File name: Pandora118s1_Cabauw_20170912_L2Fit_fwvt1c10d20170202p1-8.txt File generation date: 20241116T034546.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Ankie Piters Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 118 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora118_of_v2d20160829.txt Instrument calibration file used: Pandora118s1_CF_v10d20170202.txt Level 1 file used: Pandora118s1_Cabauw_20170912_L1_smca1c10d20170202p1-8.txt Full location name: Cabauw Short location name: Cabauw Country of location: Netherlands Location latitude [deg]: 51.9704 Location longitude [deg]: 4.9262 Location altitude [m]: 0 Local noon date: 20170912 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1801 Nominal wavelengths inside fitting window [nm]: 492.0580 492.1793 492.3007 492.4221 492.5434 492.6647 492.7860 492.9073 493.0286 493.1498 493.2711 493.3923 493.5135 493.6347 493.7558 493.8770 493.9981 494.1192 494.2403 494.3614 494.4825 494.6035 494.7246 494.8456 494.9666 495.0875 495.2085 495.3295 495.4504 495.5713 495.6922 495.8131 495.9339 496.0548 496.1756 496.2964 496.4172 496.5380 496.6588 496.7795 496.9002 497.0209 497.1416 497.2623 497.3830 497.5036 497.6242 497.7448 497.8654 497.9860 498.1065 498.2271 498.3476 498.4681 498.5886 498.7091 498.8295 498.9499 499.0704 499.1908 499.3112 499.4315 499.5519 499.6722 499.7925 499.9128 500.0331 500.1534 500.2736 500.3938 500.5140 500.6342 500.7544 500.8746 500.9947 501.1149 501.2350 501.3551 501.4751 501.5952 501.7152 501.8352 501.9553 502.0752 502.1952 502.3152 502.4351 502.5550 502.6749 502.7948 502.9147 503.0345 503.1544 503.2742 503.3940 503.5138 503.6335 503.7533 503.8730 503.9927 504.1124 504.2321 504.3517 504.4714 504.5910 504.7106 504.8302 504.9498 505.0693 505.1889 505.3084 505.4279 505.5474 505.6668 505.7863 505.9057 506.0251 506.1445 506.2639 506.3833 506.5026 506.6219 506.7413 506.8605 506.9798 507.0991 507.2183 507.3375 507.4567 507.5759 507.6951 507.8143 507.9334 508.0525 508.1716 508.2907 508.4098 508.5288 508.6478 508.7668 508.8858 509.0048 509.1238 509.2427 509.3616 509.4805 509.5994 509.7183 509.8371 509.9560 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170912T051703.0Z 6464.220174 300 1 32.00 2 89.78 83.63 37.32 197.44 0.00 1 0.00 1 0 15 3.790e-02 3.782e-02 3.114e-02 3.083e-02 1.021161e+04 2.304357e+03 6.886707e+02 -6.000000e+00 2.165771e+03 280.80 -2.00 20.00 -2.00 505.32 0.00e+00 3.407286e-03 8.656662e-04 1.926412e-04 -6.000000e+00 1.073412e-03 280.80 -2.00 20.00 -2.00 500.24 0.00e+00 1.982153e+00 6.400969e-01 6.746984e-02 -6.000000e+00 7.637677e-01 229.17 -2.00 3.84 -2.00 501.86 0.00e+00 20.127 0.181 489.00 513.00 1 8.9653e+00 4.9089e-02 3.9358e-02 -6.0000e+00 5.8682e-02 1.2193e-01 1.2259e-02 2.6454e-03 -6.0000e+00 1.4975e-02 1.1537e-05 -8.6994e-03 3.2552e-03 9.5044e-05 -6.0000e+00 4.3238e-03 -2.1458e-03 1.8531e-04 12 8 8 10 0 0 95.26 21.61 3.17 -0.00215 -0.06249 8 2 1 4 0 4000.000 26.11 20.03 21.61 7094 853 -420 3653 -4105 -6016 3054 6661 -415 983 -4124 -5899 -9717 -7831 -9158 11370 -1969 4256 -2262 656 1649 1264 6648 2755 4167 -2252 4414 -2383 1919 -1659 2819 -6835 2119 5452 30 3578 1252 1696 4436 153 -2718 176 -1975 3814 -6943 942 1710 2643 -2143 -6143 4109 -618 -2140 -2626 994 505 -1352 -1710 3880 4084 3163 412 -1114 -1476 -651 2154 4657 4166 -3824 766 4626 -667 3633 -2971 -5924 -196 3927 -2335 4491 6322 785 -1657 -2467 2116 5666 -2185 -5130 2663 -5250 9261 -1262 -10 5036 -2156 -2139 -633 8374 3547 -3566 506 443 916 -1617 -3683 4176 1121 -2959 25 6573 3326 -2499 -1140 -2553 -3747 -2271 -507 -2086 5171 796 -2095 858 -464 -2219 -4832 1064 4891 -2596 -832 7358 468 110 24 748 694 4037 -3606 -2417 -3601 -1697 1478 -1116 -133 -3025 -5193 