File name: Pandora206s1_BuffaloNY_20230908_L2Fit_fout2c4d20220512p1-8.txt File generation date: 20241121T061243.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Kang Sun Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 206 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora206_OF_v3d20211008.txt Instrument calibration file used: Pandora206s1_CF_v4d20220512.txt Level 1 file used: Pandora206s1_BuffaloNY_20230908_L1_smca1c4d20220512p1-8.txt Full location name: University at Buffalo Short location name: BuffaloNY Country of location: Canada Location latitude [deg]: 43.0015 Location longitude [deg]: -78.7869 Location altitude [m]: 190 Local noon date: 20230908 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2154 305.3564 305.4973 305.6383 305.7792 305.9201 306.0611 306.2020 306.3428 306.4837 306.6246 306.7654 306.9063 307.0471 307.1879 307.3287 307.4695 307.6103 307.7511 307.8918 308.0326 308.1733 308.3140 308.4548 308.5955 308.7362 308.8768 309.0175 309.1582 309.2988 309.4394 309.5801 309.7207 309.8613 310.0019 310.1424 310.2830 310.4236 310.5641 310.7046 310.8451 310.9857 311.1261 311.2666 311.4071 311.5476 311.6880 311.8285 311.9689 312.1093 312.2497 312.3901 312.5305 312.6708 312.8112 312.9515 313.0919 313.2322 313.3725 313.5128 313.6531 313.7934 313.9336 314.0739 314.2141 314.3543 314.4946 314.6348 314.7750 314.9151 315.0553 315.1955 315.3356 315.4758 315.6159 315.7560 315.8961 316.0362 316.1763 316.3163 316.4564 316.5964 316.7364 316.8765 317.0165 317.1565 317.2964 317.4364 317.5764 317.7163 317.8563 317.9962 318.1361 318.2760 318.4159 318.5558 318.6956 318.8355 318.9753 319.1152 319.2550 319.3948 319.5346 319.6744 319.8141 319.9539 320.0937 320.2334 320.3731 320.5128 320.6525 320.7922 320.9319 321.0716 321.2112 321.3509 321.4905 321.6301 321.7697 321.9093 322.0489 322.1885 322.3280 322.4676 322.6071 322.7467 322.8862 323.0257 323.1652 323.3046 323.4441 323.5836 323.7230 323.8624 324.0018 324.1413 324.2806 324.4200 324.5594 324.6988 324.8381 324.9774 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230908T125708.9Z 8651.539686 229 1 24.01 2 67.24 104.19 16.48 206.94 0.00 1 0.00 1 0 17 3.124e-01 3.722e-02 2.292e-01 2.482e-02 3.128837e-01 1.260835e-02 3.693886e-03 -6.000000e+00 1.772102e-01 229.71 -2.00 3.55 -2.00 318.90 0.00e+00 3.180040e-03 2.927820e-03 7.715481e-04 -6.000000e+00 8.735561e-03 286.00 -2.00 20.00 -2.00 318.12 0.00e+00 2.563 0.000 302.00 328.00 3 7.6620e+00 3.4908e-02 3.0392e-02 -6.0000e+00 4.4471e-01 5.0123e-02 4.0627e-02 1.8496e-02 -6.0000e+00 4.8375e-01 6.9927e-02 2.9709e-02 8.1518e-03 -6.0000e+00 2.8549e-01 -3.0341e-02 1.5587e-02 4.1833e-03 -6.0000e+00 1.2308e-01 1.2984e-05 -9.3221e-04 7.1663e-04 3.1284e-05 -6.0000e+00 8.0882e-03 -2.1737e-02 -8.4907e-06 12 8 8 10 0 0 -132.70 18.17 4.41 -0.02174 -0.02874 6 6 2 8 0 4000.000 15.00 18.17 25.05 21.48 21.69 19.0 979.11 900000 5292 900000 182194 118189 79783 -22738 160725 900000 900000 -1361 900000 -80355 31475 -28420 62860 83440 14632 61117 24759 71098 13196 28187 8384 24211 -23835 58859 -16010 45342 15778 19239 -18753 39660 -4186 39864 8598 21351 31823 13234 8695 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1499 2 -2815 1751 -6040 -191 4929 -1340 2885 1341 -1696 446 669 593 -1943 1365 -2954 -3123 2907 -3343 -801 1895 1885 -6940 43 1236 -2 -1417 -2952 -686 -1090 3217 -372 4569 -3047 6646 -2010 430 1053 2306 -3002 2899 1689 -2169 1165 -4329 3539 -4537 4997 -752 4381 -55 -5869 316 SS 20230908T140826.0Z 8651.589190 267 1 24.01 2 55.14 119.06 25.66 242.51 0.00 1 0.00 1 0 17 4.142e-02 1.679e-02 4.471e-02 1.240e-02 2.477865e-01 6.175621e-03 2.959393e-03 -6.000000e+00 2.338573e-02 229.70 -2.00 3.55 -2.00 317.56 0.00e+00 -1.125477e-03 9.562960e-04 2.356150e-04 -6.000000e+00 1.038859e-03 286.00 -2.00 20.00 -2.00 316.76 0.00e+00 1.745 0.000 302.00 328.00 3 7.7005e+00 1.6471e-02 2.1493e-02 -6.0000e+00 5.8338e-02 6.1702e-02 1.8621e-02 1.2904e-02 -6.0000e+00 6.3280e-02 3.9590e-02 1.1357e-02 6.3356e-03 -6.0000e+00 3.7706e-02 -2.3023e-02 5.6612e-03 1.8696e-03 -6.0000e+00 1.6049e-02 3.1133e-05 -1.1113e-05 3.4520e-04 1.8505e-05 -6.0000e+00 1.0559e-03 -2.1761e-02 1.5769e-04 12 8 8 10 0 0 -182.47 18.15 0.49 -0.02176 -0.02184 6 6 2 8 0 4000.000 15.00 18.15 27.10 21.48 21.69 19.2 991.70 721 9969 7035 -5938 20224 -6475 9526 -12819 3717 9308 13060 -10734 -10603 -6956 -4226 164 4309 9399 -605 -5911 2140 -1658 -2653 586 1483 -822 -1058 -1042 1769 3459 -428 -6225 11655 3919 -2333 -5648 -4504 -1707 1907 -3993 -2328 494 2423 -269 4620 -2583 -4257 9682 -4286 464 -1768 3632 -549 -602 1124 864 122 3368 670 -2511 -1068 3161 -707 1481 466 -2344 -884 -4523 3068 -1204 2477 -1639 2794 1721 1330 1150 -611 690 -3935 -1728 -2019 2123 -636 -1449 -143 693 1392 1077 -650 -55 656 -1714 1275 -2795 290 -5673 2232 282 1486 -374 3028 82 -908 -657 81 -59 -662 1079 500 -1299 872 1036 -3014 -657 -1240 477 -480 -2122 -812 407 150 135 1845 -626 1994 -355 447 -906 2416 -30 1527 -375 -666 697 932 689 -386 1213 -4 1098 -910 -908 -2215 67 934 702 -637 1499 -596 799 -1468 422 1075 1426 -1444 -1591 -1143 -768 32 827 1772 -131 -1403 480 -381 -630 144 382 -227 -296 -281 422 789 -107 -1768 3010 1145 -668 -1606 -1393 -594 773 -1977 -1245 267 1325 -152 2463 -1479 -2423 4792 -2308 244 -1006 2104 -338 -393 745 584 85 2265 452 -1726 -742 2255 -569 1248 397 -1866 -662 -3393 2244 -1019 2223 -1601 2613 1567 1132 904 -439 459 -2843 -1380 -1813 1960 -645 -1538 -160 806 1691 1355 -837 -68 759 -1850 1254 -2736 290 -6446 2596 361 1996 -499 3775 97 -1044 -755 102 -78 -915 1489 725 -2040 1415 1696 -4926 -972 -1736 613 -619 -2901 -1178 606 229 209 2745 -911 2665 -479 564 -1157 3202 -42 2215 -569 -1026 1095 1557 1176 -682 2159 -7 1910 -1557 -1544 -3715 SS 20230908T143905.5Z 8651.610480 278 1 23.00 2 50.44 126.61 30.71 251.56 0.00 1 0.00 1 0 25 1.074e-02 7.054e-03 7.816e-03 3.706e-03 2.083837e-01 1.858332e-03 2.559818e-03 -6.000000e+00 6.059520e-03 229.70 -2.00 3.55 -2.00 316.30 0.00e+00 4.688282e-04 2.107761e-04 5.684564e-05 -6.000000e+00 2.693209e-04 286.00 -2.00 20.00 -2.00 315.54 0.00e+00 1.567 0.000 302.00 328.00 3 6.1836e+00 4.8547e-03 1.8892e-02 -6.0000e+00 1.5116e-02 1.7680e-02 5.4311e-03 1.0964e-02 -6.0000e+00 1.6399e-02 8.4180e-03 3.1429e-03 5.3513e-03 -6.0000e+00 9.7710e-03 -5.2274e-03 1.4730e-03 1.5009e-03 -6.0000e+00 4.1568e-03 1.8582e-04 -1.4234e-04 1.0111e-04 1.6721e-05 -6.0000e+00 2.7376e-04 -1.9516e-02 1.0851e-04 12 9 1 12 1 1 99.92 18.15 0.34 -0.01952 -0.02059 5 7 1 8 0 3832.540 15.00 18.15 28.67 21.58 21.69 19.3 1001.55 -1541 2445 -2527 -2300 200 -2566 -897 -2500 1859 -880 2215 -3094 -3227 -1581 1114 -305 337 -983 743 673 464 -223 205 2016 -320 687 295 499 -514 1959 1182 129 1814 562 -1590 -2306 -1503 -1256 1012 -251 -663 -1456 892 -1115 531 -1344 -993 -1588 -1245 460 226 1044 933 1652 389 977 752 519 119 -48 436 1774 1180 1697 2016 -30 -669 -876 728 -158 493 -485 496 611 187 -578 -619 -899 -811 -1182 -1094 -1012 -2279 -1023 -868 -759 -154 -10 556 545 184 457 127 -356 336 -48 936 835 113 -62 216 -862 -1026 -431 -678 -1080 -871 -540 64 474 775 560 -262 181 -202 83 -103 169 -235 343 -394 65 618 248 814 327 459 786 1154 -44 373 -602 201 66 -110 218 92 339 -112 -464 -623 -218 -622 -285 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