File name: Pandora206s1_BuffaloNY_20231021_L2Fit_fnvs5c4d20220512p1-8.txt File generation date: 20241121T063555.5Z Data description: Level 2 spectral fitting results file Data file version: fnvs5c4p1-8 Local principal investigator: Kang Sun Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 206 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora206_OF_v3d20211008.txt Instrument calibration file used: Pandora206s1_CF_v4d20220512.txt Level 1 file used: Pandora206s1_BuffaloNY_20231021_L1_smca1c4d20220512p1-8.txt Full location name: University at Buffalo Short location name: BuffaloNY Country of location: Canada Location latitude [deg]: 43.0015 Location longitude [deg]: -78.7869 Location altitude [m]: 190 Local noon date: 20231021 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 918 1463 Nominal wavelengths inside fitting window [nm]: 400.1150 400.2472 400.3794 400.5115 400.6437 400.7758 400.9080 401.0401 401.1722 401.3043 401.4363 401.5684 401.7004 401.8324 401.9645 402.0965 402.2284 402.3604 402.4924 402.6243 402.7562 402.8882 403.0201 403.1519 403.2838 403.4157 403.5475 403.6793 403.8112 403.9430 404.0747 404.2065 404.3383 404.4700 404.6017 404.7335 404.8652 404.9968 405.1285 405.2602 405.3918 405.5234 405.6551 405.7867 405.9182 406.0498 406.1814 406.3129 406.4445 406.5760 406.7075 406.8390 406.9704 407.1019 407.2333 407.3648 407.4962 407.6276 407.7590 407.8903 408.0217 408.1530 408.2844 408.4157 408.5470 408.6783 408.8095 408.9408 409.0720 409.2033 409.3345 409.4657 409.5969 409.7280 409.8592 409.9903 410.1215 410.2526 410.3837 410.5147 410.6458 410.7769 410.9079 411.0389 411.1700 411.3009 411.4319 411.5629 411.6939 411.8248 411.9557 412.0866 412.2175 412.3484 412.4793 412.6101 412.7410 412.8718 413.0026 413.1334 413.2642 413.3949 413.5257 413.6564 413.7872 413.9179 414.0486 414.1792 414.3099 414.4405 414.5712 414.7018 414.8324 414.9630 415.0936 415.2241 415.3547 415.4852 415.6157 415.7462 415.8767 416.0072 416.1377 416.2681 416.3986 416.5290 416.6594 416.7898 416.9201 417.0505 417.1808 417.3112 417.4415 417.5718 417.7021 417.8323 417.9626 418.0928 418.2231 418.3533 418.4835 418.6136 418.7438 418.8740 419.0041 419.1342 419.2643 419.3944 419.5245 419.6546 419.7846 419.9147 420.0447 420.1747 420.3047 420.4347 420.5646 420.6946 420.8245 420.9544 421.0843 421.2142 421.3441 421.4739 421.6038 421.7336 421.8634 421.9932 422.1230 422.2528 422.3826 422.5123 422.6420 422.7717 422.9014 423.0311 423.1608 423.2904 423.4201 423.5497 423.6793 423.8089 423.9385 424.0680 424.1976 424.3271 424.4566 424.5861 424.7156 424.8451 424.9746 425.1040 425.2334 425.3629 425.4923 425.6216 425.7510 425.8804 426.0097 426.1390 426.2683 426.3976 426.5269 426.6562 426.7854 426.9147 427.0439 427.1731 427.3023 427.4315 427.5606 427.6898 427.8189 427.9480 428.0771 428.2062 428.3353 428.4644 428.5934 428.7224 428.8514 428.9804 429.1094 429.2384 429.3674 429.4963 429.6252 429.7541 429.8830 430.0119 430.1408 430.2696 430.3984 430.5273 430.6561 430.7849 430.9136 431.0424 431.1711 431.2999 431.4286 431.5573 431.6860 431.8146 431.9433 432.0719 