File name: Pandora260s1_CameronLA_20231127_L2Fit_fout2c1d20230417p1-8.txt File generation date: 20240118T235903.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v1d20230417.txt Level 1 file used: Pandora260s1_CameronLA_20231127_L1_smca1c1d20230417p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20231127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session and full initial 1.8 lab calibration, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0364 305.1770 305.3177 305.4583 305.5989 305.7394 305.8800 306.0206 306.1611 306.3016 306.4422 306.5827 306.7232 306.8637 307.0041 307.1446 307.2851 307.4255 307.5659 307.7064 307.8468 307.9872 308.1276 308.2679 308.4083 308.5487 308.6890 308.8293 308.9696 309.1100 309.2503 309.3905 309.5308 309.6711 309.8113 309.9516 310.0918 310.2320 310.3722 310.5124 310.6526 310.7928 310.9329 311.0731 311.2132 311.3533 311.4934 311.6335 311.7736 311.9137 312.0538 312.1938 312.3339 312.4739 312.6139 312.7539 312.8939 313.0339 313.1739 313.3139 313.4538 313.5937 313.7337 313.8736 314.0135 314.1534 314.2933 314.4331 314.5730 314.7128 314.8527 314.9925 315.1323 315.2721 315.4119 315.5517 315.6915 315.8312 315.9709 316.1107 316.2504 316.3901 316.5298 316.6695 316.8092 316.9488 317.0885 317.2281 317.3677 317.5074 317.6470 317.7865 317.9261 318.0657 318.2053 318.3448 318.4843 318.6239 318.7634 318.9029 319.0423 319.1818 319.3213 319.4607 319.6002 319.7396 319.8790 320.0184 320.1578 320.2972 320.4366 320.5759 320.7153 320.8546 320.9939 321.1332 321.2725 321.4118 321.5511 321.6904 321.8296 321.9688 322.1081 322.2473 322.3865 322.5257 322.6649 322.8040 322.9432 323.0823 323.2215 323.3606 323.4997 323.6388 323.7779 323.9170 324.0560 324.1951 324.3341 324.4731 324.6122 324.7512 324.8901 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231127T132843.9Z 8731.561619 301 1 11.21 2 82.73 119.46 94.72 301.68 0.00 1 0.00 1 0 17 5.828e-01 3.834e-02 3.176e-01 1.640e-02 7.238666e-01 9.452447e-03 1.067654e-02 -6.000000e+00 3.425502e-01 224.75 -2.00 3.24 -2.00 321.60 0.00e+00 8.330814e-03 4.902912e-03 1.435204e-02 -6.000000e+00 1.808466e-02 287.73 -2.00 20.00 -2.00 321.07 0.00e+00 7.291 0.005 302.00 328.00 3 1.6472e+00 3.4293e-02 1.0891e-01 -6.0000e+00 8.4267e-01 7.3816e-01 4.3694e-02 9.7638e-02 -6.0000e+00 9.1610e-01 -1.1279e+00 3.3875e-02 2.9297e-02 -6.0000e+00 5.4624e-01 4.7411e-01 1.6526e-02 7.6471e-03 -6.0000e+00 2.4236e-01 3.5580e-05 -8.3523e-04 4.5792e-04 2.1245e-04 -6.0000e+00 1.6134e-02 -6.2294e-02 0.0000e+00 12 9 9 12 33 1 55.23 24.73 0.80 -0.06229 -0.06857 6 4 1 5 0 1600.730 33.50 20.00 24.73 8.83 1.6 807.12 900000 -86728 -126372 900000 -78628 900000 900000 -110603 49801 -98443 -96961 900000 61302 -35115 -2230 -52289 249017 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900000 1648 3387 1372 314 4943 6020 4255 2185 6331 957 2849 1922 657 324 4703 8160 6999 7644 2838 4726 1254 3486 2382 2724 2467 2634 -102 -1509 -13129 -543 -340 -91 4852 6420 -761 1063 -1431 -2960 1142 -2304 1002 10356 -4439 -7211 400 -5392 502 -1582 4431 -3726 -2096 -8496 2442 -4821 -8301 -669 -2166 -2066 -1979 -4100 -1038 -2843 1149 238 -332 5275 -2087 -1231 -3802 6001 288 3718 3098 2474 6731 3292 5410 3036 -2193 1573 -1073 1925 -36 2420 208 -1247 -4614 -2223 5277 1654 -462 726 -3307 -5585 SS 20231127T133818.2Z 8731.568266 304 1 54.40 2 80.94 120.80 96.40 302.93 0.00 1 0.00 1 0 25 3.980e-01 9.127e-03 1.717e-01 1.551e-03 6.648298e-01 