File name: Pandora118s1_Cabauw_20180520_L2Fit_fwvt1c11d20171029p1-8.txt File generation date: 20241121T210602.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c11p1-8 Local principal investigator: Martin Tiefengraber Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 118 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora118_of_v4d20160829.txt Instrument calibration file used: Pandora118s1_CF_v11d20171029.txt Level 1 file used: Pandora118s1_Cabauw_20180520_L1_smca1c11d20171029p1-8.txt Full location name: Cabauw Short location name: Cabauw Country of location: Netherlands Location latitude [deg]: 51.9704 Location longitude [deg]: 4.9262 Location altitude [m]: 0 Local noon date: 20180520 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1801 Nominal wavelengths inside fitting window [nm]: 492.0537 492.1751 492.2965 492.4178 492.5391 492.6605 492.7817 492.9030 493.0243 493.1455 493.2667 493.3880 493.5091 493.6303 493.7515 493.8726 493.9937 494.1148 494.2359 494.3570 494.4780 494.5991 494.7201 494.8411 494.9621 495.0831 495.2040 495.3249 495.4459 495.5668 495.6876 495.8085 495.9294 496.0502 496.1710 496.2918 496.4126 496.5333 496.6541 496.7748 496.8955 497.0162 497.1369 497.2576 497.3782 497.4988 497.6194 497.7400 497.8606 497.9812 498.1017 498.2222 498.3427 498.4632 498.5837 498.7041 498.8246 498.9450 499.0654 499.1858 499.3061 499.4265 499.5468 499.6671 499.7874 499.9077 500.0280 500.1482 500.2685 500.3887 500.5089 500.6290 500.7492 500.8693 500.9895 501.1096 501.2297 501.3497 501.4698 501.5898 501.7099 501.8299 501.9499 502.0698 502.1898 502.3097 502.4296 502.5495 502.6694 502.7893 502.9091 503.0289 503.1488 503.2686 503.3883 503.5081 503.6278 503.7476 503.8673 503.9870 504.1066 504.2263 504.3459 504.4656 504.5852 504.7047 504.8243 504.9439 505.0634 505.1829 505.3024 505.4219 505.5414 505.6608 505.7802 505.8996 506.0190 506.1384 506.2578 506.3771 506.4964 506.6157 506.7350 506.8543 506.9736 507.0928 507.2120 507.3312 507.4504 507.5696 507.6887 507.8078 507.9270 508.0461 508.1651 508.2842 508.4032 508.5223 508.6413 508.7603 508.8792 508.9982 509.1171 509.2360 509.3549 509.4738 509.5927 509.7115 509.8304 509.9492 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180520T034739.0Z 6714.158090 310 1 32.00 2 89.81 56.65 109.77 354.68 0.00 1 0.00 1 0 22 5.079e-02 5.008e-02 4.556e-02 4.495e-02 5.822302e+02 2.681863e+03 2.590792e+02 -6.000000e+00 2.867687e+03 277.50 -2.00 20.00 -2.00 505.25 0.00e+00 1.210460e-03 1.234446e-03 8.029616e-05 -6.000000e+00 1.426697e-03 277.50 -2.00 20.00 -2.00 500.04 0.00e+00 2.760353e+00 9.227252e-01 7.157837e-02 -6.000000e+00 1.028226e+00 231.46 -2.00 3.84 -2.00 501.70 0.00e+00 20.250 0.184 489.00 513.00 1 6.7777e+00 7.0826e-02 3.9566e-02 -6.0000e+00 7.8896e-02 1.4432e-01 1.7944e-02 2.3328e-03 -6.0000e+00 2.0145e-02 9.9688e-05 7.2827e-03 4.9195e-03 6.9435e-05 -6.0000e+00 5.7925e-03 -4.3494e-02 5.4112e-04 12 8 8 10 0 0 83.39 21.83 6.63 -0.04349 0.00702 8 2 1 4 0 4000.000 26.32 20.00 21.83 -3812 -969 -6932 -1310 2234 4246 5333 -87 238 -3330 10613 -2953 -10425 4089 -9257 -1525 1459 -1116 -5463 2599 -3825 2930 7321 1368 2936 1150 6118 -652 -4282 -5395 1975 -8137 7930 -2079 -633 -1265 855 6316 2373 11117 -4959 14736 4064 7423 -143 -6292 -322 536 6902 -8088 8668 -7626 -5360 -4308 2562 472 5811 -4327 399 8270 772 -777 -5015 11022 -1577 3380 997 967 -1466 3501 3914 -4896 2973 -3477 7145 -6581 -913 -6279 8699 -3831 3766 -1772 982 4320 -2414 2265 -3116 895 -6085 126 7287 -2213 1830 1056 199 -8827 -726 -5933 9545 9074 6124 -5507 1512 2373 953 -6192 -1718 4269 -4165 7634 448 361 -2535 7953 -1423 4473 1150 -2795 -3120 4969 5516 2217 -1291 5908 5222 4347 -329 -2362 -1730 1345 -3790 5114 -8630 -5090 -3554 -3159 -2167 65 -7829 9738 -8478 -2000 -5966 -1069 5295 2800 3926 -4576 5382 5692 -3895 -985 -7680 -1412 2382 4517 5674 -98 264 -3777 10355 -3241 -12131 4100 -10586 -1638 1552 -1239 -6432 2842 -4457 3206 7683 1523 3219 1277 6410 -714 -4735 -5918 2007 -9254 7909 -2339 -710 -1426 935 6465 2505 10732 -5624 13888 4288 7630 -159 -7371 -352 571 6724 -8877 7882 -8029 -5536 -4485 2553 490 5785 -4763 419 8039 807 -826 -5545 10326 -1648 3305 983 940 -1442 3248 3612 -4949 2801 -3510 6449 -6692 -866 -6196 7375 -3672 3373 -1682 914 3916 -2354 2113 -3058 844 -6171 121 6579 -2211 1767 1018 191 -9066 -672 -5650 7682 7307 5122 -5283 1393 2196 895 -6193 -1624 3777 -4013 6640 424 346 -2533 7210 -1418 4228 1117 -2800 -3094 4482 4899 2029 -1226 5239 4671 3924 -310 -2265 -1643 1229 -3596 4377 -8377 -4775 -3324 -2997 -2071 61 -8088 8524 -8891 -1981 -6147 -1050 4829 2572 3494 -4355 4643 4942 SO 20180520T035222.0Z 6714.161366 314 1 32.00 2 89.20 57.57 109.83 355.81 0.00 1 0.00 1 0 15 3.754e-02 3.681e-02 3.484e-02 3.442e-02 5.379799e+03 2.365946e+03 4.196878e+02 -6.000000e+00 2.119000e+03 277.50 -2.00 20.00 -2.00 505.26 0.00e+00 1.684145e-03 9.512321e-04 7.231363e-05 -6.000000e+00 1.054435e-03 277.50 -2.00 20.00 -2.00 500.04 0.00e+00 1.833868e+00 7.171629e-01 2.913371e-02 -6.000000e+00 7.614100e-01 231.46 -2.00 3.84 -2.00 501.69 0.00e+00 19.140 0.156 489.00 513.00 1 6.7165e+00 5.5025e-02 3.5425e-02 -6.0000e+00 5.8399e-02 1.4618e-01 1.3861e-02 2.0884e-03 -6.0000e+00 1.4954e-02 1.3104e-04 1.1613e-03 3.7260e-03 5.2113e-05 -6.0000e+00 4.2849e-03 -7.4859e-03 1.5294e-04 12 8 8 10 0 0 71.14 21.83 3.74 -0.00749 0.00057 8 2 1 4 0 4000.000 26.32 20.00 21.83 -2083 -1197 5958 -4570 -5047 -888 -1798 4002 -2159 2535 -3421 -1611 1708 1175 -2452 -1180 -3514 -355 5105 469 4046 5090 -743 1704 -2941 -244 -977 -4297 318 1523 -4069 -15 5454 -2620 1177 4999 -3389 9580 -2948 1570 907 3969 -4956 -6204 683 5377 -1391 -3982 930 -4133 7953 4529 -834 -2981 226 2113 -499 4276 4399 4355 -3265 32 -965 3800 -4104 5754 4640 3906 4017 -6317 -1350 -5571 4767 -3361 -535 -5953 2271 1896 4184 -2027 3054 -1443 1065 8390 -5518 -1037 -2454 2280 6836 -2113 -2154 3877 1272 -39 2544 -3365 1534 3607 19 -2302 1649 2182 -191 121 5000 -3240 -2591 788 -5035 8800 6338 -911 -6814 -5543 -4219 -1520 5342 1850 695 -371 820 -3424 2321 1839 4596 2097 -4409 -1768 -1820 2378 -2449 285 -5392 175 563 -967 519 -351 13634 -2202 579 -750 73 2635 2572 -3041 -6505 -232 3708 -5275 -2079 -1201 5724 -5012 -5711 -985 -2034 4314 -2458 2723 -3843 -1751 1770 1211 -2612 -1248 -3851 -385 5359 519 4341 5412 -836 1882 -3401 -274 -1097 -4906 338 1563 -4363 -15 5463 -2913 1284 5276 -3866 9531 -3278 1660 967 4132 -5677 -7265 751 5637 -1548 -4463 975 -4425 7375 4263 -824 -3033 228 2143 -529 4347 4469 4423 -3570 34 -1033 3858 -4446 5582 4477 3741 3792 -6519 -1319 -5695 4445 -3414 -529 -6120 2123 1753 3746 -1925 2763 -1368 992 7347 -5557 -1006 -2406 2135 6112 -2067 -2124 3634 1229 -38 2372 -3238 1373 3084 16 -2018 1401 1879 -174 113 4518 -3170 -2498 729 -4908 7555 5647 -881 -7034 -5689 -4297 -1515 5005 1785 672 -358 768 -3315 2116 1689 4120 1930 -4316 -1682 -1728 2152 -2300 256 -5068 156 503 -888 478 -331 11367 -2157 556 -732 71 2495 2422 -2978 -6470 -214 3253 -5064 SO 20180520T035655.0Z 6714.164526 318 1 32.01 2 88.61 58.46 109.88 356.90 0.00 1 0.00 1 0 15 3.308e-02 3.250e-02 2.665e-02 2.640e-02 1.285135e+03 1.611763e+03 1.699061e+02 -6.000000e+00 1.867684e+03 277.50 -2.00 20.00 -2.00 505.25 0.00e+00 9.629970e-04 7.249420e-04 3.412676e-05 -6.000000e+00 9.293657e-04 277.50 -2.00 20.00 -2.00 500.11 0.00e+00 2.132530e+00 5.420918e-01 1.464085e-02 -6.000000e+00 6.710296e-01 231.46 -2.00 3.84 -2.00 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