File name: Pandora206s1_BuffaloNY_20240901_L2Fit_fwvt1c6d20240814p1-8.txt File generation date: 20241204T195627.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Kang Sun Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 206 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora206_OF_v3d20211008.txt Instrument calibration file used: Pandora206s1_CF_v6d20240814.txt Level 1 file used: Pandora206s1_BuffaloNY_20240901_L1_smca1c6d20240814p1-8.txt Full location name: University at Buffalo Short location name: BuffaloNY Country of location: Canada Location latitude [deg]: 43.0015 Location longitude [deg]: -78.7869 Location altitude [m]: 190 Local noon date: 20240901 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1793 Nominal wavelengths inside fitting window [nm]: 492.0089 492.1299 492.2509 492.3719 492.4929 492.6139 492.7349 492.8558 492.9767 493.0976 493.2185 493.3394 493.4602 493.5810 493.7019 493.8227 493.9434 494.0642 494.1850 494.3057 494.4264 494.5471 494.6678 494.7885 494.9091 495.0297 495.1504 495.2709 495.3915 495.5121 495.6326 495.7532 495.8737 495.9942 496.1147 496.2351 496.3556 496.4760 496.5964 496.7168 496.8372 496.9575 497.0779 497.1982 497.3185 497.4388 497.5591 497.6793 497.7996 497.9198 498.0400 498.1602 498.2804 498.4005 498.5207 498.6408 498.7609 498.8810 499.0011 499.1211 499.2411 499.3612 499.4812 499.6012 499.7211 499.8411 499.9610 500.0809 500.2008 500.3207 500.4406 500.5604 500.6803 500.8001 500.9199 501.0396 501.1594 501.2792 501.3989 501.5186 501.6383 501.7580 501.8776 501.9973 502.1169 502.2365 502.3561 502.4757 502.5952 502.7148 502.8343 502.9538 503.0733 503.1927 503.3122 503.4316 503.5511 503.6705 503.7898 503.9092 504.0286 504.1479 504.2672 504.3865 504.5058 504.6250 504.7443 504.8635 504.9827 505.1019 505.2211 505.3403 505.4594 505.5785 505.6976 505.8167 505.9358 506.0549 506.1739 506.2929 506.4119 506.5309 506.6499 506.7688 506.8878 507.0067 507.1256 507.2445 507.3633 507.4822 507.6010 507.7198 507.8386 507.9574 508.0761 508.1949 508.3136 508.4323 508.5510 508.6697 508.7883 508.9070 509.0256 509.1442 509.2628 509.3814 509.4999 509.6184 509.7370 509.8555 509.9739 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240901T105053.9Z 9010.452012 60 1 46.52 2 88.92 80.04 71.62 83.17 0.00 1 0.00 1 0 36 1.902e-02 1.880e-02 8.616e-04 8.590e-04 1.515056e+04 6.272735e+01 9.698274e+02 -6.000000e+00 1.099481e+03 286.51 -2.00 20.00 -2.00 505.42 0.00e+00 5.042848e-03 2.436716e-05 2.982363e-04 -6.000000e+00 5.432306e-04 286.51 -2.00 20.00 -2.00 501.02 0.00e+00 1.527926e-01 1.674608e-02 1.152722e-01 -6.000000e+00 3.792769e-01 230.26 -2.00 3.55 -2.00 502.52 0.00e+00 18.371 0.119 489.00 513.00 1 4.4104e+00 1.2873e-03 3.2939e-02 -6.0000e+00 2.9197e-02 -3.1326e-02 3.1724e-04 3.0729e-03 -6.0000e+00 7.4323e-03 1.6548e-03 9.6201e-04 8.5978e-05 1.4415e-04 -6.0000e+00 2.0828e-03 6.4394e-04 1.3665e-04 12 8 8 10 0 0 97.87 17.35 15.47 0.00064 0.00732 31 10 1 2 0 1500.530 15.00 17.35 25.62 20.14 19.85 24.3 974.97 -3528 -2908 -1433 420 1958 3049 3710 4188 3692 2840 1807 731 -81 -1023 -1480 -1721 -983 -240 823 1399 1326 1190 1194 1290 1655 1718 1380 645 -718 -2484 -3493 -3278 -2614 -894 372 820 377 -1 -461 -803 -713 -166 424 1410 1959 2337 2260 1491 397 -689 -2131 -3322 -3672 -3449 -2098 -472 709 1333 1609 1707 1630 1822 2161 1923 1625 914 16 -706 -1399 -2048 -2348 -2415 -1725 -1152 -801 -1131 -1575 -2596 -3038 -3109 -2602 -2447 -2049 -1721 -1150 -1062 -1018 -1059 -951 -749 -17 788 1679 2414 1918 1299 574 -755 -2265 -3488 -3984 -3608 -2426 -1127 187 -99 -478 -1311 -1407 -1132 -246 535 1436 2225 2962 3337 3429 3550 2990 