File name: Pandora206s1_BuffaloNY_20231011_L2Fit_fwvt1c4d20220512p1-8.txt File generation date: 20241121T063804.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Kang Sun Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 206 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora206_OF_v3d20211008.txt Instrument calibration file used: Pandora206s1_CF_v4d20220512.txt Level 1 file used: Pandora206s1_BuffaloNY_20231011_L1_smca1c4d20220512p1-8.txt Full location name: University at Buffalo Short location name: BuffaloNY Country of location: Canada Location latitude [deg]: 43.0015 Location longitude [deg]: -78.7869 Location altitude [m]: 190 Local noon date: 20231011 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1793 Nominal wavelengths inside fitting window [nm]: 492.0227 492.1437 492.2647 492.3857 492.5066 492.6276 492.7485 492.8694 492.9903 493.1112 493.2321 493.3529 493.4738 493.5946 493.7154 493.8362 493.9569 494.0777 494.1984 494.3191 494.4398 494.5605 494.6812 494.8018 494.9224 495.0430 495.1636 495.2842 495.4048 495.5253 495.6459 495.7664 495.8869 496.0073 496.1278 496.2482 496.3687 496.4891 496.6095 496.7298 496.8502 496.9705 497.0909 497.2112 497.3315 497.4517 497.5720 497.6922 497.8125 497.9327 498.0528 498.1730 498.2932 498.4133 498.5334 498.6535 498.7736 498.8937 499.0137 499.1338 499.2538 499.3738 499.4938 499.6137 499.7337 499.8536 499.9735 500.0934 500.2133 500.3332 500.4530 500.5729 500.6927 500.8125 500.9322 501.0520 501.1717 501.2915 501.4112 501.5309 501.6505 501.7702 501.8898 502.0095 502.1291 502.2487 502.3682 502.4878 502.6073 502.7268 502.8464 502.9658 503.0853 503.2048 503.3242 503.4436 503.5630 503.6824 503.8018 503.9211 504.0404 504.1598 504.2790 504.3983 504.5176 504.6368 504.7561 504.8753 504.9945 505.1136 505.2328 505.3519 505.4711 505.5902 505.7093 505.8283 505.9474 506.0664 506.1854 506.3044 506.4234 506.5424 506.6613 506.7803 506.8992 507.0181 507.1370 507.2558 507.3747 507.4935 507.6123 507.7311 507.8499 507.9687 508.0874 508.2061 508.3248 508.4435 508.5622 508.6808 508.7995 508.9181 509.0367 509.1553 509.2739 509.3924 509.5109 509.6295 509.7480 509.8664 509.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231011T114052.6Z 8684.486719 120 1 26.10 2 87.76 101.77 53.66 113.05 0.00 1 0.00 1 0 36 6.501e-03 6.443e-03 1.303e-04 1.301e-04 1.203884e+04 9.210961e+00 8.047604e+02 -6.000000e+00 3.693669e+02 282.19 -2.00 20.00 -2.00 505.36 0.00e+00 2.600945e-03 3.641285e-06 1.523363e-04 -6.000000e+00 1.837831e-04 282.19 -2.00 20.00 -2.00 500.72 0.00e+00 1.259517e+00 2.559996e-03 8.448540e-02 -6.000000e+00 1.294130e-01 226.03 -2.00 3.55 -2.00 502.28 0.00e+00 15.408 0.070 489.00 513.00 1 1.0018e+00 1.9650e-04 2.5031e-02 -6.0000e+00 9.9486e-03 -1.7332e-02 4.8804e-05 2.3936e-03 -6.0000e+00 2.5366e-03 7.2342e-02 