File name: Pandora206s1_BuffaloNY_20221018_L2Fit_fout2c4d20220512p1-8.txt File generation date: 20241121T042352.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: ---- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 206 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora206_OF_v2d20211008.txt Instrument calibration file used: Pandora206s1_CF_v4d20220512.txt Level 1 file used: Pandora206s1_BuffaloNY_20221018_L1_smca1c4d20220512p1-8.txt Full location name: University at Buffalo Short location name: BuffaloNY Country of location: Canada Location latitude [deg]: 43.0015 Location longitude [deg]: -78.7869 Location altitude [m]: 190 Local noon date: 20221018 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2154 305.3564 305.4973 305.6383 305.7792 305.9201 306.0611 306.2020 306.3428 306.4837 306.6246 306.7654 306.9063 307.0471 307.1879 307.3287 307.4695 307.6103 307.7511 307.8918 308.0326 308.1733 308.3140 308.4548 308.5955 308.7362 308.8768 309.0175 309.1582 309.2988 309.4394 309.5801 309.7207 309.8613 310.0019 310.1424 310.2830 310.4236 310.5641 310.7046 310.8451 310.9857 311.1261 311.2666 311.4071 311.5476 311.6880 311.8285 311.9689 312.1093 312.2497 312.3901 312.5305 312.6708 312.8112 312.9515 313.0919 313.2322 313.3725 313.5128 313.6531 313.7934 313.9336 314.0739 314.2141 314.3543 314.4946 314.6348 314.7750 314.9151 315.0553 315.1955 315.3356 315.4758 315.6159 315.7560 315.8961 316.0362 316.1763 316.3163 316.4564 316.5964 316.7364 316.8765 317.0165 317.1565 317.2964 317.4364 317.5764 317.7163 317.8563 317.9962 318.1361 318.2760 318.4159 318.5558 318.6956 318.8355 318.9753 319.1152 319.2550 319.3948 319.5346 319.6744 319.8141 319.9539 320.0937 320.2334 320.3731 320.5128 320.6525 320.7922 320.9319 321.0716 321.2112 321.3509 321.4905 321.6301 321.7697 321.9093 322.0489 322.1885 322.3280 322.4676 322.6071 322.7467 322.8862 323.0257 323.1652 323.3046 323.4441 323.5836 323.7230 323.8624 324.0018 324.1413 324.2806 324.4200 324.5594 324.6988 324.8381 324.9774 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221018T125813.8Z 8326.540437 253 1 29.90 2 76.15 117.90 22.81 218.23 0.00 1 0.00 1 0 25 2.780e-01 1.133e-02 2.422e-01 9.504e-03 5.838138e-01 5.037581e-03 6.751001e-03 -6.000000e+00 1.582840e-01 225.27 -2.00 3.55 -2.00 320.76 0.00e+00 6.477470e-04 2.089424e-03 1.207968e-03 -6.000000e+00 8.522011e-03 281.31 -2.00 20.00 -2.00 320.16 0.00e+00 4.081 0.001 302.00 328.00 3 4.5969e+00 1.5818e-02 5.0591e-02 -6.0000e+00 3.9331e-01 8.6971e-02 2.0748e-02 3.1999e-02 -6.0000e+00 4.3124e-01 -6.4374e-03 2.0711e-02 1.5748e-02 -6.0000e+00 2.5057e-01 -7.8383e-03 1.0275e-02 4.6814e-03 -6.0000e+00 1.0736e-01 4.8851e-05 -1.3529e-03 2.6938e-04 5.1746e-05 -6.0000e+00 7.6118e-03 