File name: Pandora118s1_Cabauw_20210724_L2Fit_fwvt1c7d20210722p1-8.txt File generation date: 20240927T101637.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: Ankie Piters Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 118 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora118_OF_v3d20200505.txt Instrument calibration file used: Pandora118s1_CF_v7d20210722.txt Level 1 file used: Pandora118s1_Cabauw_20210724_L1_smca1c7d20210722p1-8.txt Full location name: Cabauw Short location name: Cabauw Country of location: Netherlands Location latitude [deg]: 51.9704 Location longitude [deg]: 4.9262 Location altitude [m]: 0 Local noon date: 20210724 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: based on 4 redo SO2 (reduce SO2) First and last pixel inside fitting window: 1653 1802 Nominal wavelengths inside fitting window [nm]: 492.1006 492.2218 492.3430 492.4641 492.5853 492.7064 492.8275 492.9486 493.0697 493.1907 493.3118 493.4328 493.5538 493.6748 493.7958 493.9167 494.0377 494.1586 494.2795 494.4004 494.5213 494.6422 494.7630 494.8838 495.0046 495.1254 495.2462 495.3670 495.4877 495.6084 495.7292 495.8499 495.9705 496.0912 496.2118 496.3325 496.4531 496.5737 496.6942 496.8148 496.9353 497.0559 497.1764 497.2969 497.4174 497.5378 497.6583 497.7787 497.8991 498.0195 498.1399 498.2602 498.3806 498.5009 498.6212 498.7415 498.8618 498.9820 499.1023 499.2225 499.3427 499.4629 499.5831 499.7033 499.8234 499.9435 500.0636 500.1837 500.3038 500.4239 500.5439 500.6639 500.7839 500.9039 501.0239 501.1439 501.2638 501.3837 501.5037 501.6235 501.7434 501.8633 501.9831 502.1029 502.2228 502.3425 502.4623 502.5821 502.7018 502.8215 502.9413 503.0609 503.1806 503.3003 503.4199 503.5395 503.6591 503.7787 503.8983 504.0179 504.1374 504.2569 504.3764 504.4959 504.6154 504.7348 504.8543 504.9737 505.0931 505.2125 505.3319 505.4512 505.5706 505.6899 505.8092 505.9285 506.0477 506.1670 506.2862 506.4054 506.5246 506.6438 506.7630 506.8822 507.0013 507.1204 507.2395 507.3586 507.4777 507.5967 507.7157 507.8348 507.9538 508.0727 508.1917 508.3107 508.4296 508.5485 508.6674 508.7863 508.9051 509.0240 509.1428 509.2616 509.3804 509.4992 509.6180 509.7367 509.8555 509.9742 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20210724T040802.8Z 7875.172254 174 1 48.97 2 88.58 58.75 94.54 235.18 0.00 1 0.00 1 0 50 1.646e-02 1.632e-02 9.277e-04 9.248e-04 9.309555e+03 6.468118e+01 5.738383e+02 -6.000000e+00 9.747761e+02 283.42 -2.00 20.00 -2.00 505.41 0.00e+00 4.454340e-03 2.641892e-05 2.412166e-04 -6.000000e+00 4.737758e-04 283.42 -2.00 20.00 -2.00 501.09 0.00e+00 7.960061e-01 1.835445e-02 8.903874e-02 -6.000000e+00 3.376733e-01 233.60 -2.00 3.84 -2.00 502.57 0.00e+00 17.475 0.118 489.00 513.00 1 5.3149e+00 1.4105e-03 3.1643e-02 -6.0000e+00 2.5992e-02 -4.6031e-02 3.4735e-04 2.4776e-03 -6.0000e+00 6.5945e-03 7.0122e-04 4.0773e-03 1.0608e-04 1.1233e-04 -6.0000e+00 2.0002e-03 -1.0941e-02 2.8252e-05 12 8 8 10 0 0 82.77 19.96 13.94 -0.01094 0.01734 15 3 1 4 0 3264.260 19.96 15.00 16.53 19.88 23.8 958.99 -4385 -3280 -1384 12 1673 2331 2742 2681 2266 1140 514 -571 -1556 -1955 -1784 -1346 -721 635 911 1215 723 1199 1363 1898 1685 1294 905 -234 -1542 -2512 -2608 -1837 -947 859 949 782 349 304 -168 -77 390 831 1421 1809 2272 1888 1607 360 -376 -1850 -2810 -3288 -2916 -1859 -616 508 1434 1422 1388 1709 2122 2299 2199 2082 1592 411 -521 -840 -1340 -1915 -1768 -1360 -812 -607 -778 -1426 -2133 -2141 -2545 -2340 -2215 -1706 -1531 -1115 -843 -862 -1021 -838 -547 73 799 1589 2162 1730 1298 518 -281 -1370 -2354 -3083 -2638 -1786 -716 -163 -133 -968 -1228 -1111 -968 -194 539 1350 2141 2844 3317 3378 3386 2611 1972 785 260 373 505 1186 