File name: Pandora118s1_Cabauw_20170801_L2Fit_fwvt1c10d20170202p1-8.txt File generation date: 20241116T031723.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Ankie Piters Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 118 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora118_of_v2d20160829.txt Instrument calibration file used: Pandora118s1_CF_v10d20170202.txt Level 1 file used: Pandora118s1_Cabauw_20170801_L1_smca1c10d20170202p1-8.txt Full location name: Cabauw Short location name: Cabauw Country of location: Netherlands Location latitude [deg]: 51.9704 Location longitude [deg]: 4.9262 Location altitude [m]: 0 Local noon date: 20170801 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1801 Nominal wavelengths inside fitting window [nm]: 492.0580 492.1793 492.3007 492.4221 492.5434 492.6647 492.7860 492.9073 493.0286 493.1498 493.2711 493.3923 493.5135 493.6347 493.7558 493.8770 493.9981 494.1192 494.2403 494.3614 494.4825 494.6035 494.7246 494.8456 494.9666 495.0875 495.2085 495.3295 495.4504 495.5713 495.6922 495.8131 495.9339 496.0548 496.1756 496.2964 496.4172 496.5380 496.6588 496.7795 496.9002 497.0209 497.1416 497.2623 497.3830 497.5036 497.6242 497.7448 497.8654 497.9860 498.1065 498.2271 498.3476 498.4681 498.5886 498.7091 498.8295 498.9499 499.0704 499.1908 499.3112 499.4315 499.5519 499.6722 499.7925 499.9128 500.0331 500.1534 500.2736 500.3938 500.5140 500.6342 500.7544 500.8746 500.9947 501.1149 501.2350 501.3551 501.4751 501.5952 501.7152 501.8352 501.9553 502.0752 502.1952 502.3152 502.4351 502.5550 502.6749 502.7948 502.9147 503.0345 503.1544 503.2742 503.3940 503.5138 503.6335 503.7533 503.8730 503.9927 504.1124 504.2321 504.3517 504.4714 504.5910 504.7106 504.8302 504.9498 505.0693 505.1889 505.3084 505.4279 505.5474 505.6668 505.7863 505.9057 506.0251 506.1445 506.2639 506.3833 506.5026 506.6219 506.7413 506.8605 506.9798 507.0991 507.2183 507.3375 507.4567 507.5759 507.6951 507.8143 507.9334 508.0525 508.1716 508.2907 508.4098 508.5288 508.6478 508.7668 508.8858 509.0048 509.1238 509.2427 509.3616 509.4805 509.5994 509.7183 509.8371 509.9560 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170801T041001.0Z 6422.173623 334 1 32.00 2 89.82 60.21 132.41 307.50 0.00 1 0.00 1 0 29 3.434e-02 3.309e-02 3.117e-02 3.081e-02 6.369852e+03 2.193931e+03 3.371456e+02 -6.000000e+00 1.983305e+03 283.44 -2.00 20.00 -2.00 505.27 0.00e+00 3.779910e-03 8.659085e-04 1.918562e-04 -6.000000e+00 9.786663e-04 283.44 -2.00 20.00 -2.00 500.10 0.00e+00 1.984999e+00 6.410886e-01 6.848378e-02 -6.000000e+00 6.958847e-01 233.22 -2.00 3.84 -2.00 501.73 0.00e+00 20.078 0.180 489.00 513.00 1 8.9530e+00 4.9274e-02 3.9197e-02 -6.0000e+00 5.3477e-02 1.4339e-01 1.2378e-02 2.4748e-03 -6.0000e+00 1.3689e-02 1.1734e-05 8.0821e-04 3.3672e-03 7.6042e-05 -6.0000e+00 3.9221e-03 2.9298e-02 -1.8302e-04 12 9 8 11 8 0 45.24 22.86 4.32 0.02930 0.03490 8 2 1 4 0 4000.000 27.15 20.00 22.86 -1969 -622 427 -571 -4050 586 334 2500 2498 -320 -1488 2858 -4151 -4196 2538 -2173 -421 -4428 3370 589 1215 -2857 1046 -3647 1001 -400 -42 363 5621 4979 2153 817 4975 3328 941 746 932 -110 -418 -1758 1751 -2226 -5781 -2284 -914 27 -3255 -3181 -2643 3212 555 583 2180 725 -534 2156 3429 3850 1289 -657 -480 699 589 -4691 1365 1924 10438 403 -3019 6091 1231 -4665 -534 -1496 -6497 -5614 10038 3838 6428 2151 -3449 2684 -102 2859 -6213 -1493 562 3839 -2416 -4081 -2221 1831 2029 4752 78 -4020 -76 -6448 -2813 6770 7026 5423 2558 229 585 -82 -2510 1774 1192 3525 2895 -2485 723 7918 -5417 -5186 -3773 -72 628 -3037 5905 -3552 -1720 297 -35 -1849 -6024 417 10160 3882 2428 -5714 -1252 3046 2182 443 -1287 -1655 120 -85 -742 4741 -368 -460 4078 -2694 2747 -4768 425 -3591 -1946 -615 429 -597 -4491 634 368 2709 2699 -351 -1624 2947 -4513 -4512 2540 -2290 -442 -4924 3531 642 1320 -3228 1139 -4178 1099 -445 -46 392 5626 4891 2147 830 4944 3445 1018 812 1006 -119 -448 -1905 1837 -2443 -6649 -2566 -1020 30 -3689 -3553 -2878 3226 558 574 2103 717 -546 2200 3519 3966 1361 -707 -516 745 627 -5241 1421 1962 9641 405 -3090 5643 1187 -4765 -528 -1503 -6864 -5821 8781 3518 5684 1971 -3345 2459 -97 2649 -6309 -1454 536 3532 -2354 -4054 -2183 1746 1943 4407 75 -3902 -69 -6082 -2504 5421 5624 4496 2244 211 546 -78 -2398 1616 1091 3180 2658 -2435 694 7153 -5598 -5380 -3877 -71 612 -3026 5315 -3466 -1644 279 -34 -1782 -6057 393 8681 3504 2200 -5522 -1147 2663 1936 405 -1218 -1593 115 -83 -728 4423 -362 -452 3809 -2657 2519 -4616 388 -3413 SO 20170801T041411.0Z 6422.176516 338 1 32.00 2 89.26 61.03 132.90 308.64 0.00 1 0.00 1 0 15 2.463e-02 2.461e-02 2.104e-02 2.087e-02 4.116920e+03 1.421221e+03 3.243935e+02 -6.000000e+00 1.422858e+03 283.44 -2.00 20.00 -2.00 505.30 0.00e+00 1.921716e-03 5.853296e-04 1.107793e-04 -6.000000e+00 7.019686e-04 283.44 -2.00 20.00 -2.00 500.20 0.00e+00 2.841398e+00 4.309466e-01 3.072643e-02 -6.000000e+00 4.984824e-01 233.22 -2.00 3.84 -2.00 501.83 0.00e+00 19.113 0.155 489.00 513.00 1 8.6544e+00 3.3144e-02 3.5396e-02 -6.0000e+00 3.8317e-02 1.0758e-01 8.3264e-03 2.0490e-03 -6.0000e+00 9.7896e-03 1.7575e-05 -3.0248e-03 2.2860e-03 5.6198e-05 -6.0000e+00 2.8122e-03 3.2499e-02 -8.4900e-05 12 9 8 11 8 0 53.23 22.86 3.17 0.03250 0.01152 8 2 1 4 0 4000.000 27.15 20.00 22.86 -3531 1134 -1400 4495 -5668 2902 2 3944 643 -2476 2625 -397 -2021 -4641 1015 1364 1156 2872 13 -2111 -2781 820 2526 1492 2312 2461 -1651 -1167 -912 -2222 -1862 963 302 1724 161 -5816 266 1082 1637 1751 -1377 3756 -1129 4661 -1496 2205 182 -549 -1828 2689 -1348 -580 -1173 1029 -847 -620 3984 40 -952 -3108 1136 -1789 4092 -1897 -1051 -178 2203 2878 -1049 431 -3753 1465 745 159 870 -807 -75 430 422 3171 -547 -6654 -2139 217 3738 -2244 907 -1983 277 -4629 1857 -1429 904 3923 1994 76 1943 1692 2344 -468 -1306 -7385 181 -793 4920 -2948 4029 -1828 2328 -2323 281 152 -3281 1170 -1709 2264 3643 628 3684 2463 -1965 5073 -1298 4335 2673 -1857 -3763 -4693 -2373 -2770 1726 -710 -272 115 -399 -2107 4788 -938 846 2049 759 2844 -3183 -807 -173 -1811 1431 1166 -834 -840 -3476 1082 -1404 4385 -6270 3014 3 4154 696 -2741 2732 -418 -2134 -4977 1024 1379 1188 2963 14 -2356 -3130 896 2718 1621 2501 2656 -1845 -1280 -975 -2348 -1932 975 313 1816 176 -6753 290 1160 1727 1835 -1490 3886 -1234 4877 -1670 2374 198 -596 -1968 2697 -1371 -573 -1157 1003 -860 -642 4010 43 -1013 -3378 1184 -1924 4151 -2035 -1107 -184 2177 2782 -1041 416 -3757 1394 719 156 844 -789 -72 403 391 2860 -511 -6619 -2055 206 3438 -2193 860 -1933 263 -4627 1759 -1408 877 3680 1882 71 1753 1498 2017 -407 -1149 -7010 164 -747 4452 -2880 3655 -1737 2124 -2228 266 146 -3294 1134 -1716 2197 3500 621 3504 2340 -1918 4586 -1243 3951 2479 -1807 -3722 -4680 -2308 -2693 1595 -661 -249 105 -367 -2001 4325 -910 817 1976 747 2757 -3282 -814 -173 -1815 1364 1094 -790 -798 SO 20170801T041811.0Z 6422.179294 342 1 32.00 2 88.72 61.81 133.36 309.74 0.00 1 0.00 1 0 22 1.985e-02 1.947e-02 1.442e-02 1.430e-02 9.854584e+03 1.066340e+03 6.982547e+02 -6.000000e+00 1.146500e+03 283.44 -2.00 20.00 -2.00 505.31 0.00e+00 2.653173e-03 4.015752e-04 1.395577e-04 -6.000000e+00 5.656554e-04 283.44 -2.00 20.00 -2.00 500.22 0.00e+00 1.540367e+00 2.965428e-01 5.880739e-02 -6.000000e+00 4.017718e-01 233.22 -2.00 3.84 -2.00 501.85 0.00e+00 17.851 0.126 489.00 513.00 1 8.5142e+00 2.2770e-02 3.1856e-02 -6.0000e+00 3.0882e-02 1.1427e-01 5.6861e-03 2.2598e-03 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