1.0107e-02 -2.8726e-04 12 8 8 10 0 0 99.99 17.67 0.85 0.01011 -0.00006 27 27 2 8 0 1107.370 15.00 17.67 12.16 21.27 21.06 12.5 909.46 -85828 -51937 900000 900000 900000 900000 900000 900000 -155681 900000 900000 900000 -84182 900000 -54023 48169 -31798 20810 15650 -1510 102898 -7005 160141 -48376 34295 -11083 32254 -22703 19971 -13060 30845 -27563 16963 2485 11987 16140 -765 31499 45905 20955 -8375 12867 -5753 316 -4466 -1075 -14830 -5094 -3757 -1021 -153 3723 9454 -7277 8590 -3255 8750 -3828 6274 -5694 1836 234 -1812 3355 245 2517 -1504 2593 -1013 925 -8 2367 -464 2693 2295 1897 -712 2392 -113 -1431 -995 662 -460 -1122 -27 -1057 1844 -823 743 298 747 -895 1445 -1774 926 -3157 1462 1695 -15 191 -931 -38 -2747 926 -1723 -1155 -1072 -159 -57 -210 -459 527 416 -583 54 781 -248 -65 -410 -449 -206 -159 1294 77 -503 1260 681 1998 243 1156 -293 443 -316 114 -433 -118 20 -84 -22 -157 582 -510 -542 -794 -480 900000 900000 900000 900000 900000 900000 -3933 900000 900000 900000 -1707 900000 -1269 499 -781 346 295 -36 952 -179 1481 -2151 749 -406 776 -899 502 -503 913 -1638 778 138 563 741 -47 1690 2650 1789 -1064 1405 -794 42 -623 -148 -2374 -761 -576 -163 -27 705 1840 -1823 1932 -856 2101 -1028 1473 -1489 466 67 -600 1177 90 862 -532 907 -411 410 -4 1160 -228 1250 969 717 -260 864 -48 -722 -556 412 -312 -805 -20 -867 1532 -718 632 242 555 -656 993 -1308 722 -2948 1495 1968 -18 231 -1055 -38 -2622 889 -1842 -1281 -1255 -197 -77 -306 -730 858 664 -892 76 1096 -358 -95 -638 -723 -325 -240 1938 111 -701 1657 869 2677 374 1880 -524 825 -618 234 -929 -262 46 -193 -49 -338 1215 -1017 -1060 SS 20221018T130608.1Z 8326.545928 256 1 46.48 2 74.88 119.43 23.74 222.04 0.00 1 0.00 1 0 25 1.816e-01 5.144e-03 2.153e-02 8.022e-04 5.448283e-01 4.068925e-04 6.255978e-03 -6.000000e+00 1.004103e-01 225.27 -2.00 3.55 -2.00 320.51 0.00e+00 1.145296e-03 1.566072e-04 3.811711e-04 -6.000000e+00 4.461582e-03 281.31 -2.00 20.00 -2.00 319.90 0.00e+00 3.760 0.001 302.00 328.00 3 9.2071e-01 1.2492e-03 4.6375e-02 -6.0000e+00 2.4826e-01 2.3127e-02 1.5871e-03 2.8510e-02 -6.0000e+00 2.7085e-01 -8.2976e-03 1.4897e-03 1.4436e-02 -6.0000e+00 1.6151e-01 -5.4385e-03 7.4776e-04 4.4936e-03 -6.0000e+00 6.8721e-02 2.8435e-03 -1.0147e-04 2.2083e-05 4.8097e-05 -6.0000e+00 4.6345e-03 8.4568e-03 -2.3523e-05 10 0 0 10 0 0 99.92 17.67 0.28 0.00846 0.00769 1244 384 1 8 0 36.650 15.00 17.67 12.35 21.27 21.06 12.8 912.64 -77826 -60837 -59879 -53301 -72933 -65112 -56801 -63500 -42818 -51079 -46351 -41088 -36150 -27400 -13628 -15222 -7887 -10694 -7946 -7165 -6416 -7411 -8684 -6842 -6688 -5915 -6465 -8105 -13101 -6558 -5965 -2154 133 -3343 -3957 -5674 -4041 -2415 -704 -237 -582 -274 896 -677 1349 385 442 676 268 694 2084 1417 1821 2223 