432.2005 432.3291 432.4577 432.5863 432.7149 432.8434 432.9720 433.1005 433.2290 433.3575 433.4859 433.6144 433.7428 433.8713 433.9997 434.1281 434.2565 434.3848 434.5132 434.6415 434.7699 434.8982 435.0265 435.1547 435.2830 435.4112 435.5395 435.6677 435.7959 435.9241 436.0522 436.1804 436.3085 436.4367 436.5648 436.6929 436.8210 436.9490 437.0771 437.2051 437.3331 437.4611 437.5891 437.7171 437.8451 437.9730 438.1009 438.2288 438.3567 438.4846 438.6125 438.7403 438.8682 438.9960 439.1238 439.2516 439.3794 439.5071 439.6349 439.7626 439.8903 440.0180 440.1457 440.2734 440.4010 440.5287 440.6563 440.7839 440.9115 441.0391 441.1667 441.2942 441.4217 441.5493 441.6768 441.8042 441.9317 442.0592 442.1866 442.3140 442.4415 442.5689 442.6962 442.8236 442.9509 443.0783 443.2056 443.3329 443.4602 443.5875 443.7147 443.8420 443.9692 444.0964 444.2236 444.3508 444.4779 444.6051 444.7322 444.8594 444.9865 445.1135 445.2406 445.3677 445.4947 445.6218 445.7488 445.8758 446.0027 446.1297 446.2567 446.3836 446.5105 446.6374 446.7643 446.8912 447.0180 447.1449 447.2717 447.3985 447.5253 447.6521 447.7789 447.9056 448.0324 448.1591 448.2858 448.4125 448.5391 448.6658 448.7924 448.9191 449.0457 449.1723 449.2989 449.4254 449.5520 449.6785 449.8050 449.9315 450.0580 450.1845 450.3109 450.4374 450.5638 450.6902 450.8166 450.9430 451.0694 451.1957 451.3220 451.4484 451.5747 451.7009 451.8272 451.9535 452.0797 452.2059 452.3321 452.4583 452.5845 452.7107 452.8368 452.9630 453.0891 453.2152 453.3413 453.4673 453.5934 453.7194 453.8454 453.9714 454.0974 454.2234 454.3494 454.4753 454.6012 454.7272 454.8531 454.9789 455.1048 455.2307 455.3565 455.4823 455.6081 455.7339 455.8597 455.9854 456.1112 456.2369 456.3626 456.4883 456.6140 456.7396 456.8653 456.9909 457.1165 457.2421 457.3677 457.4933 457.6188 457.7444 457.8699 457.9954 458.1209 458.2464 458.3718 458.4973 458.6227 458.7481 458.8735 458.9989 459.1243 459.2496 459.3749 459.5003 459.6256 459.7508 459.8761 460.0014 460.1266 460.2518 460.3770 460.5022 460.6274 460.7526 460.8777 461.0028 461.1280 461.2531 461.3781 461.5032 461.6283 461.7533 461.8783 462.0033 462.1283 462.2533 462.3782 462.5032 462.6281 462.7530 462.8779 463.0028 463.1276 463.2525 463.3773 463.5021 463.6269 463.7517 463.8765 464.0012 464.1259 464.2507 464.3754 464.5000 464.6247 464.7494 464.8740 464.9986 465.1232 465.2478 465.3724 465.4970 465.6215 465.7460 465.8705 465.9950 466.1195 466.2440 466.3684 466.4929 466.6173 466.7417 466.8661 466.9904 467.1148 467.2391 467.3634 467.4877 467.6120 467.7363 467.8606 467.9848 468.1090 468.2332 468.3574 468.4816 468.6058 468.7299 468.8540 468.9781 469.1022 469.2263 469.3504 469.4744 469.5985 469.7225 469.8465 469.9705 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Spectrometer control temperature [°C], 999=no temperature signal Column 159: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 160: Temperature in head sensor [°C], 999=no temperature signal Column 161: Temperature at electronics board 1 [°C], 999=no temperature signal Column 162: Temperature at electronics board 2 [°C], 999=no temperature signal Column 163: Humidity in head sensor [%], -9=no humidity signal Column 164: Pressure in head sensor [hPa], -9=no pressure signal Columns 165-710: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 711-1256: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231021T143924.0Z 8694.610695 114 1 24.01 2 62.57 140.46 132.21 90.21 0.00 1 0.00 1 0 17 3.468e-03 3.453e-03 2.973e-03 2.951e-03 1.085202e+03 5.930188e+02 1.089449e+02 3.077989e+02 6.988798e+02 280.92 -2.00 20.00 -2.00 444.01 0.00e+00 5.468323e-04 3.164488e-04 1.963754e-06 1.171323e-05 3.797920e-04 280.92 -2.00 20.00 -2.00 453.43 0.00e+00 1.553269e-04 2.641318e-05 1.032080e-06 7.704691e-06 3.126866e-05 224.03 -2.00 2.19 -2.00 432.70 0.00e+00 5.312488e+05 4.225068e+05 2.029933e+04 1.883885e+05 4.991157e+05 262.61 -2.00 11.28 -2.00 456.86 0.00e+00 3.236816e-01 8.892622e-02 8.868382e-04 7.352877e-03 1.082704e-01 224.99 -2.00 3.55 -2.00 452.85 0.00e+00 -5.884018e-06 1.108977e-05 1.892658e-07 9.394728e-07 1.326837e-05 280.92 -2.00 20.00 -2.00 454.48 0.00e+00 2.159 0.000 397.00 473.00 4 9.0516e+00 3.1204e-03 5.3780e-03 3.1842e-04 3.5427e-03 9.1649e-02 3.6062e-03 1.1233e-03 1.8073e-04 4.3307e-03 -1.1952e-02 2.1255e-03 1.4823e-04 7.2313e-05 2.5332e-03 -1.8369e-03 7.0158e-04 1.7492e-05 1.9508e-05 8.4288e-04 -2.5352e-04 3.5806e-04 4.0989e-06 1.0792e-05 4.2380e-04 1.3986e-04 3.1008e-03 2.0836e-03 1.2555e-05 2.4691e-05 2.2082e-03 1.1603e-05 3.4016e-05 2.2427e-07 2.9063e-07 3.8671e-05 -2.7309e-05 4.4245e-05 2.2068e-07 3.4180e-07 5.1837e-05 -2.9526e-02 2.6297e-04 3.1390e-01 2.7535e-01 1.0270e-03 1.0319e-03 3.1112e-01 12 8 8 10 0 0 37.64 18.20 2.02 -0.02953 -0.02695 6 6 2 2 0 4000.000 15.00 18.20 17.24 21.69 21.58 18.9 945.26 132 -31 201 22 -172 -121 437 113 -142 -247 -217 4 -35 9 -204 -359 -185 237 -473 209 -370 68 106 -345 -1199 -315 54 -73 229 -727 344 -413 305 542 187 -9 -216 424 84 459 202 -78 123 121 67 426 142 -316 45 -39 806 -224 320 137 -122 228 98 -122 443 -354 680 -801 334 653 -35 763 -148 343 10 128 -143 112 611 658 -222 -4 -581 154 88 -132 -88 445 283 68 394 319 -24 -186 114 135 -10 -95 23 -3 -98 -584 -409 415 -108 435 -683 113 -448 336 -324 135 -6 -109 -295 20 -218 -765 -184 -336 287 -169 -144 -82 -304 -495 -136 -407 159 -95 -197 -185 310 303 -60 -22 -178 2 -494 68 -575 -275 383 -357 446 -25 141 372 439 277 424 255 419 -517 -16 216 187 -1109 -75 116 -304 11 -57 723 -1390 147 347 -232 -243 -288 153 618 421 -100 -384 -573 299 -805 -36 142 263 -241 -16 -26 330 102 -132 313 -314 -45 -17 378 -12 115 159 341 -330 -68 -922 303 45 -31 55 326 -237 326 723 -361 262 418 290 -587 345 -365 -6 64 -797 349 -145 182 96 574 -478 289 -216 707 120 -406 -82 310 134 -250 113 86 -106 310 -22 -410 351 -858 172 -611 51 -219 -144 258 299 282 468 -2 -80 429 -530 629 58 -286 -122 21 236 -5 230 395 -63 60 -793 -24 343 -457 113 -665 415 -821 -309 114 -36 -273 -357 -240 -343 350 8 542 -123 -665 -301 534 -596 450 25 138 1048 -425 1080 -592 351 0 351 -370 98 -51 -120 -60 -105 227 -714 107 381 406 270 380 -123 649 -201 251 -301 -511 -488 125 340 266 -526 -313 183 236 