1048 903 1092 798 531 476 -480 -1287 -1705 -1759 -1400 -837 -124 301 705 895 1138 903 1202 1104 748 -93 -1371 -2237 -2453 -1800 -3973 -3009 -1287 11 1538 2175 2584 2539 2146 1081 484 -536 -1462 -1834 -1673 -1271 -690 613 858 1154 694 1150 1314 1833 1640 1264 881 -227 -1484 -2399 -2486 -1762 -925 847 950 760 339 293 -162 -75 380 816 1407 1809 2282 1907 1618 362 -375 -1832 -2756 -3208 -2846 -1831 -616 515 1413 1415 1389 1712 2129 2315 2221 2099 1600 413 -522 -835 -1327 -1898 -1749 -1349 -809 -608 -782 -1430 -2127 -2115 -2513 -2306 -2191 -1692 -1531 -1122 -852 -876 -1040 -853 -556 72 787 1570 2132 1702 1303 512 -273 -1321 -2260 -2969 -2558 -1765 -699 -164 -135 -999 -1267 -1146 -969 -195 548 1380 2198 2929 3432 3526 3560 2770 2092 807 275 391 529 1240 1069 926 1121 822 549 490 -495 -1325 -1752 -1815 -1457 -881 -132 314 743 954 1221 977 1302 1197 809 -101 -1480 -2409 -2640 -1940 SQ 20210724T041106.1Z 7875.174376 178 1 36.34 2 88.17 59.35 94.91 235.75 0.00 1 0.00 1 0 22 1.302e-02 1.293e-02 7.686e-04 7.667e-04 1.130932e+04 5.507551e+01 7.086906e+02 -6.000000e+00 7.711436e+02 283.42 -2.00 20.00 -2.00 505.41 0.00e+00 4.067591e-03 2.191152e-05 2.307535e-04 -6.000000e+00 3.747125e-04 283.42 -2.00 20.00 -2.00 501.05 0.00e+00 8.766482e-01 1.530465e-02 9.865305e-02 -6.000000e+00 2.666790e-01 233.60 -2.00 3.84 -2.00 502.55 0.00e+00 16.417 0.098 489.00 513.00 1 4.7737e+00 1.1748e-03 2.9113e-02 -6.0000e+00 2.0533e-02 -5.7288e-02 2.8966e-04 2.6128e-03 -6.0000e+00 5.1988e-03 1.3946e-03 -7.5648e-04 8.6704e-05 1.1182e-04 -6.0000e+00 1.5804e-03 3.5355e-02 -1.2793e-04 12 9 9 12 1 1 69.44 19.96 10.90 0.03535 0.03011 20 6 1 4 0 1721.830 19.96 15.00 16.53 19.96 23.8 959.53 -3057 -2367 -950 139 1073 2069 2299 2261 1742 993 392 -307 -1196 -1607 -1351 -1183 -460 118 853 898 690 1012 1068 1382 1394 1169 766 0 -1050 -2027 -2058 -1592 -879 509 520 414 194 231 -216 -107 265 780 1089 1380 1783 1440 1106 331 -416 -1415 -2336 -2546 -2489 -1638 -502 420 881 824 1046 1316 1687 1831 1788 1412 1063 401 -348 -610 -1167 -1222 -1314 -1113 -749 -433 -509 -1161 -1652 -1761 -1645 -1967 -1830 -1470 -1245 -888 -778 -753 -745 -646 -392 46 610 1138 1689 1421 1004 634 -49 -955 -1670 -2577 -2411 -1704 -786 -128 -281 -841 -1170 -1142 -867 -147 560 1088 1653 2335 2570 2761 2767 2251 1517 539 276 307 456 931 895 809 751 395 305 334 -299 -1036 -1212 -1311 -1094 -581 -96 116 541 903 871 784 913 965 730 72 -851 -1788 -1894 -1527 -2755 -2167 -885 127 1004 1959 2204 2181 1683 957 375 -292 -1137 -1525 -1280 -1131 -429 112 820 872 675 993 1053 1368 1388 1127 737 0 -1027 -1968 -1989 -1552 -844 496 515 413 194 229 -215 -106 264 783 1070 1371 1780 1446 1108 330 -411 -1382 -2333 -2518 -2468 -1586 -494 420 894 844 1041 1312 1685 1836 1798 1422 1066 400 -345 -600 -1182 -1231 -1324 -1091 -739 -430 -506 -1152 -1627 -1719 -1594 -1911 -1783 -1438 -1228 -882 -778 -757 -750 -649 -394 46 616 1154 1708 1428 993 614 -47 -926 -1606 -2491 -2279 -1644 -780 -126 -284 -861 -1200 -1172 -892 -148 566 1110 1694 2400 2660 2880 2912 2320 1567 556 291 320 475 970 912 829 772 408 316 344 -307 -1063 -1239 -1346 -1134 -610 -102 122 575 968 943 856 972 1028 775 76 -899 -1884 -2047 -1611 SQ 20210724T041404.5Z 7875.176441 182 1 48.95 2 87.78 59.92 95.27 236.29 0.00 1 0.00 1 0 22 9.970e-03 9.873e-03 4.311e-04 4.300e-04 1.236725e+04 3.132300e+01 7.951681e+02 -6.000000e+00 5.904052e+02 283.42 -2.00 20.00 -2.00 505.42 0.00e+00 3.722210e-03 1.231434e-05 2.137720e-04 -6.000000e+00 2.869122e-04 283.42 -2.00 20.00 -2.00 501.01 0.00e+00 1.024791e+00 8.606923e-03 9.929388e-02 -6.000000e+00 2.043694e-01 233.60 -2.00 3.84 -2.00 502.52 0.00e+00 15.383 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