794 1947 915 832 426 689 1343 1778 2456 2598 913 884 -97 -303 907 575 827 474 572 459 -57 -278 -749 -1104 -465 -826 -893 -905 -2005 -1333 -1142 -505 -105 316 652 689 739 470 185 128 315 -52 542 703 176 -203 -384 -886 -840 -494 -978 -1059 -737 -563 -244 328 603 411 358 160 -170 67 -93 186 -194 -203 -245 3 273 296 610 151 374 635 354 279 144 -35 -333 -127 -89 -143 144 154 -26 -20 -48 -233 -248 -895 -676 -703 -555 -833 -698 -622 -854 -536 -751 -667 -636 -670 -581 -311 -414 -220 -336 -261 -247 -224 -260 -331 -282 -296 -276 -307 -372 -612 -312 -333 -134 9 -254 -281 -415 -330 -231 -75 -30 -82 -41 138 -107 212 62 72 113 46 127 420 318 441 583 222 556 272 244 122 194 394 576 893 1048 380 348 -38 -122 402 296 462 275 324 245 -28 -121 -308 -461 -218 -458 -571 -655 -1576 -1095 -1008 -433 -94 287 587 642 634 377 142 102 281 -48 579 851 227 -255 -448 -934 -895 -503 -1087 -1231 -902 -735 -345 511 942 662 564 260 -257 98 -137 288 -322 -349 -415 4 432 447 877 210 499 898 565 490 253 -64 -639 -256 -193 -323 330 360 -61 -45 -100 -463 -484 SS 20221018T134058.9Z 8326.570126 269 1 3.93 2 69.54 126.50 28.53 236.09 0.00 1 0.00 1 0 17 4.563e-02 5.628e-03 1.961e-02 1.978e-03 4.193362e-01 9.731209e-04 4.965751e-03 -6.000000e+00 2.522491e-02 225.26 -2.00 3.55 -2.00 319.11 0.00e+00 9.507124e-04 2.408531e-04 1.731538e-04 -6.000000e+00 1.120820e-03 281.30 -2.00 20.00 -2.00 318.42 0.00e+00 2.832 0.000 302.00 328.00 3 1.6687e+00 2.6909e-03 3.5151e-02 -6.0000e+00 6.2366e-02 1.5861e-02 3.1372e-03 2.1706e-02 -6.0000e+00 6.8043e-02 -8.8971e-03 2.3728e-03 1.0755e-02 -6.0000e+00 4.0574e-02 -8.4487e-04 1.2539e-03 3.2295e-03 -6.0000e+00 1.7264e-02 3.7277e-03 -1.1609e-04 5.4114e-05 3.2093e-05 -6.0000e+00 1.1643e-03 8.3053e-03 -2.7071e-05 12 1 1 12 1 1 99.43 17.67 0.25 0.00831 0.00743 39 164 1 8 0 91.700 15.00 17.67 13.44 21.27 21.06 12.7 917.48 -16592 -14342 -8758 -18163 -17289 -18762 -11698 -20070 -10986 -13652 -8875 -11387 -5813 -2469 -1669 -1597 -3338 -2468 -2383 3212 -3358 -424 -443 -731 -36 -2260 516 -1145 -2200 -2249 717 -630 6248 -1772 -3706 -3396 -2177 -1971 -176 -2276 -964 -578 -290 -692 94 -84 -832 -438 -300 396 1008 874 1102 1123 1330 1428 774 1039 875 213 981 968 1755 1818 651 65 -178 -598 739 674 640 984 284 568 -170 -210 -914 327 -791 -585 -969 -1157 -2023 -1394 -1180 -627 -414 349 636 395 1002 409 164 29 267 188 321 660 61 -277 -336 -873 -596 -225 -835 -777 -808 -554 -329 377 238 140 68 37 -44 202 153 49 -107 -74 -432 -28 604 387 601 302 719 882 435 604 271 117 -245 66 -138 -259 205 259 -187 -45 -267 -529 -385 -486 -459 -277 -589 -494 -543 -345 -732 -413 -561 -347 -499 -290 -143 -115 -114 -259 -203 -208 277 -314 -38 -42 -75 -4 -264 59 -137 -252 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