1.138e-01 1.092e-01 1.089e-01 1.052e-01 5.813274e+03 7.259382e+03 6.159279e+02 -6.000000e+00 6.236321e+03 283.72 -2.00 20.00 -2.00 505.25 0.00e+00 4.798537e-03 2.909988e-03 3.295811e-04 -6.000000e+00 3.164046e-03 283.72 -2.00 20.00 -2.00 500.00 0.00e+00 3.564372e-01 2.167300e+00 5.222657e-02 -6.000000e+00 2.229579e+00 224.35 -2.00 3.16 -2.00 501.65 0.00e+00 20.122 0.076 489.00 513.00 1 9.9268e+00 1.6652e-01 3.2038e-02 -6.0000e+00 1.7072e-01 1.4849e-01 4.2804e-02 1.7627e-03 -6.0000e+00 4.4824e-02 4.8072e-06 4.3532e-03 9.9792e-03 1.4308e-04 -6.0000e+00 1.1210e-02 3.4259e-02 -8.3578e-04 12 8 8 10 0 0 -100.23 21.08 6.58 0.03426 0.06445 8 2 1 4 0 4000.000 25.28 20.00 21.08 900000 8206 8847 14538 -5904 10267 8734 10194 -10729 5457 123 1666 -1931 -2751 -636 -15317 186 7943 -14488 23170 3697 3279 10 -6684 4497 12722 8832 -14182 1554 -3707 -5413 -4093 724 1558 13386 -7636 -2415 8577 -9469 3054 230 11888 10315 -28831 -11841 803 8169 1202 22071 11828 -6387 26131 -2757 10732 34257 8952 14824 -6140 25593 -8391 -12268 -2454 2118 6552 18242 17452 -10387 13869 -17265 -4150 -6656 2592 895 10738 -17899 3982 209 -13047 8223 -5332 -4072 1475 -734 3135 -5907 19899 964 2387 -16795 514 10878 -1550 751 -1595 -11350 13030 -9046 18503 -5922 899 1922 10364 29198 9587 50 -9341 -14499 -10889 12690 24822 2465 -3662 7488 17556 7211 24977 -15919 7637 -5966 6206 15167 -6194 5312 3567 14865 -4397 228 -2457 -6396 -17913 -13393 -1297 19593 6398 -4817 -14567 14044 -4310 884 15920 7110 9426 -5452 -14586 -7062 20879 1822 1388 7195 10457 -380 17587 -4048 1601 900000 7555 8276 13279 -6828 10360 9135 10662 -13909 5989 141 1840 -2176 -3080 -689 -19067 198 7957 -17331 20821 3813 3404 11 -7674 4637 12157 8804 -17745 1645 -4052 -5842 -4249 711 1542 12147 -8820 -2689 8550 -11197 3149 242 11115 9857 -41226 -14490 878 8368 1323 19574 11465 -7289 21018 -2881 9592 24021 8185 13147 -6923 21465 -9979 -15181 -2750 2272 6757 16805 16197 -12639 13063 -21840 -4537 -7368 2584 899 9744 -21780 3942 217 -14463 7745 -5292 -3937 1341 -681 2808 -5825 15262 901 2215 -18942 487 9254 -1488 707 -1552 -12363 11253 -9736 14907 -5954 823 1697 8216 18818 7477 43 -9211 -15605 -11580 10714 18398 2256 -3541 6515 14031 6507 19156 -18571 7088 -6383 5920 13295 -6706 5067 3402 12454 -4421 219 -2439 -6637 -20897 -14933 -1279 15658 5814 -4843 -15866 11314 -4139 809 12723 6324 8323 -5325 -15749 -7111 16955 1691 1297 6328 8817 -350 13228 -3708 1379 SO 20190603T110322.0Z 7093.460671 490 1 32.01 2 88.99 61.76 88.87 64.54 0.00 1 0.00 1 0 50 8.070e-02 7.926e-02 6.964e-02 6.828e-02 