2.2741e-03 1.3102e-05 1.0017e-04 -6.0000e+00 7.1184e-04 3.2834e-03 -1.3251e-05 12 8 8 10 0 0 -4.68 17.80 3.79 0.00328 0.01906 639 197 1 2 0 40.650 14.99 17.80 13.12 21.38 21.17 18.9 915.78 -1304 -1065 -566 173 609 968 1261 1277 1166 842 412 32 -188 -432 -656 -671 -422 -130 295 458 417 420 385 362 537 591 352 151 -138 -768 -1060 -972 -716 -106 353 427 249 125 -95 -277 -267 -97 119 415 633 781 733 451 53 -361 -864 -1228 -1446 -1311 -775 -159 295 522 578 621 654 738 785 690 588 377 2 -341 -438 -633 -752 -708 -520 -325 -141 -192 -514 -881 -1005 -1064 -1013 -844 -755 -616 -390 -353 -326 -332 -297 -296 -102 153 619 849 685 501 185 -287 -616 -1079 -1370 -1242 -891 -372 50 -42 -211 -400 -527 -395 -63 254 551 828 1053 1111 1149 1203 978 620 364 209 128 328 521 473 505 571 358 401 462 -54 -441 -533 -649 -510 -26 109 187 420 527 460 484 481 382 245 29 -418 -922 -1072 -897 -1229 -991 -540 166 599 952 1261 1265 1158 832 412 32 -184 -421 -636 -654 -416 -128 296 466 419 424 389 369 549 606 361 153 -138 -769 -1047 -961 -704 -107 357 437 255 127 -96 -279 -269 -99 122 431 650 805 754 461 54 -366 -858 -1221 -1427 -1300 -767 -161 298 534 595 640 662 750 802 706 599 380 2 -343 -437 -626 -739 -696 -515 -325 -142 -193 -511 -865 -977 -1029 -979 -820 -739 -608 -388 -347 -322 -327 -292 -291 -101 153 619 846 674 489 176 -273 -573 -994 -1264 -1164 -844 -359 48 -42 -211 -399 -525 -395 -64 254 556 839 1071 1117 1168 1234 1007 635 368 209 129 331 517 473 507 572 359 402 461 -54 -434 -532 -640 -509 -26 110 193 430 546 481 501 500 397 253 30 -431 -943 -1094 -923 SQ 20231011T114118.8Z 8684.487023 120 2 26.22 2 87.68 101.84 53.59 113.15 0.00 1 0.00 1 0 22 6.409e-03 6.355e-03 1.251e-04 1.250e-04 1.189252e+04 8.832475e+00 7.955765e+02 -6.000000e+00 3.641888e+02 282.19 -2.00 20.00 -2.00 505.36 0.00e+00 2.555294e-03 3.503788e-06 1.499353e-04 -6.000000e+00 1.812016e-04 282.19 -2.00 20.00 -2.00 500.71 0.00e+00 1.247412e+00 2.465718e-03 8.352823e-02 -6.000000e+00 1.275817e-01 226.03 -2.00 3.55 -2.00 502.27 0.00e+00 15.204 0.067 489.00 513.00 1 9.5697e-01 1.8946e-04 2.4604e-02 -6.0000e+00 9.8080e-03 -1.6209e-02 4.6980e-05 2.3620e-03 -6.0000e+00 2.5003e-03 7.7968e-02 2.1859e-03 1.2606e-05 9.9813e-05 -6.0000e+00 7.0180e-04 -8.6414e-03 6.8829e-05 12 8 8 10 0 0 5.91 17.80 3.69 -0.00864 0.00652 639 197 1 2 0 40.650 15.00 17.80 13.30 21.38 21.17 18.9 915.78 -1302 -1058 -576 107 559 934 1228 1234 1143 832 395 43 -207 -419 -623 -648 -443 -122 287 447 407 437 346 391 546 581 380 166 -113 -739 -1054 -992 -693 -130 374 400 253 126 -91 -262 -243 -106 146 413 624 764 712 455 69 -324 -847 -1192 -1433 -1309 -779 -179 280 506 584 597 681 728 778 675 595 364 15 -315 -422 -618 -761 -700 -529 -303 -110 -152 -520 -867 -989 -1038 -1021 -832 -744 -602 -354 -333 -306 -342 -302 -279 -95 144 605 836 688 481 