File name: Pandora206s1_BuffaloNY_20231205_L2Fit_fout2c4d20220512p1-8.txt
File generation date: 20241121T065807.0Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c4p1-8
Local principal investigator: Kang Sun
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 206
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora206_OF_v3d20211008.txt
Instrument calibration file used: Pandora206s1_CF_v4d20220512.txt
Level 1 file used: Pandora206s1_BuffaloNY_20231205_L1_smca1c4d20220512p1-8.txt
Full location name: University at Buffalo
Short location name: BuffaloNY
Country of location: Canada
Location latitude [deg]: 43.0015
Location longitude [deg]: -78.7869
Location altitude [m]: 190
Local noon date: 20231205
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 223 365
Nominal wavelengths inside fitting window [nm]: 305.0744 305.2154 305.3564 305.4973 305.6383 305.7792 305.9201 306.0611 306.2020 306.3428 306.4837 306.6246 306.7654 306.9063 307.0471 307.1879 307.3287 307.4695 307.6103 307.7511 307.8918 308.0326 308.1733 308.3140 308.4548 308.5955 308.7362 308.8768 309.0175 309.1582 309.2988 309.4394 309.5801 309.7207 309.8613 310.0019 310.1424 310.2830 310.4236 310.5641 310.7046 310.8451 310.9857 311.1261 311.2666 311.4071 311.5476 311.6880 311.8285 311.9689 312.1093 312.2497 312.3901 312.5305 312.6708 312.8112 312.9515 313.0919 313.2322 313.3725 313.5128 313.6531 313.7934 313.9336 314.0739 314.2141 314.3543 314.4946 314.6348 314.7750 314.9151 315.0553 315.1955 315.3356 315.4758 315.6159 315.7560 315.8961 316.0362 316.1763 316.3163 316.4564 316.5964 316.7364 316.8765 317.0165 317.1565 317.2964 317.4364 317.5764 317.7163 317.8563 317.9962 318.1361 318.2760 318.4159 318.5558 318.6956 318.8355 318.9753 319.1152 319.2550 319.3948 319.5346 319.6744 319.8141 319.9539 320.0937 320.2334 320.3731 320.5128 320.6525 320.7922 320.9319 321.0716 321.2112 321.3509 321.4905 321.6301 321.7697 321.9093 322.0489 322.1885 322.3280 322.4676 322.6071 322.7467 322.8862 323.0257 323.1652 323.3046 323.4441 323.5836 323.7230 323.8624 324.0018 324.1413 324.2806 324.4200 324.5594 324.6988 324.8381 324.9774
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Spectrometer control temperature [°C], 999=no temperature signal
Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 96: Temperature in head sensor [°C], 999=no temperature signal
Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20231205T150758.5Z 8739.630538 325 1 27.03 2 70.78 151.23 58.69 248.49 0.00 1 0.00 1 0 17 1.721e-01 7.110e-03 1.669e-01 5.589e-03 4.784719e-01 2.753108e-03 5.668140e-03 -6.000000e+00 9.443631e-02 222.46 -2.00 3.55 -2.00 319.56 0.00e+00 1.955520e-03 7.805467e-04 6.259174e-04 -6.000000e+00 4.132678e-03 275.49 -2.00 20.00 -2.00 319.01 0.00e+00 3.003 0.000 302.00 328.00 3 5.2904e+00 7.7078e-03 3.8339e-02 -6.0000e+00 2.3252e-01 3.4760e-02 9.1744e-03 2.5217e-02 -6.0000e+00 2.5411e-01 6.8088e-03 7.9341e-03 1.2479e-02 -6.0000e+00 1.5132e-01 -1.1676e-02 4.2162e-03 4.4368e-03 -6.0000e+00 6.4692e-02 7.7076e-05 -6.4772e-05 1.5123e-04 4.0354e-05 -6.0000e+00 4.3819e-03 -1.2287e-02 1.6784e-04 12 9 1 12 1 1 98.88 17.91 0.41 -0.01229 -0.01277 6 7 1 8 0 3860.430 15.00 17.91 9.22 21.48 21.38 19.0 931.66 5413 8665 120565 -2217 135328 -18619 4773 23682 21304 5739 69249 -2125 -6540 -4231 -15151 12078 -1402 4565 -7902 -2534 -5776 -6382 -2083 1087 8670 -4266 4658 -4906 4870 -481 -496 1434 6901 2204 -2494 -8571 1635 -1411 2287 -2670 -8421 -322 -575 1748 805 -1266 -3717 -5053 -2081 1572 1936 2108 -59 2081 1115 1662 1203 676 1956 -2150 1219 1801 1203 1550 -223 401 -1950 -791 536 -197 855 600 1269 631 -730 -108 -1929 1472 -1529 -1378 -577 -485 -1621 -262 -761 -148 226 -163 1234 171 1212 1051 323 541 -26 -870 446 736 280 260 295 -255 -934 -388 -603 -1316 -929 88 -306 -109 169 443 -677 -101 -363 360 -85 -130 -178 -242 58 -1090 287 -40 1863 390 342 266 1529 -479 490 452 -527 120 19 199 -170 364 -150 -276 -187 -321 -232 64 114 657 -34 738 -289 63 304 308 106 706 -46 -183 -143 -676 498 -70 234 -491 -157 -380 -417 -136 75 608 -349 368 -407 348 -38 -45 146 737 264 -292 -1045 206 -209 399 -588 -2125 -79 -149 451 211 -345 -1042 -1449 -591 447 602 721 -22 804 456 696 521 292 834 -913 532 832 626 867 -131 219 -1083 -436 307 -128 605 443 920 437 -482 -65 -1088 790 -924 -946 -439 -405 -1443 -241 -754 -152 242 -175 1346 181 1195 985 287 480 -25 -930 521 950 380 346 375 -302 -1046 -444 -736 -1653 -1221 119 -434 -167 273 736 -1113 -160 -546 520 -124 -193 -277 -396 95 -1736 449 -59 2669 557 466 374 2309 -774 826 796 -947 225 38 400 -342 745 -308 -555 -364 -607 -426
SS 20231205T151254.6Z 8739.633966 327 1 23.84 2 70.35 152.35 59.53 249.49 0.00 1 0.00 1 0 17 8.320e-02 5.950e-03 6.809e-02 4.088e-03 4.696349e-01 2.008167e-03 5.579589e-03 -6.000000e+00 4.563541e-02 222.46 -2.00 3.55 -2.00 319.44 0.00e+00 1.856888e-03 5.456221e-04 2.801809e-04 -6.000000e+00 1.997491e-03 275.49 -2.00 20.00 -2.00 318.88 0.00e+00 2.942 0.000 302.00 328.00 3 4.7129e+00 5.5910e-03 3.7442e-02 -6.0000e+00 1.1236e-01 3.6801e-02 6.5998e-03 2.4242e-02 -6.0000e+00 1.2280e-01 -1.1490e-02 5.5196e-03 1.2252e-02 -6.0000e+00 7.3125e-02 -1.9243e-03 2.9411e-03 4.1546e-03 -6.0000e+00 3.1259e-02 1.4774e-04 -3.1327e-04 1.1070e-04 4.0211e-05 -6.0000e+00 2.1180e-03 -1.2195e-02 1.2901e-04 12 1 1 12 1 1 98.16 17.91 0.42 -0.01220 -0.01455 10 8 1 8 0 2166.690 15.00 17.91 9.45 21.48 21.27 19.0 933.33 -28727 329 33594 -77045 -22773 -4340 4889 -12533 -11423 2849 7096 -9592 6922 -8717 1639 -4869 -4640 -5183 -1378 -5963 1074 1133 3671 7289 1486 -8388 1337 -199 -4153 952 -509 157 2698 -3818 -2067 -2447 -4354 179 1823 -1752 -658 -1620 -277 -1220 2009 -1105 -307 -3862 575 280 869 596 708 1972 1272 1389 507 86 677 -1050 494 1758 1604 1362 484 38 720 394 1006 -31 844 1212 506 -28 168 -672 -405 -624 -916 -1129 -506 -736 -1589 -925 -1193 -309 -96 61 178 895 707 426 -101 -249 210 594 261 510 91 -194 148 -421 -1082 -326 -582 -1425 -645 35 -634 94 594 332 -7 40 49 492 -102 -279 -480 -363 -90 141 81 44 1120 164 398 1106 626 386 374 -174 109 70 -270 -377 225 72 93 -198 -335 -164 -295 -541 5 441 -2782 -449 -69 77 -265 -271 63 153 -263 196 -336 69 -258 -267 -325 -89 -423 73 76 249 518 119 -784 116 -17 -343 82 -48 17 323 -521 -258 -300 -604 28 340 -406 -168 -442 -78 -354 566 -326 -90 -1186 172 87 294 211 269 798 544 609 231 39 296 -461 220 846 864 775 285 22 403 222 578 -21 618 920 383 -20 111 -420 -232 -352 -566 -776 -396 -621 -1460 -883 -1170 -321 -105 69 198 950 692 404 -91 -223 206 630 301 666 123 -258 191 -494 -1224 -376 -701 -1816 -857 47 -919 143 972 541 -11 63 75 702 -148 -422 -745 -591 -147 221 124 68 1603 237 548 1558 943 613 639 -300 194 130 -519 -763 444 146 187 -396 -638 -309 -539