3.315265e+03 4.278922e+03 1.709956e+02 -6.000000e+00 4.424613e+03 283.72 -2.00 20.00 -2.00 505.19 0.00e+00 4.893194e-03 1.860380e-03 2.411846e-04 -6.000000e+00 2.239768e-03 283.72 -2.00 20.00 -2.00 500.10 0.00e+00 1.039805e+00 1.351193e+00 7.505273e-02 -6.000000e+00 1.562948e+00 224.35 -2.00 3.16 -2.00 501.70 0.00e+00 18.629 0.061 489.00 513.00 1 9.6558e+00 1.0382e-01 2.9216e-02 -6.0000e+00 1.2000e-01 1.2189e-01 2.6374e-02 1.9654e-03 -6.0000e+00 3.0943e-02 7.5008e-06 1.1656e-02 6.4645e-03 8.7104e-05 -6.0000e+00 7.9151e-03 -1.4306e-02 1.9603e-04 12 9 8 11 8 0 93.82 21.08 -4.64 -0.01431 0.06654 8 2 1 4 0 4000.000 25.28 19.99 21.08 -8614 -5080 3323 -3441 14046 -329 8753 2911 -8685 9552 -2748 3073 -5718 13515 3237 5638 -14742 122 3832 4285 9330 1420 -6891 914 -1775 10906 -15630 871 13973 -5804 7843 -2763 9498 -6941 22103 4744 11442 3209 -2119 5850 -12861 1941 -1805 7703 892 -8905 -7895 7734 5766 -9402 6911 -11541 -8888 -5672 -2120 13407 -919 19480 4365 3892 -3955 365 3371 3649 -7385 -534 -4864 3065 -7523 8119 946 5130 -6265 12408 178 -10293 8225 1885 -5127 -1832 2800 -782 4780 -3750 -16092 7278 473 8960 4053 1423 2288 -10309 -2841 -10945 2294 16483 -1996 -6611 -6501 4140 -2866 -3999 -4865 2744 772 -7560 9831 -221 5295 3169 2995 -7717 -2946 1526 -6891 4146 -2679 6840 6070 14329 -4566 -7996 13346 -7788 16642 12099 1261 -9468 -8563 8426 7833 -2372 8602 13009 12249 5994 6050 -7405 10139 2700 12533 6199 5996 16182 -15471 -6530 -13470 13793 -1343 -8057 2690 3559 -5056 -8844 -9349 -5465 3400 -3883 13633 -376 9249 3271 -10880 9819 -3140 3262 -6534 12601 3328 5688 -17301 126 3899 4379 9077 1495 -7903 975 -1956 10610 -19739 921 12658 -6216 7175 -2811 8731 -7775 19036 4911 11029 3322 -2289 5795 -15382 2019 -1974 7769 975 -10808 -9477 7868 5892 -10950 6661 -13030 -9598 -5923 -2176 12145 -988 17386 4558 4082 -4483 397 3580 3875 -8733 -584 -5470 3132 -8426 7681 950 4899 -6709 11130 182 -11066 7781 1750 -5019 -1717 2495 -723 4200 -3608 -17639 6363 446 7760 3679 1322 2106 -10825 -2805 -11905 2207 13723 -1971 -6693 -6419 3585 -2602 -3614 -4437 2365 701 -7686 8514 -210 4719 2850 2694 -7813 -2896 1462 -7293 3972 -2768 6467 5815 12649 -4833 -8630 11446 -8145 13576 10377 1213 -10179 -9135 7579 7078 -2232 7214 10939 10198 5241 5265 -6998 8696 2392 10854 5443 5312 12998 -17118 -6634 -14692 11405 -1275 -7994 2341 3027 -4699 -8671 SO 20190603T110735.0Z 7093.463600 494 1 32.01 2 88.23 61.16 88.12 63.94 0.00 1 0.00 1 0 22 5.316e-02 5.074e-02 5.294e-02 5.220e-02 2.651093e+03 3.202263e+03 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