201 -285 -594 -1036 -1339 -1202 -890 -345 57 -10 -227 -411 -535 -366 -71 263 545 827 1049 1095 1151 1178 988 584 366 187 91 317 530 434 507 548 352 402 447 -43 -451 -531 -631 -491 -46 126 167 430 533 451 487 457 366 220 32 -441 -904 -1104 -895 -1207 -990 -551 103 542 924 1211 1231 1142 828 390 43 -204 -410 -608 -635 -439 -121 290 449 411 444 352 400 562 589 384 170 -114 -729 -1047 -987 -685 -132 381 413 261 129 -92 -266 -247 -108 148 422 644 792 737 468 71 -329 -845 -1168 -1421 -1280 -775 -179 285 521 593 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2.1080e-03 1.4343e-01 1.8912e-03 1.4259e-05 8.2808e-05 -6.0000e+00 5.9172e-04 -2.1580e-03 3.1803e-05 12 8 8 10 0 0 35.73 17.80 2.95 -0.00216 0.01096 507 406 2 2 0 22.200 15.00 17.80 13.29 21.38 21.17 19.1 917.85 -1152 -946 -533 53 451 749 997 1003 945 674 294 -12 -204 -375 -575 -580 -415 -121 229 388 327 355 305 315 472 499 304 138 -57 -613 -866 -797 -582 -49 358 376 232 151 -56 -217 -193 -91 128 348 520 679 619 394 50 -290 -721 -1038 -1239 -1143 -667 -117 271 431 490 527 576 635 666 567 505 318 -13 -293 -350 -454 -608 -549 -409 -241 -32 -76 -439 -693 -825 -855 -853 -701 -609 -502 -279 -257 -245 -266 -244 -250 -96 79 496 703 577 437 201 -216 -457 -868 -1112 -1014 -755 -304 58 -22 -196 -325 -440 -332 -39 242 487 716 898 885 955 983 809 474 315 170 65 240 412 346 367 455 263 323 387 -69 -417 -460 -575 -445 -42 97 150 366 457 385 422 378 296 182 48 -364 -760 -959 -800 -1084 -898 -518 52 444 754 1001 1018 961 682 295 -12 -204 -372 -568 -575 -417 -122 234 395 335 365 315 327 482 511 311 142 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10 0 0 10 0 0 11.33 17.76 2.27 -0.00979 -0.00155 1971 1971 2 2 0 2.490 15.00 17.76 23.32 21.27 21.17 19.3 977.18 -793 -651 -458 -39 208 415 583 588 570 425 139 -65 -150 -234 -385 -419 -318 -141 154 266 220 276 219 158 295 315 131 50 33 -329 -471 -439 -357 -1 320 300 200 196 38 -115 -122 -80 2 168 280 396 387 218 -14 -210 -505 -662 -838 -812 -503 -148 122 239 321 323 368 399 423 335 304 210 -20 -213 -172 -236 -323 -273 -206 -98 75 81 -180 -346 -375 -392 -420 -266 -237 -191 -18 -66 -34 -72 -96 -134 -81 -1 278 436 350 252 166 -31 -169 -440 -634 -591 -459 -188 45 -67 -128 -202 -290 -246 -20 116 270 418 518 464 439 470 358 148 111 56 -27 135 201 95 214 266 81 160 273 -26 -233 -254 -358 -286 20 90 79 236 299 222 236 234 148 112 55 -178 -497 -632 -528 -796 -643 -463 -40 213 435 621 620 602 446 147 -68 -154 -238 -397 -425 -326 -148 161 282 235 295 230 166 311 332 137 53 34 -340 -478 -445 -367 -1 332 315 210 203 40 -119 -127 -84 2 175 293 416 405 226 -14 -214 -502 -655 -820 -798 -503 -148 122 243 328 329 375 408 434 344 310 212 -20 -213 -170 -231 -314 -265 -201 -97 75 80 -176 -335 -359 -375 -402 -256 -230 -187 -18 -65 -34 -71 -95 -133 -79 -1 278 437 350 248 164 -30 -163 -418 -600 -565 -441 -182 45 -65 -127 -198 -282 -239 -20 114 267 417 521 460 438 468 354 148 109 55 -26 130 194 92 207 257 79 154 261 -25 -222 -238 -336 -271 19 86 77 228 291 217 232 231 146 110 53 -172 -472 -597 -501 SQ 20231011T153043.4Z 8684.646336 219 3 5.03 2 54.21 151.70 34.49 193.46 0.00 1 0.00 1 0 22 3.230e-03 3.222e-03 7.232e-05 7.215e-05 1.181628e+03 4.258565e+00 8.839697e+01 -6.000000e+00 1.835309e+02 282.17 -2.00 20.00 -2.00 505.25 0.00e+00 5.258008e-04 1.995247e-06 3.009314e-05 -6.000000e+00 9.131260e-05 282.17 -2.00 20.00 -2.00 500.35 0.00e+00 7.869662e-02 1.433079e-03 9.520887e-03 -6.000000e+00 6.428051e-02 226.01 -2.00 3.55 -2.00 501.96 0.00e+00 1.705 0.000 489.00 513.00 1 2.1345e-01 1.1023e-04 2.6169e-03 -6.0000e+00 4.9418e-03 1.9109e-03 2.8084e-05 2.4842e-04 -6.0000e+00 1.2594e-03 1.2310e+00 1.1987e-03 7.7166e-06 1.5019e-05 -6.0000e+00 3.5368e-04 -9.2171e-03 9.1766e-05 10 0 0 10 0 0 34.68 17.76 2.27 -0.00922 -0.00090 1971 1971 2 2 0 2.490 15.00 17.76 23.34 21.27 21.17 19.4 977.18 -809 -668 -447 -26 206 426 582 583 566 442 150 -61 -143 -240 -389 -421 -314 -152 143 265 226 269 202 157 306 317 143 50 27 -344 -489 -454 -353 13 326 300 197 182 57 -117 -130 -93 11 155 291 401 379 220 -10 -208 -504 -675 -849 -817 -510 -163 124 250 318 345 383 414 430 331 307 207 -16 -210 -168 -241 -315 -276 -205 -93 90 68 -185 -350 -384 -391 -433 -259 -227 -185 -24 -66 -31 -64 -114 -141 -74 0 270 420 347 252 162 -40 -158 -430 -645 -583 -465 -178 52 -72 -130 -213 -291 -230 -23 121 259 417 501 479 434 473 377 159 124 58 -38 129 208 92 206 270 72 151 259 -7 -233 -258 -357 -293 0 75 69 247 308 230 243 233 159 118 62 -175 -491 -659 -540 -807 -671 -451 -26 215 444 617 613 595 471 158 -63 -146 -248 -400 -433 -321 -158 152 280 240 286 215 167 328 340 152 53 28 -354 -494 -458 -361 13 343 314 206 192 60 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4.9120e-03 1.9323e-03 2.8658e-05 2.4473e-04 -6.0000e+00 1.2519e-03 1.1824e+00 1.2929e-03 7.8702e-06 1.4999e-05 -6.0000e+00 3.5153e-04 -9.3894e-03 8.7838e-05 10 0 0 10 0 0 63.65 17.76 2.27 -0.00939 -0.00042 1971 1971 2 2 0 2.490 15.00 17.76 23.34 21.27 21.17 19.4 977.59 -790 -671 -456 -25 198 415 578 577 564 448 139 -60 -156 -221 -381 -428 -309 -151 154 270 224 266 210 165 307 303 121 42 49 -341 -491 -450 -349 3 327 304 196 187 60 -102 -118 -92 12 159 282 409 394 206 -10 -213 -485 -666 -843 -794 -506 -148 128 251 311 331 372 411 422 321 305 195 -14 -204 -166 -216 -314 -289 -204 -96 82 69 -162 -360 -387 -403 -431 -270 -231 -179 -28 -65 -38 -69 -106 -143 -70 11 280 443 348 269 179 -40 -176 -443 -644 -599 -456 -174 74 -76 -130 -214 -299 -223 -23 125 266 408 510 466 431 456 351 172 105 61 -30 146 205 87 216 267 69 160 271 -18 -233 -241 -361 -295 7 83 69 246 300 226 231 221 147 111 66 -178 -486 -642 -542 -791 -676 -461 -26 207 435 615 608 594 469 146 -62 -161 -229 -393 -442 -316 -158 160 286 239 284 224 177 323 319 127 44 50 -352 -497 -455 -358 3 345 318 206 194 62 -106 -122 -95 12 165 295 429 411 213 -10 -216 -491 -658 -824 -779 -505 -149 131 255 317 337 379 420 432 329 310 197 -13 -204 -163 -211 -305 -281 -199 -95 81 68 -159 -348 -370 -385 -412 -260 -223 -175 -27 -63 -37 -67 -105 -141 -69 10 279 443 347 264 176 -39 -169 -419 -608 -571 -437 -168 73 -75 -129 -209 -290 -216 -23 124 262 406 512 462 429 453 347 172 103 59 -29 141 198 84 209 257 66 154 259 -17 -221 -226 -338 -279 7 80 68 238 291 220 227 218 145 109 64 -172 -461 -605 -513 SQ 20231011T153053.6Z 8684.646454 219 5 5.01 2 54.19 151.74 34.50 193.53 0.00 1 0.00 1 0 15 3.174e-03 3.167e-03 7.532e-05 7.515e-05 1.158948e+03 4.424448e+00 8.764630e+01 -6.000000e+00 1.803186e+02 282.17 -2.00 20.00 -2.00 505.24 0.00e+00 5.126633e-04 2.078342e-06 2.928164e-05 -6.000000e+00 8.971649e-05 282.17 -2.00 20.00 -2.00 500.37 0.00e+00 8.844347e-02 1.493152e-03 9.130781e-03 -6.000000e+00 6.316299e-02 226.01 -2.00 3.55 -2.00 501.97 0.00e+00 1.704 0.000 489.00 513.00 1 2.9170e-01 1.1486e-04 2.6019e-03 -6.0000e+00 4.8558e-03 1.9494e-03 2.9262e-05 2.4263e-04 -6.0000e+00 1.2377e-03 1.1378e+00 1.3449e-03 8.0431e-06 1.5003e-05 -6.0000e+00 3.4749e-04 -8.6311e-03 7.9625e-05 10 0 0 10 0 0 91.11 17.76 2.27 -0.00863 0.00070 1971 1971 2 2 0 2.490 15.00 17.76 23.34 21.27 21.17 19.4 977.59 -792 -642 -437 -23 201 416 576 570 561 433 133 -79 -156 -232 -377 -418 -306 -167 152 267 216 264 204 161 309 302 138 52 43 -334 -477 -450 -358 9 308 307 192 185 43 -98 -111 -83 14 156 272 403 385 206 -16 -193 -486 -655 -835 -813 -507 -155 121 227 290 327 374 408 426 310 303 202 -14 -211 -162 -228 -303 -286 -208 -93 82 68 -170 -340 -378 -390 -415 -261 -232 -182 -29 -69 -37 -86 -90 -131 -57 8 283 452 337 249 169 -55 -164 -415 -637 -586 -445 -170 41 -86 -131 -215 -297 -224 -15 119 261 424 508 462 424 469 354 152 116 54 -32 146 199 84 194 244 91 145 274 -13 -225 -253 -353 -294 15 79 64 240 295 225 238 236 160 117 62 -179 -495 -625 -523 -781 -637 -444 -24 207 438 603 603 594 456 139 -83 -161 -236 -383 -426 -315 -175 159 284 231 277 215 170 327 319 145 56 45 -339 -485 -457 -369 9 320 323 202 193 44 -102 -116 -85 15 163 286 424 404 214 -16 -197 -484 -650 -820 -802 -498 -156 122 232 297 335 382 418 438 318 309 205 -14 -212 -160 -223 -295 -279 -204 -92 80 68 -167 -330 -364 -373 -399 -252 -226 -175 -28 -67 -36 -85 -89 -130 -56 8 283 454 337 245 167 -54 -155 -395 -604 -561 -428 -165 40 -84 -127 -211 -289 -218 -15 116 258 424 502 459 423 467 351 152 114 53 -31 141 193 81 188 236 88 140 262 -13 -214 -239 -332 -279 14 76 61 232 287 221 235 233 158 115 60 -170 -471 -591 -497 SQ 20231011T153058.8Z 8684.646513 219 6 5.12 2 54.18 151.77 34.51 193.57 