1917 1003 342 320 811 1425 1713 1832 1799 1516 1336 977 -37 -928 -1444 -1602 -1223 -359 221 652 1187 1440 1355 1334 1437 1260 942 -43 -1371 -2349 -2963 -2529 -3161 -2620 -1310 378 1790 2829 3489 3964 3518 2708 1719 694 -76 -964 -1395 -1633 -938 -225 781 1341 1282 1157 1166 1267 1633 1703 1372 621 -709 -2436 -3401 -3190 -2495 -865 366 816 376 -1 -458 -799 -712 -167 430 1395 1956 2343 2268 1496 398 -683 -2097 -3242 -3567 -3371 -2072 -473 721 1370 1611 1714 1644 1847 2198 1965 1658 931 16 -712 -1406 -2052 -2347 -2419 -1732 -1164 -814 -1150 -1590 -2609 -3033 -3090 -2574 -2430 -2044 -1729 -1162 -1082 -1010 -1048 -965 -758 -18 778 1659 2367 1914 1268 547 -709 -2113 -3248 -3724 -3419 -2354 -1097 187 -101 -479 -1320 -1416 -1145 -250 549 1478 2292 3051 3456 3595 3659 3110 2001 1040 351 326 823 1447 1748 1876 1849 1564 1379 1007 -39 -954 -1485 -1658 -1279 -380 230 689 1266 1552 1475 1462 1538 1349 1006 -45 -1457 -2490 -3156 -2710 SQ 20240901T115013.0Z 9010.493205 92 1 27.71 2 78.14 90.10 61.18 93.01 0.00 1 0.00 1 0 15 3.581e-03 3.559e-03 1.132e-03 1.128e-03 5.532104e+03 7.590802e+01 3.888894e+02 -6.000000e+00 2.069870e+02 286.50 -2.00 20.00 -2.00 505.25 0.00e+00 8.928376e-04 3.166554e-05 5.519135e-05 -6.000000e+00 1.023134e-04 286.50 -2.00 20.00 -2.00 500.29 0.00e+00 5.064283e-01 2.272667e-02 3.545168e-02 -6.000000e+00 7.156793e-02 230.25 -2.00 3.55 -2.00 501.91 0.00e+00 4.712 0.002 489.00 513.00 1 6.4483e+00 1.7497e-03 7.3848e-03 -6.0000e+00 5.5072e-03 9.2041e-03 4.4164e-04 9.3363e-04 -6.0000e+00 1.4058e-03 1.5149e-03 1.7624e-03 1.1790e-04 4.2671e-05 -6.0000e+00 3.9201e-04 4.5875e-03 -6.8362e-05 10 0 0 10 0 0 99.98 17.32 2.28 0.00459 0.01681 18 18 1 2 0 1539.410 15.00 17.32 27.04 20.14 19.85 24.0 982.63 -690 -651 -347 -191 223 414 600 606 676 552 162 -25 -5 -223 -578 -504 -164 -104 18 278 363 240 318 150 117 415 52 44 42 -390 -550 -645 -364 -163 381 493 104 250 -39 -241 64 -129 49 189 92 379 418 297 50 -282 -494 -509 -805 -939 -556 -284 46 236 199 527 463 389 420 338 342 246 62 -347 -29 -338 -120 -448 -277 -290 -6 8 -124 -365 -318 -264 -506 -305 -95 -373 92 -199 -217 15 -284 -201 -86 17 415 423 565 174 227 -19 -139 -387 -793 -718 -692 -397 428 55 -114 -179 -365 -275 -122 34 263 447 521 530 586 401 356 62 197 -4 -41 -96 456 135 197 256 374 83 413 -32 -437 -246 -250 -478 42 139 95 238 256 244 168 217 201 186 146 -221 -476 -656 -446 -675 -640 -348 -197 230 436 627 640 716 581 169 -26 -5 -230 -593 -517 -169 -110 19 296 389 258 342 162 127 448 56 47 45 -400 -553 -664 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1.4316e-04 6.0414e-03 -6.0000e+00 5.7142e-03 -6.7449e-03 3.6205e-05 7.4022e-04 -6.0000e+00 1.4579e-03 1.1274e+00 1.0833e-03 9.8312e-06 3.4587e-05 -6.0000e+00 4.0696e-04 2.5806e-03 -2.0144e-05 10 0 0 10 0 0 30.80 17.32 2.38 0.00258 0.01010 1168 1168 2 2 0 4.200 15.00 17.32 27.79 20.14 19.85 24.1 987.59 -871 -725 -542 -64 234 440 666 708 672 565 236 19 -78 -211 -406 -460 -369 -184 115 297 237 275 263 182 323 380 177 46 98 -317 -547 -524 -420 -114 296 335 161 179 37 -108 -177 -98 -5 147 300 444 429 265 12 -192 -495 -720 -900 -895 -600 -178 110 244 342 374 424 479 513 403 378 261 20 -213 -227 -256 -382 -358 -260 -181 19 34 -222 -472 -485 -464 -524 -371 -281 -275 -120 -90 -117 -119 -141 -167 -70 10 315 548 466 334 248 -32 -204 -516 -754 -732 -598 -303 39 -51 -184 -204 -304 -273 -53 140 272 461 577 569 537 572 496 239 150 108 -3 119 296 170 216 327 127 118 322 19 -285 -290 -363 -375 -15 109 66 239 365 258 260 280 195 143 83 -174 -538 -727 -591 -857 -715 -536 -65 240 452 695 747 698 594 246 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