File name: Pandora206s1_BuffaloNY_20230703_L2Fit_fout2c4d20220512p1-8.txt File generation date: 20241121T054656.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Kang Sun Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 206 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora206_OF_v3d20211008.txt Instrument calibration file used: Pandora206s1_CF_v4d20220512.txt Level 1 file used: Pandora206s1_BuffaloNY_20230703_L1_smca1c4d20220512p1-8.txt Full location name: University at Buffalo Short location name: BuffaloNY Country of location: Canada Location latitude [deg]: 43.0015 Location longitude [deg]: -78.7869 Location altitude [m]: 190 Local noon date: 20230703 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2154 305.3564 305.4973 305.6383 305.7792 305.9201 306.0611 306.2020 306.3428 306.4837 306.6246 306.7654 306.9063 307.0471 307.1879 307.3287 307.4695 307.6103 307.7511 307.8918 308.0326 308.1733 308.3140 308.4548 308.5955 308.7362 308.8768 309.0175 309.1582 309.2988 309.4394 309.5801 309.7207 309.8613 310.0019 310.1424 310.2830 310.4236 310.5641 310.7046 310.8451 310.9857 311.1261 311.2666 311.4071 311.5476 311.6880 311.8285 311.9689 312.1093 312.2497 312.3901 312.5305 312.6708 312.8112 312.9515 313.0919 313.2322 313.3725 313.5128 313.6531 313.7934 313.9336 314.0739 314.2141 314.3543 314.4946 314.6348 314.7750 314.9151 315.0553 315.1955 315.3356 315.4758 315.6159 315.7560 315.8961 316.0362 316.1763 316.3163 316.4564 316.5964 316.7364 316.8765 317.0165 317.1565 317.2964 317.4364 317.5764 317.7163 317.8563 317.9962 318.1361 318.2760 318.4159 318.5558 318.6956 318.8355 318.9753 319.1152 319.2550 319.3948 319.5346 319.6744 319.8141 319.9539 320.0937 320.2334 320.3731 320.5128 320.6525 320.7922 320.9319 321.0716 321.2112 321.3509 321.4905 321.6301 321.7697 321.9093 322.0489 322.1885 322.3280 322.4676 322.6071 322.7467 322.8862 323.0257 323.1652 323.3046 323.4441 323.5836 323.7230 323.8624 324.0018 324.1413 324.2806 324.4200 324.5594 324.6988 324.8381 324.9774 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230703T132908.8Z 8584.561907 219 1 28.00 2 51.16 93.81 131.12 267.77 0.00 1 0.00 1 0 17 1.125e-01 2.340e-02 8.065e-02 1.466e-02 2.673334e-01 7.357401e-03 3.151833e-03 -6.000000e+00 6.428477e-02 232.93 -2.00 3.55 -2.00 318.09 0.00e+00 -9.390697e-04 1.302399e-03 7.848123e-05 -6.000000e+00 2.823111e-03 286.18 -2.00 20.00 -2.00 317.27 0.00e+00 1.591 0.000 302.00 328.00 3 8.1050e+00 2.0045e-02 2.1290e-02 -6.0000e+00 1.6164e-01 1.7060e-04 2.2732e-02 1.4176e-02 -6.0000e+00 1.7486e-01 5.9098e-02 1.4413e-02 6.8815e-03 -6.0000e+00 1.0393e-01 -2.8813e-02 7.3505e-03 2.0067e-03 -6.0000e+00 4.3959e-02 2.3326e-05 -1.9706e-04 4.1123e-04 1.9749e-05 -6.0000e+00 2.8687e-03 -2.0696e-02 3.3500e-04 12 8 8 10 0 0 77.47 18.54 1.71 -0.02070 -0.02218 7 7 2 8 0 4000.000 15.00 18.54 26.65 21.88 21.98 17.7 1030.08 -46659 74053 -16314 33373 8567 20636 6743 33152 7546 23544 29764 38591 24817 2426 -12656 6587 20561 6183 -757 -3582 21109 -6494 2743 2940 8738 -5262 -3478 1328 -5671 -4100 -5882 18298 -3082 17244 3046 1020 290 -1048 7715 993 2117 -1819 -757 -5410 3454 -4340 -2239 -15365 -377 -4117 1916 -280 -3344 3903 5000 4624 -1127 2750 315 -5073 -4593 2718 -1428 1723 1221 1965 -2119 209 1346 -1287 494 -1142 1896 1677 3980 -2308 3574 -2299 6278 -3905 -1605 4534 -2196 426 -2258 677 1456 2818 -566 2473 -2078 -2479 929 -3249 -2136 -378 1311 1052 1665 1440 2481 -1741 -396 -2867 -84 -2765 1062 -451 770 1438 2600 2154 -2747 -1026 -2717 -233 -4597 -1446 -3126 1127 680 807 305 1831 3306 893 -1431 -1160 -565 -1258 1816 -1141 398 -464 225 -312 -26 2756 920 889 1467 -1377 -3215 -4878 2753 -1465 1801 518 1082 420 1849 599 1727 2099 2501 2070 281 -1950 939 2665 961 -132 -669 3174 -1273 501 576 1713 -1245 -823 282 -1180 -817 -1270 3445 -759 3789 716 234 74 -302 2462 405 944 -881 -375 -2842 1647 -2242 -1112 -8462 -175 -1979 917 -148 -1923 2216 2917 2757 -730 1715 196 -3299 -3044 1795 -1069 1346 965 1412 -1467 141 914 -1028 429 -1055 1706 1458 3155 -1802 2365 -1514 3926 -3059 -1339 3946 -2192 431 -2516 789 1717 3391 -711 2994 -2423 -2648 903 -3147 -2157 -401 1519 1364 2219 1946 3113 -2098 -438 -3340 -105 -3726 1437 -650 1110 2195 4158 3512 -4527 -1546 -3927 -306 -6275 -1992 -4704 1742 1080 1259 467 2643 4583 1211 -1874 -1511 -787 -1822 2691 -1792 625 -759 390 -555 -47 4981 1709 1653 2611 -2431 -5620 SS 20230703T143039.7Z 8584.604626 237 1 28.00 2 40.11 106.25 141.69 278.48 0.00 1 0.00 1 0 17 4.385e-02 1.672e-02 2.555e-02 9.386e-03 2.293688e-01 4.748069e-03 2.728553e-03 -6.000000e+00 2.504498e-02 232.93 -2.00 3.55 -2.00 317.03 0.00e+00 -2.945995e-04 6.275783e-04 2.429592e-04 -6.000000e+00 1.100874e-03 286.18 -2.00 20.00 -2.00 316.22 0.00e+00 1.306 0.000 302.00 328.00 3 7.8693e+00 1.2619e-02 1.7806e-02 -6.0000e+00 6.2972e-02 7.4977e-02 1.4158e-02 1.2102e-02 -6.0000e+00 6.8143e-02 2.5812e-03 8.3388e-03 5.8066e-03 -6.0000e+00 4.0496e-02 -8.8197e-03 3.9976e-03 1.6660e-03 -6.0000e+00 1.7116e-02 4.1071e-05 -8.6679e-04 2.5944e-04 1.7400e-05 -6.0000e+00 1.1189e-03 -2.0235e-02 1.1471e-04 12 8 8 10 0 0 82.18 18.52 1.12 -0.02024 -0.02675 7 7 2 8 0 4000.000 14.99 18.52 26.00 21.88 21.98 17.7 1026.68 -10753 4845 202 -6705 -2541 3297 -4516 1413 -7706 -3025 -2491 3105 -6420 1148 -9721 38645 7736 348 2449 3773 9087 -7280 19 2887 1995 1 1235 -498 -839 893 1180 -1192 2452 4161 -234 -6031 -6217 -3457 -125 -327 580 -3602 2003 -384 -1302 -565 -1627 -6358 -1130 -2593 -503 -891 81 1839 2028 