0.00 1 0.00 1 0 15 3.171e-03 3.164e-03 7.716e-05 7.698e-05 1.162589e+03 4.541412e+00 8.761130e+01 -6.000000e+00 1.801877e+02 282.17 -2.00 20.00 -2.00 505.25 0.00e+00 5.084607e-04 2.129001e-06 2.903424e-05 -6.000000e+00 8.964978e-05 282.17 -2.00 20.00 -2.00 500.36 0.00e+00 8.865158e-02 1.529498e-03 9.206220e-03 -6.000000e+00 6.311155e-02 226.01 -2.00 3.55 -2.00 501.97 0.00e+00 1.704 0.000 489.00 513.00 1 3.3769e-01 1.1763e-04 2.6018e-03 -6.0000e+00 4.8519e-03 1.9834e-03 2.9964e-05 2.4389e-04 -6.0000e+00 1.2365e-03 1.0868e+00 1.2025e-03 8.2337e-06 1.4781e-05 -6.0000e+00 3.4723e-04 -9.7757e-03 9.2934e-05 10 0 0 10 0 0 35.85 17.76 2.26 -0.00978 -0.00143 1971 1971 2 2 0 2.490 15.00 17.76 23.34 21.27 21.17 19.4 977.59 -765 -642 -453 -27 212 404 570 564 560 432 137 -58 -155 -218 -375 -409 -315 -139 159 250 223 257 204 156 292 300 120 40 39 -319 -457 -427 -350 20 317 304 195 186 30 -106 -111 -104 -5 151 265 387 379 210 -3 -210 -491 -644 -833 -807 -511 -149 122 229 307 331 377 401 419 328 304 211 -16 -212 -165 -228 -313 -284 -194 -99 76 69 -181 -342 -370 -392 -426 -249 -242 -193 -24 -64 -41 -70 -111 -138 -61 -6 284 440 349 247 170 -40 -172 -431 -644 -579 -445 -176 43 -74 -144 -206 -297 -224 -23 116 264 426 514 463 430 474 361 163 117 72 -37 133 200 78 215 255 64 153 272 -10 -226 -262 -373 -292 5 86 68 235 320 232 249 230 157 112 71 -168 -495 -636 -535 -757 -639 -461 -27 219 425 598 598 594 455 142 -61 -161 -223 -381 -417 -325 -146 167 266 234 270 215 165 309 318 127 41 41 -325 -466 -435 -354 20 330 320 205 194 31 -111 -116 -107 -5 158 278 408 398 219 -3 -214 -490 -641 -820 -797 -503 -150 123 234 314 338 386 412 431 337 311 214 -16 -209 -164 -224 -306 -277 -190 -98 74 67 -179 -333 -357 -376 -410 -241 -236 -186 -23 -62 -41 -69 -109 -137 -60 -6 284 442 349 244 165 -39 -164 -411 -612 -544 -429 -171 42 -73 -140 -203 -290 -218 -23 113 261 426 508 460 429 472 357 160 116 70 -36 129 194 76 209 247 62 148 260 -9 -215 -247 -351 -277 5 83 65 228 311 227 245 227 155 110 69 -159 -471 -602 -508 SQ 20231011T153103.9Z 8684.646573 219 7 5.01 2 54.18 151.79 34.51 193.60 0.00 1 0.00 1 0 22 3.166e-03 3.156e-03 7.751e-05 7.733e-05 1.165902e+03 4.551965e+00 8.837218e+01 -6.000000e+00 1.799008e+02 282.17 -2.00 20.00 -2.00 505.24 0.00e+00 5.163320e-04 2.137844e-06 2.943998e-05 -6.000000e+00 8.950854e-05 282.17 -2.00 20.00 -2.00 500.36 0.00e+00 9.164282e-02 1.536197e-03 9.147639e-03 -6.000000e+00 6.301631e-02 226.01 -2.00 3.55 -2.00 501.96 0.00e+00 1.704 0.000 489.00 513.00 1 3.4598e-01 1.1816e-04 2.6028e-03 -6.0000e+00 4.8445e-03 1.9164e-03 3.0107e-05 2.4326e-04 -6.0000e+00 1.2348e-03 1.0775e+00 1.3618e-03 8.2674e-06 1.5030e-05 -6.0000e+00 3.4669e-04 -8.8020e-03 8.1061e-05 10 0 0 10 0 0 88.26 17.76 2.26 -0.00880 0.00064 1971 1971 2 2 0 2.490 15.00 17.76 23.34 21.27 21.17 