File name: Pandora114s1_BuenosAires_20190607_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T064613.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190607_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190607 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190607T110123.0Z 7097.459294 496 1 32.01 2 89.75 61.80 134.32 95.09 0.00 1 0.00 1 0 15 1.313e-01 1.199e-01 1.188e-01 1.134e-01 1.401158e+04 8.435141e+03 7.953303e+02 -6.000000e+00 7.190815e+03 283.52 -2.00 20.00 -2.00 505.22 0.00e+00 -2.898757e-03 3.098775e-03 1.908992e-04 -6.000000e+00 3.645786e-03 283.52 -2.00 20.00 -2.00 499.82 0.00e+00 -8.945933e-01 2.324685e+00 9.377426e-02 -6.000000e+00 2.562643e+00 224.28 -2.00 3.16 -2.00 501.50 0.00e+00 20.126 0.076 489.00 513.00 1 1.0191e+01 1.7851e-01 3.2138e-02 -6.0000e+00 1.9638e-01 1.7611e-01 4.5913e-02 2.6498e-03 -6.0000e+00 5.1282e-02 4.4384e-06 -1.3211e-02 9.9890e-03 9.8150e-05 -6.0000e+00 1.2913e-02 1.9846e-02 -4.4127e-04 12 8 8 10 0 0 98.50 21.18 9.55 0.01985 -0.07179 8 2 1 4 0 4000.000 25.39 19.99 21.18 900000 -12008 4511 4629 -7605 8296 -14564 18243 4450 -5077 14901 -830 10727 -151 8088 -11158 -8249 -601 4278 -2782 121 -10118 12020 10572 206 11516 5943 18260 -16789 -473 17808 -12227 1352 11483 13661 635 -11898 -5494 -12615 -10260 -9167 22313 12880 -793 11381 -2611 168 11028 -3316 -9544 7705 25150 -6687 19420 3812 5909 8447 22662 12493 4142 -10949 19282 1947 -709 -12072 10951 -20953 7415 -2067 2102 6883 2670 14661 -22053 -184 -6230 3281 -10657 485 29477 -3871 5689 7667 13815 -13170 -793 17715 -238 195 -27120 13142 -10676 11774 23370 8146 5842 -13709 21715 -9252 11928 -2281 -7882 35298 -12543 -2687 -16490 9234 -1351 3377 13564 16968 9971 -16512 -3122 -14141 21889 47017 -2452 15685 -10056 15613 -2087 10896 28215 -14237 -238 4433 8213 -737 -2035 19840 -12774 2459 -11546 10196 -12439 5386 20595 6269 -7242 -3027 9043 -6645 9649 9271 2613 -14114 -12529 14357 -2597 36489 -15960 20165 -10151 900000 -13729 4406 4631 -8876 8497 -19195 17671 5017 -6328 15143 -975 11072 -172 8348 -13821 -9889 -673 4653 -3336 144 -12596 12884 11499 232 11605 6341 17185 -22270 -525 16099 -14496 1372 10551 12553 687 -14989 -6555 -16079 -12621 -11005 19345 12217 -864 11048 -2941 185 10951 -3784 -11457 7651 20501 -7284 15829 3559 5386 7636 18305 11479 4205 -12982 16860 2020 -756 -14491 10468 -27482 7253 -2191 2103 6478 2592 12494 -26964 -181 -6601 3209 -12083 488 21843 -3930 5185 6818 11568 -13633 -733 14702 -225 185 -34102 11047 -11348 9979 18877 7244 5357 -15238 16595 -9320 9364 -1997 -7118 20353 -11589 -2278 -16611 7570 -1295 3191 11685 14027 8728 -18697 -3101 -15817 17183 28744 -2453 13076 -10899 13232 -2131 9765 20973 -15825 -225 3942 7018 -691 -1937 15161 -13489 2221 -11951 8429 -12703 