2853 -845 2146 394 -1813 200 9508 974 3625 639 139 -975 -1354 495 -19 175 157 3439 1151 -940 -834 735 -2937 -2011 -2620 -1833 -1159 -1972 -823 115 -61 461 1411 382 642 -196 -262 -1054 -2721 -1342 -1394 55 948 1368 241 741 -1438 -804 -2238 -60 -2101 -373 4416 -8 -371 608 967 -1563 -114 -735 -261 -1563 -69 -891 859 -503 1684 604 847 1568 165 -1217 -1020 -574 -208 1486 -46 410 -832 -384 -95 1500 993 1212 529 -54 -1760 -2098 -1600 677 30 -1020 -320 369 -577 190 -1274 -510 -407 493 -1202 226 -2405 6733 1832 91 651 1023 2388 -2212 5 853 623 0 407 -161 -248 251 348 -381 817 1424 -77 -2004 -2265 -1409 -57 -178 342 -2297 1243 -246 -832 -357 -1016 -4018 -659 -1514 -302 -575 54 1278 1451 2049 -643 1579 288 -1337 148 6862 828 3206 581 116 -752 -1008 378 -17 169 153 3353 1107 -861 -682 548 -2120 -1480 -2184 -1642 -1139 -2084 -892 128 -73 580 1816 501 807 -229 -286 -1053 -2628 -1341 -1534 67 1214 1855 323 926 -1747 -905 -2638 -75 -2770 -504 5948 -11 -562 962 1538 -2441 -168 -990 -336 -2027 -91 -1245 1266 -770 2489 882 1179 2107 214 -1510 -1256 -752 -288 2128 -67 596 -1264 -619 -161 2550 1686 2074 912 -90 -2892 -3363 SS 20230703T153614.5Z 8584.650168 264 1 28.00 2 29.28 124.98 152.49 294.18 0.00 1 0.00 1 0 25 1.945e-02 1.350e-02 1.391e-02 6.523e-03 1.879794e-01 3.292002e-03 2.209993e-03 -6.000000e+00 1.111663e-02 232.93 -2.00 3.55 -2.00 316.36 0.00e+00 8.367097e-04 3.747863e-04 4.927393e-05 -6.000000e+00 4.883625e-04 286.19 -2.00 20.00 -2.00 315.59 0.00e+00 1.146 0.000 302.00 328.00 3 7.6408e+00 8.6734e-03 1.5076e-02 -6.0000e+00 2.7951e-02 3.3293e-02 9.6893e-03 9.8221e-03 -6.0000e+00 3.0241e-02 1.4838e-02 5.5829e-03 4.7354e-03 -6.0000e+00 1.7973e-02 -8.6319e-03 2.5895e-03 1.3936e-03 -6.0000e+00 7.6002e-03 6.5950e-05 4.0792e-04 1.7875e-04 1.3903e-05 -6.0000e+00 4.9631e-04 -2.1054e-02 2.3225e-04 12 8 8 10 0 0 56.28 18.51 1.22 -0.02105 -0.01799 7 7 2 8 0 4000.000 15.01 18.51 28.18 21.88 21.88 18.0 1041.53 -4241 7754 -7040 384 3467 -3651 -393 -232 2540 -4414 582 -4676 -842 -521 -626 1158 -609 2884 2724 2672 1130 1814 -1403 2410 -1361 785 -1304 1052 -2558 -1008 291 461 3150 2846 -94 -4495 1761 -3112 2524 -1506 609 -1570 670 -956 1158 -304 -2042 -5072 -1971 -920 -418 1623 -1232 2809 1282 1082 477 1052 377 45 -989 -645 1884 3089 1031 -1299 -421 -2009 1616 -780 1165 890 2894 466 1916 -652 -273 -2555 -3029 -1478 -2018 -241 -2227 -666 -629 82 820 1853 530 1749 -870 -1126 -458 -1666 -196 -1020 566 1443 1147 -635 1057 -1481 -1787 -1798 -317 -1183 -437 -52 21 995 582 1160 -821 542 -1953 -141 -2629 -489 -2358 1486 517 1280 1169 831 2222 -176 -17 -363 603 -1003 1875 -1484 346 -449 135 -22 1032 1431 236 485 12 -1263 -2230 -831 1468 -1582 75 566 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