8.398403e-04 7.437018e-03 -6.000000e+00 2.285244e-01 224.75 -2.00 3.24 -2.00 320.74 0.00e+00 4.544302e-04 3.719673e-04 3.591393e-03 -6.000000e+00 1.126073e-02 287.73 -2.00 20.00 -2.00 320.13 0.00e+00 6.018 0.003 302.00 328.00 3 6.3295e-01 2.6987e-03 6.9796e-02 -6.0000e+00 5.6489e-01 -7.4218e-02 3.7289e-03 3.9326e-02 -6.0000e+00 6.1389e-01 3.0050e-02 3.9154e-03 1.8161e-02 -6.0000e+00 3.6341e-01 -1.9646e-02 1.9228e-03 5.2663e-03 -6.0000e+00 1.6018e-01 3.9582e-04 -1.8232e-04 4.0785e-05 6.6398e-05 -6.0000e+00 1.0454e-02 -5.8528e-02 0.0000e+00 11 9 0 11 32 0 47.13 24.73 0.67 -0.05853 -0.05990 232 24 1 5 0 234.450 33.50 19.99 24.73 9.45 1.6 813.43 900000 -150469 -194809 900000 -126538 900000 900000 -83076 900000 58427 -112039 900000 -102136 109823 -60332 -33145 900000 214963 -18143 900000 31962 -25816 -49728 36838 -29262 3699 14470 125477 3773 68814 -10147 8236 -14620 -10665 -29108 -19681 2719 -11436 -1914 -4072 3235 4027 -3799 -1513 -6035 10006 -683 -663 6990 7011 -2518 743 -2190 957 5217 1328 -530 3246 540 414 -1431 -1174 178 3681 4928 2778 2981 -1675 -747 597 986 637 1452 1295 423 -718 -2722 -5644 -3728 -2589 -2056 -424 -895 -1880 -678 -610 -48 1049 1156 1344 3080 457 -638 -355 -817 -87 -203 967 1012 140 -757 -824 -1671 -1878 -402 -1289 -1110 -938 -465 626 1049 1449 949 438 308 -783 -426 -407 336 428 472 399 790 1010 43 293 -1032 -1191 233 -200 -286 -565 -637 -805 -401 -260 -43 651 888 521 270 -220 -706 900000 -723 -1685 900000 -611 900000 900000 -301 900000 88 -812 900000 -879 166 -583 -310 900000 325 -222 900000 275 -405 -1014 350 -610 61 229 663 65 623 -233 194 -519 -427 -1455 -847 98 -549 -103 -282 250 345 -379 -156 -663 958 -75 -75 774 825 -357 117 -399 170 975 275 -118 718 121 90 -317 -274 46 1068 1596 946 982 -584 -272 245 431 305 712 621 192 -298 -1131 -2312 -1566 -1147 -1088 -258 -579 -1334 -504 -489 -38 860 970 1119 2587 366 -488 -264 -647 -73 -199 1013 1142 171 -912 -983 -1795 -1864 -410 -1446 -1304 -1095 -582 809 1526 2200 1518 700 474 -1147 -636 -621 506 687 785 649 1229 1524 67 438 -1512 -1689 349 -327 -500 -1029 -1235 -1565 -829 -552 -97 1464 2033 1192 589 -476 -1447 SS 20231127T134916.3Z 8731.575883 309 1 54.25 2 78.91 122.39 98.28 304.40 0.00 1 0.00 1 0 25 1.753e-01 8.850e-03 2.730e-02 8.978e-04 5.730435e-01 4.620347e-04 6.332555e-03 -6.000000e+00 9.835793e-02 224.75 -2.00 3.24 -2.00 319.88 0.00e+00 1.044935e-03 1.529078e-04 1.750408e-03 -6.000000e+00 4.453494e-03 287.73 -2.00 20.00 -2.00 319.19 0.00e+00 5.015 0.001 302.00 328.00 3 6.2537e-01 1.3467e-03 5.7255e-02 -6.0000e+00 2.4254e-01 -3.9587e-02 1.6643e-03 2.9088e-02 -6.0000e+00 2.6255e-01 1.8304e-04 1.5073e-03 1.4419e-02 -6.0000e+00 1.5711e-01 -6.4951e-03 7.8847e-04 4.1005e-03 -6.0000e+00 6.9717e-02 1.0982e-03 -2.8270e-04 2.3393e-05 4.7523e-05 -6.0000e+00 4.4739e-03 -5.7976e-02 0.0000e+00 11 8 0 10 0 0 98.99 24.71 0.53 -0.05798 -0.06010 377 40 1 5 0 143.890 33.50 20.00 24.71 10.53 1.6 821.83 900000 -80222 -90020 -26663 -55018 -35625 -34705 -78478 -36308 -39662 -65911 -16697 -53939 -25637 -30819 -20474 15682 -2004 -15074 355 -5280 -9371 -16674 -4566 -13315 -12668 -5380 -358 -9761 -1157 -13886 -2961 -5692 -4422 -8410 -11932 -6812 -9346 -4237 -311 -118 1410 -1449 816 -805 3059 -532 -1090 1260 774 -4 1398 623 1905 2348 1847 1454 1906 633 673 -271 1522 1174 3509 3710 1776 1101 -1432 -882 675 1284 1345 1306 1172 761 -408 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