4527 14737 5182 -6943 -2839 7665 -6694 8379 8180 2487 -15042 -13189 12268 -2462 24589 -16801 14504 -9757 SO 20190607T110532.0Z 7097.462176 500 1 32.01 2 89.00 61.21 133.50 94.47 0.00 1 0.00 1 0 50 7.992e-02 8.109e-02 8.759e-02 8.567e-02 -3.977217e+02 5.020706e+03 3.643516e+02 -6.000000e+00 4.377868e+03 283.52 -2.00 20.00 -2.00 505.22 0.00e+00 4.456788e-03 2.332071e-03 2.577484e-04 -6.000000e+00 2.222116e-03 283.52 -2.00 20.00 -2.00 499.90 0.00e+00 3.034426e+00 1.712993e+00 5.443414e-02 -6.000000e+00 1.567062e+00 224.28 -2.00 3.16 -2.00 501.56 0.00e+00 18.655 0.061 489.00 513.00 1 9.7489e+00 1.3176e-01 2.8982e-02 -6.0000e+00 1.1997e-01 1.0108e-01 3.3802e-02 1.6137e-03 -6.0000e+00 3.1517e-02 5.9454e-06 2.7125e-02 8.1098e-03 1.0312e-04 -6.0000e+00 7.8792e-03 -3.9546e-02 -4.3663e-04 12 9 8 11 8 0 -23.98 21.17 3.40 -0.03955 0.14860 8 2 1 4 0 4000.000 25.39 20.00 21.17 900000 -389 4176 14577 9154 -16269 9640 10054 -1819 16917 17758 910 -18893 1184 15785 -3272 -2194 -17902 3300 12185 3432 -5231 3138 -5002 10853 -1702 945 -5717 126 -1294 -14253 7649 7787 -2743 6502 -7565 -3601 6781 -815 1568 2079 9996 737 -7350 4356 -2108 -5102 -3606 13569 -178 1453 -5056 2312 1880 -15957 1247 -4358 3151 13284 4723 12992 14930 6741 -1457 -2265 -6735 854 -16596 -5033 5144 -6657 3406 6247 -9587 -2638 5323 16393 4129 8352 -660 -3987 -10985 5276 -2472 8179 11349 375 -6615 1591 -2623 1331 8440 4234 1274 -5504 -2105 -2360 -5486 17439 5351 -11903 -4957 -4754 1467 7301 9283 -3601 1367 7016 4393 7088 -9754 -3599 -2597 12027 9806 1654 126 -6204 -2274 -3115 -8102 -13980 5608 -3131 -14320 -799 8775 3132 13238 -1340 -3967 3942 -1683 14508 2450 -1158 -6117 7052 -1800 4324 15063 3993 5483 4197 5286 -7311 6085 6636 -7305 10886 5539 -296 -16879 900000 -401 4258 13814 9389 -21956 10176 10614 -2150 16336 16722 999 -24931 1264 14486 -3651 -2461 -22448 3661 12497 3593 -5974 3303 -5740 10694 -1906 1027 -6561 133 -1348 -16517 7108 7367 -2979 6624 -8978 -4092 6871 -880 1641 2165 9681 792 -8681 4633 -2408 -5998 -4139 12914 -190 1488 -5378 2239 1821 -18759 1271 -4831 3299 12642 4891 12364 13958 6868 -1615 -2523 -7767 899 -20439 -5438 4953 -7118 3261 5805 -10519 -2732 5126 14041 3930 7481 -639 -3973 -11011 4814 -2296 6868 9292 344 -6527 1444 -2478 1209 7176 3799 1197 -5604 -2077 -2316 -5471 13545 4577 -11807 -4501 -4292 1263 6093 7795 -3477 1248 5965 3781 5915 -9727 -3438 -2508 10226 8646 1598 124 -6545 -2304 -3155 -8504 -15334 5004 -3040 -15632 -767 7691 2909 11117 -1301 -3955 3620 -1616 11650 2186 -1064 -5939 6107 -1738 3994 12649 3773 5122 3752 4700 -7404 5380 5769 -7145 8657 4569 -259 -17676 SO 20190607T110939.0Z 7097.465035 504 1 32.01 2 88.26 60.62 132.70 93.87 0.00 1 0.00 1 0 20 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