7993 -1986 2499 -820 1780 -909 6303 809 -413 3562 -4438 -6767 3206 6814 -454 1052 -4582 -6570 -11039 -8622 -10146 10350 -2056 4273 -2465 704 1764 1360 6797 2927 4385 -2532 4622 -2641 1996 -1743 2780 -7386 2134 5455 33 3769 1347 1803 4542 162 -2960 187 -2172 4007 -8170 1032 1852 2804 -2336 -6807 4018 -619 -2147 -2661 991 520 -1442 -1852 3989 4191 3278 440 -1210 -1601 -694 2213 4591 4064 -3970 751 4341 -657 3450 -3039 -6244 -194 3686 -2287 4072 5589 730 -1585 -2392 1976 5144 -2149 -5196 2496 -5287 8092 -1227 -9 4669 -2132 -2080 -592 6952 3004 -3167 425 372 778 -1450 -3485 3766 1050 -2881 23 5760 3028 -2432 -1109 -2544 -3806 -2279 -503 -2121 4927 787 -2106 824 -446 -2152 -4798 1004 4458 -2546 -802 6544 443 103 22 683 631 3564 -3473 -2342 -3578 -1679 1434 -1121 -133 -3119 -5478 7385 -2001 2377 -789 1655 -865 SO 20170912T052134.0Z 6464.223310 304 1 32.00 2 89.09 84.52 37.53 199.15 0.00 1 0.00 1 0 15 1.933e-02 1.923e-02 1.462e-02 1.454e-02 9.370285e+03 1.058968e+03 6.648976e+02 -6.000000e+00 1.104163e+03 280.80 -2.00 20.00 -2.00 505.35 0.00e+00 3.405394e-03 4.069912e-04 1.808762e-04 -6.000000e+00 5.475592e-04 280.80 -2.00 20.00 -2.00 500.39 0.00e+00 2.525871e+00 2.971295e-01 6.350013e-02 -6.000000e+00 3.904764e-01 229.17 -2.00 3.84 -2.00 501.99 0.00e+00 18.820 0.148 489.00 513.00 1 8.3305e+00 2.2827e-02 3.4894e-02 -6.0000e+00 2.9987e-02 7.8477e-02 5.6519e-03 2.4099e-03 -6.0000e+00 7.6790e-03 2.5248e-05 2.6231e-03 1.5589e-03 9.0778e-05 -6.0000e+00 2.2071e-03 1.9700e-02 -1.5694e-04 12 9 8 11 8 0 97.21 21.61 1.32 0.01970 0.03790 8 2 1 4 0 4000.000 26.11 19.99 21.61 -3256 -1333 236 -203 -413 -2705 -149 -2450 2718 -1170 563 -623 -382 -1019 1061 -386 1302 -1144 392 2830 -22 3026 22 2351 342 1990 -1433 1700 -2218 -2057 -526 -987 1076 -326 1326 -1561 -1108 854 156 -548 861 2464 -545 -198 -623 -32 -1222 1977 -724 1981 -265 -998 529 780 1913 -377 1804 -3853 2899 849 601 425 2984 -32 -1491 -182 -3014 2273 -1507 4227 -1838 -1112 -1798 -664 1324 146 1459 -516 2835 -377 859 -2570 2426 -1704 666 -3622 1214 -2963 339 105 -763 865 -3126 2433 1070 2829 2067 -1799 -2457 -46 -679 -1650 1992 276 -1828 -3005 2716 492 3939 2244 -2001 -1251 1161 1057 -242 -269 -1424 4189 -3272 2496 -14 1102 -207 1501 -2102 -352 984 -1872 4594 -2005 -1126 -2695 -1147 1551 -358 496 1445 1664 -570 4021 -1062 3359 -718 2509 -69 1171 1328 -1422 -4573 -6376 -3102 -1265 227 -202 -423 -2888 -157 -2659 2803 -1241 578 -639 -386 -1024 1041 -387 1302 -1194 411 2924 -24 3143 24 2469 368 2106 -1554 1767 -2334 -2118 -527 -1000 1092 -344 1404 -1705 -1199 898 164 -578 897 2550 -587 -215 -683 -35 -1337 2074 -765 1994 -265 -988 515 764 1898 -391 1865 -4236 2995 892 634 451 3087 -34 -1590 -189 -3165 2239 -1516 3987 -1827 -1100 -1805 -662 1299 143 1392 -495 2603 -356 802 -2487 2249 -1660 638 -3621 1158 -2929 324 101 -743 837 -3151 2309 1009 2551 1825 -1608 -2166 -39 -586 -1470 1767 258 -1771 -2951 2515 463 3583 2095 -1969 -1238 1132 1037 -242 -271 -1459 4077 -3396 2421 -14 1056 -200 1434 -2086 -345 952 -1857 4281 -1980 -1091 -2620 -1088 1435 -339 474 1395 1624 -578 3933 -1099 3344 -746 2529 -70 1176 1309 -1418 -4656 -6621 SO 20170912T052606.0Z 6464.226458 308 1 32.00 2 88.39 85.41 37.75 200.85 0.00 1 0.00 1 0 22 5.880e-03 5.928e-03 3.470e-03 3.459e-03 1.306022e+04 2.553517e+02 8.570953e+02 -6.000000e+00 3.359042e+02 280.80 -2.00 20.00 -2.00 505.41 0.00e+00 5.384897e-03 9.712456e-05 2.941863e-04 -6.000000e+00 1.666289e-04 280.80 -2.00 20.00 -2.00 500.73 0.00e+00 1.852590e+00 6.952154e-02 1.020865e-01 -6.000000e+00 1.189513e-01 229.17 -2.00 3.84 -2.00 502.28 0.00e+00 17.067 0.110 489.00 513.00 1 6.9863e+00 5.3316e-03 3.1066e-02 -6.0000e+00 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