File name: Pandora26s1_CambridgeMA_20240526_L2Fit_fout2c10d20240425p1-8.txt File generation date: 20241217T225255.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v10d20240425.txt Level 1 file used: Pandora26s1_CambridgeMA_20240526_L1_smca1c10d20240425p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240526 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0963 305.2371 305.3779 305.5186 305.6594 305.8002 305.9409 306.0816 306.2224 306.3631 306.5038 306.6445 306.7851 306.9258 307.0664 307.2071 307.3477 307.4883 307.6289 307.7695 307.9101 308.0507 308.1912 308.3318 308.4723 308.6129 308.7534 308.8939 309.0344 309.1748 309.3153 309.4558 309.5962 309.7366 309.8771 310.0175 310.1579 310.2982 310.4386 310.5790 310.7193 310.8597 311.0000 311.1403 311.2806 311.4209 311.5612 311.7015 311.8417 311.9820 312.1222 312.2624 312.4026 312.5428 312.6830 312.8232 312.9634 313.1035 313.2437 313.3838 313.5239 313.6640 313.8041 313.9442 314.0843 314.2243 314.3644 314.5044 314.6444 314.7844 314.9244 315.0644 315.2044 315.3444 315.4843 315.6243 315.7642 315.9041 316.0440 316.1839 316.3238 316.4637 316.6035 316.7434 316.8832 317.0230 317.1628 317.3026 317.4424 317.5822 317.7220 317.8617 318.0015 318.1412 318.2809 318.4206 318.5603 318.7000 318.8397 318.9793 319.1190 319.2586 319.3982 319.5378 319.6774 319.8170 319.9566 320.0962 320.2357 320.3753 320.5148 320.6543 320.7938 320.9333 321.0728 321.2123 321.3517 321.4912 321.6306 321.7700 321.9094 322.0488 322.1882 322.3276 322.4669 322.6063 322.7456 322.8849 323.0243 323.1636 323.3028 323.4421 323.5814 323.7206 323.8599 323.9991 324.1383 324.2775 324.4167 324.5559 324.6951 324.8342 324.9734 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240526T115030.8Z 8912.493412 241 1 1.91 2 63.36 84.75 95.28 235.29 0.00 1 0.00 1 0 17 3.042e-02 7.325e-03 1.626e-02 4.142e-03 3.677705e-01 2.190711e-03 4.258864e-03 -6.000000e+00 1.848566e-02 231.76 -2.00 3.54 -2.00 317.63 0.00e+00 5.218853e-04 3.509229e-04 1.593884e-04 -6.000000e+00 8.160746e-04 283.62 -2.00 20.00 -2.00 316.86 0.00e+00 2.218 0.000 302.00 328.00 3 3.2352e+00 5.8618e-03 2.9426e-02 -6.0000e+00 4.6300e-02 -1.8145e-02 6.5961e-03 1.9054e-02 -6.0000e+00 5.0084e-02 -2.1044e-02 4.0088e-03 9.2437e-03 -6.0000e+00 2.9766e-02 3.7411e-03 1.9608e-03 2.6299e-03 -6.0000e+00 1.2315e-02 1.4519e-03 1.7906e-03 1.2927e-04 3.1345e-05 -6.0000e+00 9.5120e-04 -7.1811e-04 2.5115e-04 12 9 1 12 1 1 41.96 25.98 0.28 -0.00072 0.01274 4 15 1 5 0 381.040 34.75 20.00 25.98 24.62 3.2 992.12 -12431 842 19338 -4936 -5961 -5896 -5758 -10010 -9807 -5479 -11147 -4847 -3724 2296 -2516 90 134 3331 1957 7654 1020 -683 -680 -228 2121 -2838 79 -1223 -2565 -4000 620 1078 -1606 135 -1880 -2662 -3749 714 1237 -663 -325 925 818 -1699 97 257 648 -1208 297 -886 1007 1338 568 1228 1262 1016 1267 707 10 1501 363 769 1897 313 153 187 -126 -104 1061 1187 1239 233 419 -13 -1296 -313 -266 -217 -890 -1105 -1974 -1041 -1653 -1633 -467 -674 -147 -368 243 488 -41 -644 -238 1116 452 317 -458 651 -606 -608 -287 -754 229 1191 -987 -608 -798 -586 861 772 -23 -202 372 131 28 404 553 -199 -403 -4 23 -94 963 211 853 642 -103 902 616 330 -157 -666 -41 260 17 328 109 -345 -154 -47 149 -553 -772 -1069 69 1336 -413 -472 -464 -488 -991 -1062 -597 -1216 -541 -474 323 -428 17 26 673 385 1610 214 -148 -153 -54 522 -756 20 -304 -629 -1025 165 316 -480 40 -559 -816 -1293 278 529 -309 -165 489 446 -901 51 134 358 -634 155 -485 579 827 356 807 861 675 851 474 7 1051 254 579 1453 257 125 145 -95 -80 868 1026 1101 216 383 -11 -1112 -254 -201 -163 -725 -970 -1874 -1031 -1688 -1771 -513 -757 -172 -442 287 550 -45 -685 -249 1162 489 367 -552 819 -806 -792 -363 -925 268 1428 -1240 -775 -1073 -800 1194 1149 -35 -312 554 191 40 544 749 -285 -592 -6 34 -142 1399 306 1174 878 -139 1235 878 489 -240 -1060 -65 417 28 563 193 -604 -268 -81 255 -921 -1277 SS 20240526T120023.9Z 8912.500276 247 1 54.33 2 61.54 86.35 96.72 236.81 0.00 1 0.00 1 0 17 1.400e-02 5.448e-03 1.147e-03 3.707e-04 3.447092e-01 1.965672e-04 4.072283e-03 -6.000000e+00 8.495047e-03 231.76 -2.00 3.54 -2.00 317.20 0.00e+00 3.980092e-04 2.783535e-05 1.062282e-04 -6.000000e+00 3.757570e-04 283.62 -2.00 20.00 -2.00 316.43 0.00e+00 2.088 0.000 302.00 328.00 3 2.1845e+00 5.2109e-04 2.7720e-02 -6.0000e+00 2.1275e-02 -3.1991e-02 5.8361e-04 1.7966e-02 -6.0000e+00 2.3028e-02 -1.1471e-02 3.4569e-04 8.7149e-03 -6.0000e+00 1.3685e-02 1.8079e-03 1.6505e-04 2.3894e-03 -6.0000e+00 5.6511e-03 4.8810e-03 -6.3839e-06 1.1615e-05 3.0601e-05 -6.0000e+00 4.3803e-04 3.5810e-03 -7.1861e-05 10 0 0 10 0 0 97.90 25.98 0.28 0.00358 0.00353 507 53 1 5 0 107.150 35.00 20.00 25.98 25.76 3.1 996.80 -4389 -3332 -3300 -4147 -6313 -5990 -4926 -3500 -1941 -2828 -2954 -2083 -1285 -568 91 397 281 1355 1889 2364 1078 353 1780 1168 365 298 -693 -693 129 106 682 740 28 -1609 -2701 -1208 -1609 -705 -344 -895 -1010 -488 29 -338 -71 -8 -335 -108 -80 402 863 1000 965 1001 570 853 774 509 511 822 1092 1417 1324 1023 187 -324 293 -3 995 682 -175 7 -93 87 -122 -222 -94 -542 -278 -636 -1188 -1356 -1820 -1392 -808 -475 -174 58 223 169 255 389 234 516 422 220 148 210 -273 -649 -653 -712 -216 121 -624 -1024 -443 -455 45 382 302 143 168 148 184 451 604 336 192 -87 -193 -45 289 206 426 608 300 1029 648 228 158 -178 -36 31 130 -25 -146 76 -152 -279 -185 -466 -507 -457 -371 -370 -444 -647 -610 -536 -419 -250 -385 -417 -317 -223 -104 19 91 69 320 465 599 282 94 487 341 113 89 -220 -211 38 32 221 244 10 -590 -976 -441 -613 -294 -169 -478 -556 -281 17 -202 -42 -5 -199 -64 -47 245 529 659 644 704 398 609 560 367 364 588 814 1086 1053 857 156 -258 233 -3 827 606 -163 7 -88 78 -106 -183 -75 -431 -227 -563 -1140 -1380 -1919 -1496 -891 -556 -205 70 265 193 278 421 240 529 449 252 177 267 -352 -847 -826 -865 -252 146 -784 -1321 -579 -627 64 561 453 218 246 210 250 604 813 461 272 -130 -283 -67 413 291 590 827 399 1394 916 327 233 -273 -55 50 215 -42 -247 131 -261 -478 -305 -762 -822 SS 20240526T120531.8Z 8912.503840 250 1 54.30 2 60.60 87.18 97.48 237.59 0.00 1 0.00 1 0 17 1.314e-02 5.369e-03 1.685e-03 5.124e-04 3.350071e-01 2.711843e-04 3.971329e-03 -6.000000e+00 7.972716e-03 231.76 -2.00 3.54 -2.00 317.33 0.00e+00 3.415860e-04 3.989519e-05 1.064453e-04 -6.000000e+00 3.526174e-04 283.62 -2.00 20.00 -2.00 316.56 0.00e+00 2.028 0.000 302.00 328.00 3 2.8461e+00 7.2101e-04 2.6970e-02 -6.0000e+00 1.9967e-02 -2.8123e-02 8.0908e-04 1.7538e-02 -6.0000e+00 2.1612e-02 -9.1436e-03 4.8197e-04 8.4957e-03 -6.0000e+00 1.2844e-02 3.7267e-04 2.3154e-04 2.3164e-03 -6.0000e+00 5.3039e-03 2.7016e-03 5.3228e-05 1.6104e-05 2.9599e-05 -6.0000e+00 4.1106e-04 3.3544e-03 -6.0081e-05 10 0 0 10 0 0 99.99 25.99 0.32 0.00335 0.00375 464 49 1 5 0 117.010 35.00 20.00 25.99 26.38 3.0 1000.52 -4401 -1595 -2445 -3649 -6407 -5128 -4229 -4504 -412 -2147 -1917 -2550 -885 -138 11 658 613 2048 1577 2410 913 -260 1859 961 153 36 -1153 -428 440 219 1061 372 -570 -1465 -2896 -743 -1781 -440 -285 -1065 -1289 -676 75 -433 -332 45 -593 -136 -411 341 651 919 962 944 444 1009 566 569 574 721 959 1359 1257 959 365 -293 258 -13 1061 696 -174 166 -8 203 -30 -167 -60 -560 -429 -574 -1084 -1340 -1862 -1354 -795 -511 -153 96 294 131 292 503 298 515 509 219 310 263 -287 -699 -658 -721 -347 111 -519 -993 -478 -485 42 397 253 111 202 169 76 343 623 258 129 -41 -300 -127 262 242 482 571 226 1019 664 177 136 -215 22 86 162 -29 -126 79 -103 -230 -158 -501 -459 -450 -156 -242 -381 -642 -506 -446 -531 -51 -257 -237 -343 -134 -24 2 143 130 452 366 573 225 -66 477 264 45 11 -344 -121 120 61 317 123 -187 -491 -960 -247 -665 -177 -136 -547 -723 -371 42 -247 -189 26 -335 -75 -230 196 398 601 631 652 320 699 399 399 421 532 695 1060 1006 807 306 -233 207 -10 879 611 -158 155 -7 188 -26 -137 -48 -447 -348 -499 -1013 -1317 -1969 -1446 -903 -590 -184 113 357 153 328 545 305 527 559 256 372 333 -379 -909 -835 -887 -410 135 -654 -1277 -643 -662 59 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