260 64 156 -140 26 483 25 -365 374 -322 -102 379 43 386 -539 411 -14 341 -302 -907 323 181 81 -278 -113 23 -216 138 118 197 4 -83 16 -537 -298 -410 376 -38 314 0 -409 476 329 -47 -146 -298 569 -45 451 -164 -14 182 -11 228 -319 -508 -519 -335 340 -274 314 -89 55 139 -459 -73 84 -1113 -27 360 266 405 289 346 -23 -138 -688 -30 -221 369 -183 -316 -345 -364 418 422 8 -258 362 -309 439 -192 -215 794 55 226 -95 -38 -701 -61 -277 -221 844 518 -171 189 -205 -64 -80 342 348 -27 -267 -54 21 -260 175 127 -345 368 37 223 119 -243 -482 65 -190 540 -190 134 -219 366 116 564 -239 69 241 -270 -276 -82 -122 388 160 63 53 113 -55 -421 -401 100 364 -372 392 41 197 -101 132 15 311 -192 -350 -157 -157 222 108 84 133 -96 -352 13 -386 295 -239 208 194 263 -259 -300 -44 41 -117 -390 615 -110 -197 -175 -246 -205 -87 -199 -80 -392 -101 329 -57 80 -220 -3 -197 -206 246 -141 721 711 78 -598 178 386 -29 -371 219 395 230 15 -192 340 -432 22 -88 78 347 96 661 -68 -379 -37 -545 55 128 -30 186 20 -163 -110 415 111 -142 -249 -218 4 -35 9 -205 -366 -189 239 -484 214 -380 68 101 -331 -1131 -303 52 -74 238 -771 359 -414 296 498 170 -8 -207 429 86 461 198 -78 121 119 67 418 136 -299 41 -36 795 -217 322 138 -124 226 97 -119 428 -353 665 -820 341 662 -36 797 -160 376 11 137 -150 114 603 656 -210 -4 -531 140 80 -129 -87 449 289 70 412 341 -27 -207 125 146 -11 -101 25 -3 -105 -624 -435 431 -110 432 -680 113 -465 362 -347 144 -7 -114 -301 21 -224 -813 -198 -361 303 -176 -148 -83 -309 -514 -144 -445 169 -102 -213 -197 322 328 -64 -22 -180 2 -487 68 -588 -285 394 -369 459 -25 143 374 442 280 437 261 431 -531 -17 216 182 -1075 -72 114 -308 11 -59 756 -1495 157 371 -248 -255 -297 155 623 434 -106 -406 -583 292 -730 -33 128 254 -241 -16 -27 326 103 -132 313 -307 -45 -17 391 -12 116 157 323 -313 -65 -894 296 45 -31 53 309 -223 308 705 -373 275 433 289 -554 320 -327 -6 59 -748 337 -143 181 94 556 -464 276 -204 638 111 -379 -77 280 123 -228 102 73 -88 242 -17 -316 272 -666 129 -451 37 -166 -113 225 278 275 486 -2 -86 442 -512 577 51 -252 -113 20 238 -5 241 410 -64 58 -737 -21 292 -397 98 -631 395 -826 -316 114 -36 -264 -340 -230 -339 350 9 556 -123 -679 -312 550 -615 455 25 136 1055 -426 1046 -579 342 0 338 -370 92 -45 -105 -52 -91 207 -681 103 369 396 256 366 -121 633 -197 242 -284 -490 -463 117 321 251 -521 -321 189 241 260 63 155 -144 26 486 25 -363 366 -320 -102 376 42 380 -526 392 -13 329 -300 -922 325 180 80 -275 -112 23 -222 136 116 198 4 -79 15 -488 -269 -373 343 -36 297 0 -388 468 323 -45 -140 -292 564 -45 459 -168 -14 178 -11 216 -307 -503 -525 -339 338 -271 307 -88 53 136 -455 -72 84 -1143 -27 372 268 413 297 355 -23 -142 -704 -31 -221 377 -187 -323 -356 -362 428 430 8 -253 344 -289 417 -184 -199 761 52 214 -92 -38 -715 -63 -284 -225 845 518 -170 184 -199 -62 -77 331 338 -27 -268 -55 21 -273 184 132 -354 373 38 228 123 -252 -501 68 -199 563 -199 138 -223 364 114 570 -244 68 240 -274 -282 -84 -124 389 166 66 55 117 -57 -439 -419 105 381 -381 403 43 206 -106 138 15 322 -199 -364 -164 -163 231 113 89 139 -101 -371 14 -408 323 -251 226 210 282 -276 -319 -47 43 -124 -417 645 -114 -202 -178 -253 -213 -92 -211 -84 -416 -108 353 -62 88 -240 -3 -206 -209 253 -145 736 709 80 -631 189 410 -31 -394 228 409 238 15 -203 361 -463 24 -94 83 364 102 698 -73 -404 -39 -568 56 SQ 20231021T154740.1Z 8694.658103 141 1 24.00 2 56.23 158.54 120.35 100.53 0.00 1 0.00 1 0 33 2.592e-03 2.583e-03 2.412e-03 2.394e-03 1.118081e+03 4.774632e+02 9.547764e+01 3.077602e+02 5.223888e+02 280.91 -2.00 20.00 -2.00 444.17 0.00e+00 9.604867e-04 2.579313e-04 2.338558e-06 1.180278e-05 2.840367e-04 280.91 -2.00 20.00 -2.00 453.57 0.00e+00 1.465684e-04 2.142671e-05 1.029922e-06 7.709817e-06 2.339018e-05 224.27 -2.00 2.19 -2.00 433.04 0.00e+00 8.637239e+05 3.405683e+05 1.344971e+04 1.883983e+05 3.732461e+05 262.60 -2.00 11.28 -2.00 456.87 0.00e+00 2.836042e-01 7.167729e-02 1.967967e-03 7.358433e-03 8.093292e-02 224.98 -2.00 3.55 -2.00 452.98 0.00e+00 7.631317e-06 8.935386e-06 2.514676e-07 9.398653e-07 9.917669e-06 280.91 -2.00 20.00 -2.00 454.55 0.00e+00 1.793 0.000 397.00 473.00 4 8.8066e+00 2.5224e-03 4.4667e-03 3.1910e-04 2.6418e-03 5.3963e-02 2.9481e-03 9.3322e-04 1.8231e-04 3.2488e-03 -9.5659e-03 1.7268e-03 1.2401e-04 7.3062e-05 1.8903e-03 -3.3437e-03 5.7171e-04 1.6033e-05 1.9649e-05 6.3079e-04 -1.0306e-03 2.9108e-04 8.2683e-06 1.0847e-05 3.1665e-04 1.9411e-04 7.8889e-03 1.6856e-03 8.8298e-06 2.4806e-05 1.6288e-03 -2.0608e-05 2.7303e-05 2.6102e-07 2.8959e-07 2.8894e-05 2.8744e-05 3.5769e-05 2.8085e-07 3.4501e-07 3.8736e-05 -2.1481e-02 1.6767e-04 2.2551e-02 2.2375e-01 6.7976e-04 1.0399e-03 2.3291e-01 12 8 8 10 0 0 97.88 18.19 2.07 -0.02148 -0.02438 6 6 2 2 0 4000.000 15.00 18.19 16.32 21.69 21.58 19.1 940.89 583 -184 -488 -26 -95 173 637 -49 89 -208 -135 -482 -205 -74 -228 -226 -24 205 -104 -144 -372 147 278 -139 -238 -456 -25 171 -138 411 85 122 177 11 -203 -145 -46 308 91 0 12 289 -149 209 262 640 499 23 -447 -83 -99 24 208 29 245 28 245 317 234 -55 -3 -787 403 23 13 217 -76 346 322 106 -98 153 -328 449 -423 -126 -186 -398 280 -288 -106 96 61 -366 -54 -262 213 -26 450 -202 747 -4 -33 -387 168 -467 -135 -161 -101 -81 -497 217 60 378 -55 202 109 171 128 174 57 235 -600 -87 182 -260 -213 -227 -419 -74 9 177 -62 -114 -488 -203 -41 100 50 -10 -348 -64 2 -253 -325 -43 -209 -71 128 273 493 547 -190 420 290 50 398 -223 -266 271 299 -12 -79 -426 134 219 -34 293 -812 240 144 -259 -11 330 87 81 46 -452 130 -285 -30 247 -192 -209 -29 -108 -194 -161 374 38 33 120 33 -154 -148 -89 195 -45 -213 -72 -170 -170 -291 186 54 151 181 -18 -616 131 506 -173 -113 177 384 -408 93 11 87 -238 -70 4 340 88 -309 545 89 -184 -143 242 294 224 24 463 91 -254 -75 46 -345 -141 286 -716 172 -19 -64 -593 244 -194 -388 36 179 122 208 362 18 -51 -196 283 550 33 21 25 383 8 324 -39 -133 -380 -134 -151 -237 -369 162 177 -150 38 -35 -5 -235 -274 188 -30 170 77 -69 193 -186 -535 -56 -10 -5 380 -54 -79 140 -405 715 -338 -236 144 -18 189 121 99 -156 -69 -187 -140 194 203 434 -326 263 377 -208 -46 215 178 151 -547 0 -212 368 732 -205 194 28 -358 45 484 -572 -548 -270 -85 14 -271 275 0 -254 299 29 -229 86 -173 383 213 85 -718 279 112 91 381 36 -106 -113 41 197 -113 -95 243 -35 5 -90 55 159 311 373 73 76 52 439 -75 71 -139 -186 3 31 -48 255 -434 -74 -487 41 -322 -356 -185 176 -273 -249 -201 54 -28 102 -87 -62 -13 240 402 424 256 120 -36 194 -549 -408 -185 -442 -277 144 1 261 -172 272 107 36 199 144 210 -82 -149 -389 196 -87 281 124 -33 64 28 -208 354 -246 -81 25 69 170 -67 310 -48 125 -181 234 144 -54 -204 50 -2 114 36 -299 -211 -77 -9 -600 20 -195 -1 -384 501 52 417 43 295 -269 -73 124 -530 -168 -331 20 401 84 -213 -7 -78 -81 148 -240 125 177 -167 -264 -474 -363 -17 333 -58 151 -204 182 204 148 550 37 441 -87 -254 -57 76 -275 489 385 -88 69 177 -1 242 347 -310 -283 -151 324 149 61 -154 -108 -44 108 -292 -302 -91 -352 144 -240 111 309 -22 -2 -17 -66 825 808 33 278 -332 -21 135 -212 -382 80 87 13 99 -485 111 -184 -161 -45 -108 80 7 178 -46 -303 -134 392 -128 561 -177 -454 -23 -85 157 601 -48 88 -209 -135 -480 -204 -74 -228 -229 -24 205 -105 -148 -380 145 263 -133 -221 -436 -24 173 -144 411 89 122 163 11 -184 -135 -44 312 93 0 11 274 -140 196 249 625 476 22 -413 -77 -94 23 199 28 235 27 241 308 226 -52 -3 -807 411 23 14 228 -79 362 335 109 -103 156 -328 428 -402 -112 -160 -345 253 -283 -105 98 63 -381 -57 -270 224 -28 471 -210 762 -4 -34 -401 172 -479 -144 -169 -103 -81 -497 218 62 391 -60 218 114 181 131 176 59 238 -622 -89 185 -273 -221 -232 -430 -77 9 185 -67 -124 -534 -218 -43 104 51 -10 -356 -64 2 -254 -334 -42 -209 -71 128 270 503 554 -186 429 289 52 416 -231 -270 262 293 -12 -77 -424 131 221 -35 313 -843 248 149 -269 -12 344 90 83 48 -467 132 -294 -29 225 -170 -192 -27 -109 -204 -167 374 38 32 116 33 -156 -154 -90 196 -46 -214 -70 -163 -166 -286 185 55 152 179 -17 -592 127 504 -174 -116 180 374 -392 84 10 78 -212 -66 4 327 85 -298 538 87 -180 -138 223 264 202 22 426 85 -236 -66 39 -276 -112 220 -561 136 -15 -49 -443 180 -150 -310 32 170 122 213 383 20 -51 -193 266 489 30 20 24 379 8 333 -40 -133 -374 -121 -131 -198 -312 144 163 -148 37 -36 -5 -228 -271 183 -29 164 76 -69 196 -192 -561 -57 -10 -5 396 -55 -81 140 -400 685 -325 -228 141 -18 186 111 89 -134 -59 -166 -132 181 193 414 -315 257 375 -203 -44 209 178 147 -517 0 -197 343 707 -201 196 29 -364 45 473 -569 -559 -282 -86 14 -279 279 0 -253 296 29 -226 87 -172 378 213 83 -726 279 111 89 372 36 -107 -116 42 200 -113 -93 229 -33 5 -84 52 150 288 352 71 75 51 430 -74 71 -136 -186 3 32 -49 257 -429 -71 -466 39 -319 -361 -187 176 -271 -245 -197 53 -28 101 -87 -63 -13 247 417 430 263 124 -38 201 -569 -419 -188 -446 -286 147 1 268 -179 281 110 36 196 138 203 -78 -143 -375 189 -85 268 121 -33 65 29 -214 360 -250 -82 25 68 165 -65 301 -47 123 -180 235 147 -56 -216 53 -3 118 37 -307 -219 -80 -9 -628 21 -205 -1 -407 520 53 418 44 300 -276 -76 124 -544 -173 -343 20 405 87 -223 -7 -81 -85 155 -252 131 186 -172 -276 -501 -386 -18 350 -61 157 -214 190 214 155 576 39 466 -93 -271 -61 80 -294 518 422 -93 75 191 -1 257 369 -333 -305 -162 344 155 62 -159 -112 -46 114 -313 -324 -97 -379 156 -264 123 339 -24 -2 -17 -68 841 829 33 287 -353 -22 145 -228 -410 84 91 14 104 -520 119 -199 -174 -49 -115 85 8 191 -49 -327 -143 409 -132