File name: Pandora141s1_Calakmul_20250615_L2Fit_fwvt1c3d20231011p1-8.txt File generation date: 20250619T232036.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 141 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora141_OF_v2d20230802.txt Instrument calibration file used: Pandora141s1_CF_v3d20231011.txt Level 1 file used: Pandora141s1_Calakmul_20250615_L1_smca1c3d20231011p1-8.txt Full location name: Calakmul Atmospheric Observatory Short location name: Calakmul Country of location: Mexico Location latitude [deg]: 18.5956 Location longitude [deg]: -89.4137 Location altitude [m]: 275 Local noon date: 20250615 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 2 First and last pixel inside fitting window: 1659 1808 Nominal wavelengths inside fitting window [nm]: 492.0753 492.1962 492.3171 492.4380 492.5588 492.6797 492.8005 492.9213 493.0421 493.1629 493.2837 493.4044 493.5251 493.6458 493.7665 493.8872 494.0079 494.1285 494.2492 494.3698 494.4904 494.6110 494.7315 494.8521 494.9726 495.0931 495.2136 495.3341 495.4546 495.5750 495.6954 495.8158 495.9362 496.0566 496.1770 496.2973 496.4177 496.5380 496.6583 496.7785 496.8988 497.0191 497.1393 497.2595 497.3797 497.4999 497.6200 497.7402 497.8603 497.9804 498.1005 498.2206 498.3407 498.4607 498.5807 498.7007 498.8207 498.9407 499.0607 499.1806 499.3006 499.4205 499.5404 499.6602 499.7801 499.8999 500.0198 500.1396 500.2594 500.3791 500.4989 500.6187 500.7384 500.8581 500.9778 501.0975 501.2171 501.3368 501.4564 501.5760 501.6956 501.8151 501.9347 502.0542 502.1738 502.2933 502.4128 502.5322 502.6517 502.7711 502.8906 503.0100 503.1293 503.2487 503.3681 503.4874 503.6067 503.7260 503.8453 503.9646 504.0838 504.2031 504.3223 504.4415 504.5607 504.6799 504.7990 504.9181 505.0373 505.1564 505.2754 505.3945 505.5136 505.6326 505.7516 505.8706 505.9896 506.1085 506.2275 506.3464 506.4653 506.5842 506.7031 506.8220 506.9408 507.0596 507.1785 507.2972 507.4160 507.5348 507.6535 507.7723 507.8910 508.0097 508.1283 508.2470 508.3656 508.4842 508.6029 508.7214 508.8400 508.9586 509.0771 509.1956 509.3141 509.4326 509.5511 509.6695 509.7880 509.9064 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250615T123249.3Z 9297.522793 258 1 28.81 2 75.11 69.95 59.74 231.83 0.00 1 0.00 1 0 15 8.454e-03 8.125e-03 2.077e-03 2.072e-03 8.943273e+03 1.451358e+02 5.629754e+02 -6.000000e+00 4.884218e+02 293.85 -2.00 20.00 -2.00 505.26 0.00e+00 3.338708e-04 5.870743e-05 4.390508e-05 -6.000000e+00 2.439625e-04 293.85 -2.00 20.00 -2.00 500.34 0.00e+00 2.614210e-01 4.111088e-02 5.598561e-02 -6.000000e+00 1.676172e-01 228.64 -2.00 3.11 -2.00 501.95 0.00e+00 3.813 0.000 489.00 513.00 1 8.9194e+00 3.1587e-03 7.1423e-03 -6.0000e+00 1.2881e-02 1.2950e-02 8.1502e-04 1.3193e-03 -6.0000e+00 3.3696e-03 1.4912e-04 -6.4598e-04 1.9348e-04 5.1150e-05 -6.0000e+00 8.4303e-04 -5.0188e-02 -4.0910e-05 12 9 8 11 8 0 99.94 19.88 0.77 -0.05019 -0.05467 9 9 1 4 0 3200.170 26.11 20.00 19.88 31.73 38.3 985.00 -577 121 -264 -121 74 210 340 629 -145 882 94 -181 148 -12 -53 118 -385 -159 -313 300 -128 26 215 117 264 764 376 149 -148 -203 -251 -749 -358 -393 218 173 371 541 142 -598 123 -202 -545 -132 -396 802 78 -312 331 -416 -624 -548 -58 -529 6059 -2872 56 383 380 -53 102 365 124 1947 -2412 -469 -73 -256 -602 382 -234 -320 -248 -86 101 -201 256 -469 -586 -440 149 -135 -377 -523 136 -217 -497 -279 -318 -52 436 -499 51 173 -291 355 -51 -271 -124 -327 -332 -353 261 -622 -204 -788 166 -32 447 218 -6 -109 458 -60 228 1117 -107 557 364 498 434 402 409 -206 299 -35 -419 401 160 -381 519 489 -324 787 4191 -3297 -672 -410 555 -248 166 -227 100 487 15 -106 -641 47 -149 -453 -553 116 -259 -121 75 217 356 662 -154 923 98 -187 151 -12 -53 119 -391 -163 -327 316 -136 27 228 124 280 810 399 157 -154 -207 -251 -750 -361 -405 229 183 392 567 148 -623 127 -210 -570 -139 -419 845 83 -328 341 -425 -625 -538 -56 -512 5682 -2917 56 392 390 -55 104 374 128 1975 -2510 -479 -74 -255 -597 373 -228 -312 -244 -85 101 -201 252 -457 -566 -422 143 -130 -365 -509 133 -213 -490 -275 -313 -51 426 -494 50 172 -289 345 -49 -254 -115 -298 -301 -322 242 -597 -201 -788 165 -32 437 213 -6 -108 457 -60 229 1118 -108 565 370 503 434 397 399 -201 292 -34 -411 390 155 -370 499 465 -306 729 3777 -3146 -638 -395 538 -244 164 -226 100 488 15 -107 -642 46 -144 -437 SQ 20250615T124424.6Z 9297.530840 265 1 2.95 2 72.52 70.60 61.85 233.69 0.00 1 0.00 1 0 15 3.953e-03 3.952e-03 2.712e-03 2.708e-03 7.870880e+03 1.848502e+02 5.120729e+02 -6.000000e+00 2.283725e+02 293.85 -2.00 20.00 -2.00 505.25 0.00e+00 4.084655e-04 7.684409e-05 4.332954e-05 -6.000000e+00 1.140714e-04 293.85 -2.00 20.00 -2.00 500.42 0.00e+00 1.434774e-01 5.343920e-02 4.751097e-02 -6.000000e+00 7.837933e-02 228.64 -2.00 3.11 -2.00 502.01 0.00e+00 3.282 0.000 489.00 513.00 1 6.9171e+00 4.1059e-03 6.1543e-03 -6.0000e+00 6.0230e-03 7.6959e-03 1.0619e-03 1.1430e-03 -6.0000e+00 1.5758e-03 1.1997e-03 6.1903e-04 2.5525e-04 5.1275e-05 -6.0000e+00 3.9413e-04 -5.2703e-02 -3.6333e-05 12 9 1 12 1 1 999.00 19.88 0.77 -0.05270 -0.04841 1 20 1 4 0 1473.340 26.00 19.99 19.88 32.27 38.4 985.28 -363 -449 -61 -23 243 532 216 770 292 701 118 -69 125 442 389 -224 -55 -376 53 154 -364 -231 -189 85 52 1154 376 -832 26 -364 -551 -538 190 -153 95 123 552 293 45 17 -82 -209 -785 -149 251 169 641 545 207 -194 -709 -138 -1046 -639 208 -48 -44 145 -301 139 -117 497 243 513 48 437 -109 -189 -568 475 -456 108 37 96 -319 -444 -480 -582 -150 -690 -498 -348 11 -276 308 19 -117 -554 -468 -65 38 36 -272 424 -106 618 -99 -473 -473 312 -617 -404 -126 -372 -2 -285 263 72 398 -67 -127 -133 -336 209 687 653 562 131 334 -178 577 408 338 -460 -408 47 -105 403 165 7 711 421 -272 112 1106 -42 -22 130 -402 107 663 54 -555 362 -109 44 -429 174 -424 -355 -352 -440 -59 -23 244 546 227 789 302 736 123 -71 126 439 395 -222 -55 -385 54 159 -381 -242 -198 89 54 1200 393 -870 26 -371 -549 -533 190 -158 98 130 576 303 46 17 -82 -212 -810 -154 262 178 667 562 211 -200 -711 -134 -1037 -631 202 -48 -44 147 -308 141 -119 504 248 523 49 438 -108 -190 -566 464 -445 104 36 95 -320 -446 -475 -567 -148 -678 -489 -343 11 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-0.04823 -0.04467 15 25 1 4 0 1221.200 26.11 20.02 19.88 32.52 38.3 985.39 -455 -203 -143 281 309 232 430 432 211 287 -134 -68 79 -26 -259 -36 14 48 42 174 -12 21 254 88 239 365 133 3 -174 -319 -643 -414 -165 -111 80 228 383 166 -109 -97 159 109 15 -3 118 265 297 267 9 -92 -386 -532 -468 -590 283 -497 -164 -62 166 206 268 313 281 568 -156 -3 -89 -181 -382 50 -61 -142 101 -6 -162 -105 -292 -318 -317 -362 -422 -302 -300 -247 -139 -149 -367 -91 -402 -296 -2 -6 -125 20 16 270 83 -130 -61 -161 -372 -375 -207 -510 -228 -237 -275 70 303 175 177 -105 74 119 173 649 487 584 401 395 243 468 305 85 230 59 -89 222 118 -130 228 267 9 227 1064 -477 -361 -218 -171 -84 158 164 12 -56 109 -96 -145 -161 -323 -215 -438 -196 -141 280 313 238 445 450 220 298 -139 -70 81 -26 -259 -36 14 49 43 181 -12 21 265 92 250 382 139 3 -179 -322 -644 -413 -166 -113 83 239 399 172 -113 -100 162 112 16 -3 123 276 309 276 10 -93 -385 -523 -455 -575 277 -497 -166 -63 169 209 273 319 287 578 -159 -3 -89 -180 -379 49 -60 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