19.4 977.59 -780 -644 -440 -16 212 418 570 567 554 426 120 -64 -137 -228 -370 -414 -303 -145 155 255 221 258 195 149 290 296 124 53 52 -322 -459 -432 -338 17 319 301 183 187 59 -107 -115 -110 0 147 268 396 378 215 -23 -202 -490 -648 -826 -806 -497 -155 121 237 300 325 386 400 418 326 297 200 -16 -225 -170 -235 -310 -273 -195 -112 91 84 -170 -330 -366 -395 -425 -264 -233 -201 -25 -70 -47 -80 -106 -134 -71 10 291 444 357 255 182 -40 -187 -432 -637 -589 -452 -179 55 -78 -136 -205 -299 -240 -24 116 256 428 511 477 424 460 365 156 115 75 -32 134 206 90 201 260 75 147 261 -17 -239 -242 -364 -289 9 97 82 252 314 215 229 235 149 103 64 -180 -483 -623 -526 -769 -638 -447 -16 218 438 596 599 586 447 127 -67 -141 -233 -382 -421 -311 -152 162 271 236 276 209 157 305 312 130 56 54 -333 -466 -439 -348 18 331 317 192 194 62 -112 -119 -115 0 153 281 416 395 222 -24 -205 -487 -643 -810 -793 -498 -156 122 242 306 332 394 409 428 334 302 202 -16 -225 -168 -230 -301 -266 -191 -111 91 84 -167 -320 -351 -377 -407 -254 -226 -197 -24 -69 -46 -79 -104 -133 -70 10 291 444 356 251 179 -39 -181 -410 -603 -563 -434 -173 55 -76 -135 -200 -290 -233 -24 113 253 426 513 473 422 457 361 155 113 73 -31 129 199 87 195 251 73 141 249 -17 -227 -227 -341 -274 8 93 80 243 304 210 225 231 147 101 62 -173 -459 -588 -498 SQ 20231011T153109.0Z 8684.646632 219 8 5.01 2 54.17 151.82 34.51 193.64 0.00 1 0.00 1 0 22 3.142e-03 3.134e-03 8.006e-05 7.985e-05 1.176001e+03 4.715380e+00 8.872366e+01 -6.000000e+00 1.785038e+02 282.17 -2.00 20.00 -2.00 505.24 0.00e+00 5.175355e-04 2.208984e-06 2.953364e-05 -6.000000e+00 8.881696e-05 282.17 -2.00 20.00 -2.00 500.33 0.00e+00 9.052716e-02 1.588870e-03 9.283248e-03 -6.000000e+00 6.253691e-02 226.01 -2.00 3.55 -2.00 501.95 0.00e+00 1.704 0.000 489.00 513.00 1 4.0593e-01 1.2220e-04 2.6058e-03 -6.0000e+00 4.8076e-03 2.0237e-03 3.1153e-05 2.4529e-04 -6.0000e+00 1.2256e-03 1.0149e+00 1.5565e-03 8.5384e-06 1.4932e-05 -6.0000e+00 3.4401e-04 -7.7106e-03 6.3552e-05 10 0 0 10 0 0 99.20 17.76 2.26 -0.00771 0.00309 1971 1971 2 2 0 2.490 15.00 17.76 23.34 21.27 21.17 19.4 977.59 -766 -636 -446 -24 209 416 560 568 549 436 131 -79 -142 -216 -377 -401 -309 -143 153 264 211 268 203 153 289 295 124 47 43 -306 -465 -424 -341 6 317 299 179 179 43 -104 -114 -104 -1 151 269 380 383 210 -18 -201 -488 -647 -845 -799 -516 -132 109 229 305 312 382 405 421 320 299 192 -34 -209 -163 -226 -303 -272 -194 -102 90 90 -175 -326 -379 -388 -417 -261 -225 -181 -22 -61 -51 -71 -112 -135 -63 7 281 418 343 246 156 -39 -174 -408 -626 -588 -464 -178 45 -64 -143 -213 -287 -243 -29 115 257 412 495 453 439 465 367 139 102 55 -35 148 203 89 196 263 74 160 278 -10 -233 -238 -348 -265 3 70 62 244 311 222 222 214 144 117 70 -164 -473 -646 -528 -770 -630 -452 -24 218 435 596 598 579 466 139 -83 -146 -224 -389 -415 -316 -149 159 280 225 286 217 164 310 316 132 49 44 -316 -471 -429 -350 6 334 312 188 189 45 -108 -118 -108 -1 156 281 398 399 217 -19 -204 -494 -640 -827 -784 -515 -132 112 233 310 317 388 413 430 327 304 193 -34 -209 -161 -220 -294 -263 -190 -100 90 89 -172 -315 -362 -370 -398 -250 -218 -177 -22 -60 -50 -70 -110 -133 -63 7 279 416 340 242 153 -38 -167 -387 -590 -560 -443 -172 45 -63 -141 -207 -277 -235 -28 114 252 409 495 455 443 469 367 138 100 53 -35 144 195 86 188 252 71 153 269 -9 -221 -223 -325 -250 3 67 60 239 300 216 216 210 141 114 67 -157 -446 -606 -498 SQ 20231011T153114.1Z 8684.646691 219 9 5.01 2 54.16 151.84 34.52 193.67 0.00 1 0.00 1 0 15 3.200e-03 3.191e-03 7.446e-05 7.429e-05 1.192704e+03 4.388820e+00 8.900012e+01 -6.000000e+00 1.818216e+02 282.17 -2.00 20.00 -2.00 505.25 0.00e+00 5.220099e-04 2.054589e-06 2.982699e-05 -6.000000e+00 9.046488e-05 282.17 -2.00 20.00 -2.00 500.35 0.00e+00 8.222554e-02 1.477522e-03 9.580234e-03 -6.000000e+00 6.369105e-02 226.01 -2.00 3.55 -2.00 501.96 0.00e+00 1.703 0.000 489.00 513.00 1 2.7127e-01 1.1362e-04 2.6143e-03 -6.0000e+00 4.8964e-03 1.9820e-03 2.8974e-05 2.4963e-04 -6.0000e+00 1.2480e-03 1.1618e+00 1.3850e-03 7.9462e-06 1.5096e-05 -6.0000e+00 3.5039e-04 -8.5276e-03 7.7287e-05 10 0 0 10 0 0 91.44 17.76 2.27 -0.00853 0.00108 1971 1971 2 2 0 2.490 15.00 17.76 23.34 21.27 21.17 19.4 977.59 -799 -656 -449 -23 199 419 569 578 576 435 148 -60 -153 -220 -397 -413 -307 -148 152 261 222 265 211 153 298 302 121 56 33 -324 -479 -433 -357 12 312 297 190 186 45 -111 -121 -93 18 155 280 397 386 212 -24 -208 -493 -670 -842 -795 -508 -130 114 242 302 328 376 407 418 317 299 221 -12 -218 -173 -231 -301 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20231011T153119.2Z 8684.646750 219 10 5.01 2 54.15 151.87 34.52 193.71 0.00 1 0.00 1 0 22 3.215e-03 3.209e-03 7.299e-05 7.283e-05 1.177745e+03 4.294472e+00 8.964451e+01 -6.000000e+00 1.826459e+02 282.17 -2.00 20.00 -2.00 505.25 0.00e+00 5.260751e-04 2.015898e-06 2.995550e-05 -6.000000e+00 9.087641e-05 282.17 -2.00 20.00 -2.00 500.36 0.00e+00 8.415279e-02 1.448730e-03 9.160969e-03 -6.000000e+00 6.398391e-02 226.01 -2.00 3.55 -2.00 501.97 0.00e+00 1.703 0.000 489.00 513.00 1 2.3367e-01 1.1143e-04 2.6053e-03 -6.0000e+00 4.9189e-03 1.9695e-03 2.8390e-05 2.4374e-04 -6.0000e+00 1.2539e-03 1.2062e+00 1.4932e-03 7.7889e-06 1.5316e-05 -6.0000e+00 3.5199e-04 -8.0214e-03 6.9794e-05 10 0 0 10 0 0 98.08 17.76 2.26 -0.00802 0.00234 1971 1971 2 2 0 2.490 15.00 17.76 23.34 21.27 21.17 19.4 977.59 -796 -662 -441 -16 213 427 579 578 569 440 123 -61 -156 -237 -389 -421 -325 -150 152 264 233 284 217 165 302 327 130 36 32 -337 -478 -450 -352 10 303 302 201 190 44 -113 -121 -92 11 150 273 395 382 213 -22 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