File name: Pandora114s1_BuenosAires_20190609_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T064658.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190609_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190609 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190609T110221.0Z 7099.459965 496 1 32.01 2 89.76 61.58 149.67 130.48 0.00 1 0.00 1 0 15 1.084e-01 1.059e-01 9.699e-02 9.411e-02 1.280658e+04 6.937398e+03 8.331763e+02 -6.000000e+00 5.940492e+03 283.42 -2.00 20.00 -2.00 505.25 0.00e+00 2.822756e-03 2.574989e-03 1.814553e-04 -6.000000e+00 3.012583e-03 283.42 -2.00 20.00 -2.00 500.04 0.00e+00 -6.993290e-01 1.896305e+00 8.783142e-02 -6.000000e+00 2.118988e+00 224.24 -2.00 3.16 -2.00 501.67 0.00e+00 20.136 0.076 489.00 513.00 1 9.9041e+00 1.4510e-01 3.2011e-02 -6.0000e+00 1.6236e-01 1.5527e-01 3.7540e-02 2.6093e-03 -6.0000e+00 4.2414e-02 5.3981e-06 -2.6943e-03 8.4756e-03 9.7469e-05 -6.0000e+00 1.0684e-02 -3.2002e-02 5.4033e-04 12 8 8 10 0 0 -37.50 20.76 10.44 -0.03200 -0.05069 8 2 1 4 0 4000.000 24.96 20.00 20.76 -15180 1262 5667 -109 5755 7962 24804 3846 6803 -10610 -9580 4421 -3111 20142 -477 21439 -6052 5767 -2129 -2217 9663 2386 11675 -4093 11194 706 -11315 11887 -9667 2980 -2289 16441 6963 -13172 -2214 -17307 13552 -10860 -2924 -5060 10758 17818 -7029 6889 -613 5535 -480 5921 -1642 -16976 8620 -9635 15809 -12670 -11371 3028 -7351 734 -7991 16535 8056 992 2042 7882 8005 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6 9254 -22242 79 -10140 9384 1959 302 2847 1774 11992 -2799 10723 -16486 7309 9658 -2145 6495 -16697 5323 3182 265 4050 4744 10847 -11875 -871 -3026 -9961 8944 6506 12060 -5913 6096 -1946 11486 -3444 -1472 9107 -5420 10580 -23931 17820 498 -21828 12840 4745 13075 -16262 3143 -1951 -856 6670 -10210 17785 5069 11351 -11842 2021 16728 5255 4152 -28496 16807 -41 -1121 16365 900000 SO 20190609T110632.0Z 7099.462870 500 1 32.01 2 89.00 60.98 149.03 129.05 0.00 1 0.00 1 0 29 7.076e-02 6.929e-02 7.121e-02 6.988e-02 6.996023e+03 4.734767e+03 5.987610e+02 -6.000000e+00 3.873990e+03 283.42 -2.00 20.00 -2.00 505.22 0.00e+00 4.975667e-03 1.894755e-03 3.423367e-04 -6.000000e+00 1.962352e-03 283.42 -2.00 20.00 -2.00 500.11 0.00e+00 7.325973e-01 1.386686e+00 5.404718e-02 -6.000000e+00 1.372628e+00 224.24 -2.00 3.16 -2.00 501.71 0.00e+00 18.659 0.061 489.00 513.00 1 9.6819e+00 1.0595e-01 2.9529e-02 -6.0000e+00 1.0533e-01 1.1886e-01 2.7102e-02 1.8168e-03 -6.0000e+00 2.7231e-02 7.3913e-06 4.5948e-03 6.5184e-03 1.2614e-04 -6.0000e+00 6.9448e-03 6.5219e-02 -4.2449e-04 12 8 8 10 0 0 -223.20 20.75 9.85 0.06522 0.09709 8 2 1 4 0 4000.000 24.96 19.99 20.75 -8266 15202 8775 -7346 11276 -4122 4827 -1675 10873 -5933 2948 -4749 -15845 2650 -11268 9493 -327 -1340 10079 -7952 3703 -1847 -1747 3782 4422 5332 14441 -3992 15831 -8201 8209 2780 -10995 -1353 -1917 -2403 12769 -7008 10779 3882 -2447 -255 7008 1829 -5701 7742 447 4989 402 -1363 -3710 -3894 4558 -9811 -6027 -4702 -6524 4241 -500 952 -6765 5217 -3039 -958 3247 143 3517 -1913 12239 1238 -5551 -9519 -4962 15248 -7418 12977 1786 7356 4059 5376 2211 -1254 -107 -962 2900 -400 4038 9196 -645 -1500 -7501 5484 -11414 12654 -6276 -9355 7371 2267 6704 4079 -12075 10123 -8200 51 -4565 14485 735 8225 4769 -105 -5717 -7835 13987 1479 396 -8798 5255 9523 -11281 -4025 -9032 11956 -3769 -2185 2261 -536 -7501 2890 4533 633 2255 12890 -9370 9759 6187 8985 5211 2634 3576 10255 3509 -1653 3240 -4464 -7952 7858 6338 -5069 666 2830 -11443 3011 56 -6410 -8939 13241 8416 -8555 11200 -4881 5314 -1983 11332 -6747 3231 -5162 -18959 2602 -12607 8627 -332 -1401 9620 -9224 3839 -2024 -1915 3938 4605 5528 13652 -4503 14388 -9214 7610 2691 -12352 -1421 -2092 -2689 12305 -8162 10387 3971 -2660 -273 7041 1963 -6691 8026 500 5308 442 -1500 -4083 -4179 4392 -10798 -6441 -5090 -7418 4435 -555 1044 -8002 5479 -3484 -1014 3295 148 3493 -1974 11515 1203 -5704 -10067 -4993 12600 -7781 11223 1728 6645 3719 4787 2016 -1181 -100 -910 2657 -382 3717 8071 -624 -1458 -7708 4954 -12315 10890 -6611 -10173 6690 2116 5826 3545 -12046 7932 -7654 44 -4280 11659 698 7325 4370 -100 -5704 -8017 11677 1425 392 -9643 5040 8807 -12945 -4325 -10209 10852 -3938 -2208 2159 -495 -7466 2608 4037 586 2054 10544 -9552 8141 5261 7314 4368 2271 3098 8472 3153 -1585 2990 -4480 -8300 7029 5772 -5168 636 2600 -11851 2645 51 -6199 SO 20190609T111045.0Z 7099.465799 504 1 32.01 2 88.24 60.37 148.38 127.65 0.00 1 0.00 1 0 22 5.268e-02 5.197e-02 5.318e-02 5.235e-02 -3.636185e+03 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