File name: Pandora260s1_CameronLA_20240715_L2Fit_fout2c4d20240619p1-8.txt File generation date: 20241203T182939.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v4d20240619.txt Level 1 file used: Pandora260s1_CameronLA_20240715_L1_smca1c4d20240619p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20240715 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0227 305.1633 305.3039 305.4444 305.5849 305.7254 305.8660 306.0064 306.1469 306.2874 306.4279 306.5683 306.7088 306.8492 306.9896 307.1300 307.2704 307.4108 307.5511 307.6915 307.8319 307.9722 308.1125 308.2528 308.3931 308.5334 308.6737 308.8140 308.9542 309.0945 309.2347 309.3750 309.5152 309.6554 309.7956 309.9357 310.0759 310.2161 310.3562 310.4963 310.6365 310.7766 310.9167 311.0568 311.1968 311.3369 311.4770 311.6170 311.7570 311.8971 312.0371 312.1771 312.3171 312.4570 312.5970 312.7369 312.8769 313.0168 313.1567 313.2966 313.4365 313.5764 313.7163 313.8562 313.9960 314.1358 314.2757 314.4155 314.5553 314.6951 314.8349 314.9746 315.1144 315.2541 315.3939 315.5336 315.6733 315.8130 315.9527 316.0924 316.2321 316.3717 316.5114 316.6510 316.7906 316.9302 317.0698 317.2094 317.3490 317.4886 317.6281 317.7676 317.9072 318.0467 318.1862 318.3257 318.4652 318.6047 318.7441 318.8836 319.0230 319.1624 319.3018 319.4412 319.5806 319.7200 319.8594 319.9987 320.1381 320.2774 320.4167 320.5560 320.6953 320.8346 320.9739 321.1132 321.2524 321.3917 321.5309 321.6701 321.8093 321.9485 322.0877 322.2269 322.3660 322.5052 322.6443 322.7834 322.9226 323.0617 323.2007 323.3398 323.4789 323.6179 323.7570 323.8960 324.0350 324.1741 324.3131 324.4520 324.5910 324.7300 324.8689 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240715T124922.5Z 8962.534288 86 1 54.34 2 73.17 74.59 167.28 339.61 0.00 1 0.00 1 0 17 3.612e-02 8.976e-03 3.162e-03 5.015e-04 4.186898e-01 2.544652e-04 4.585863e-03 -6.000000e+00 2.055436e-02 230.08 -2.00 3.24 -2.00 318.22 0.00e+00 9.473572e-04 4.891179e-05 6.946346e-04 -6.000000e+00 9.386681e-04 294.31 -2.00 20.00 -2.00 317.30 0.00e+00 3.399 0.000 302.00 328.00 3 1.1557e+00 6.8841e-04 3.9495e-02 -6.0000e+00 5.1193e-02 -3.9833e-03 7.8410e-04 2.0304e-02 -6.0000e+00 5.5222e-02 -7.0568e-03 5.1614e-04 9.8288e-03 -6.0000e+00 3.3056e-02 -2.4690e-03 2.7347e-04 2.7152e-03 -6.0000e+00 1.4423e-02 3.4359e-03 1.2355e-04 1.3299e-05 2.6211e-05 -6.0000e+00 9.1245e-04 1.4036e-03 0.0000e+00 11 8 0 10 0 0 99.79 24.99 0.42 0.00140 0.00233 442 46 1 5 0 122.930 33.50 19.93 24.99 35.99 0.2 1004.57 -10799 -8746 -10081 -7456 -15195 -11150 -11537 -11487 -8277 -7700 -14186 -11501 -10055 -4402 -3526 -1672 930 1239 -257 2460 1671 -733 182 1441 -764 589 366 -597 -2379 -1116 -382 425 1251 -327 -4322 -5258 -4544 -2678 -592 797 193 253 423 273 549 1239 288 82 -316 -525 481 765 766 1613 1114 1028 1403 791 123 153 227 1442 1820 3052 2040 185 -82 -1778 -198 1036 943 1260 828 973 393 -650 -1504 -3081 -2767 -1973 -1814 -1303 -1940 -2214 -1242 -558 348 692 1337 1307 1027 637 -642 -1029 -838 -658 -305 913 897 150 -306 -1223 -1773 -1101 -414 -1357 -832 -770 -343 601 938 1062 713 389 -5 -420 38 -154 460 630 533 492 923 841 459 469 -835 -169 273 -65 -84 -507 -407 -611 -12 151 -143 697 477 118 -32 -511 -955 -460 -424 -533 -378 -742 -492 -543 -613 -490 -498 -995 -809 -815 -409 -355 -194 115 163 -37 360 257 -115 29 243 -142 115 68 -117 -445 -204 -77 88 290 -85 -1118 -1292 -1190 -737 -194 291 81 105 184 123 247 560 132 38 -146 -248 240 394 426 900 662 631 837 481 74 95 142 905 1262 2197 1496 139 -58 -1250 -142 801 786 1065 715 852 324 -514 -1136 -2231 -2052 -1575 -1594 -1231 -1949 -2251 -1274 -615 388 803 1566 1506 1158 663 -651 -1042 -849 -717 -361 1120 1182 204 -399 -1535 -2106 -1310 -510 -1754 -1078 -1053 -479 869 1430 1660 1120 587 -7 -589 53 -223 679 966 822 750 1405 1245 669 677 -1164 -235 390 -97 -132 -819 -677 -1022 -21 270 -265 1273 892 219 -58 -918 -1651 SS 20240715T125957.3Z 8962.541636 93 1 54.82 2 70.95 75.71 167.88 350.47 0.00 1 0.00 1 0 17 5.383e-02 1.017e-02 1.165e-02 1.667e-03 3.747966e-01 8.432670e-04 4.102749e-03 -6.000000e+00 3.063077e-02 230.08 -2.00 3.24 -2.00 318.27 0.00e+00 3.764473e-04 1.650493e-04 5.630115e-04 -6.000000e+00 1.398768e-03 294.31 -2.00 20.00 -2.00 317.35 0.00e+00 3.026 0.000 302.00 328.00 3 3.8061e+00 2.2891e-03 3.5254e-02 -6.0000e+00 7.6289e-02 7.8717e-03 2.6159e-03 1.8282e-02 -6.0000e+00 8.2291e-02 1.9805e-02 1.7412e-03 8.7897e-03 -6.0000e+00 4.9260e-02 -1.5812e-02 9.2432e-04 2.4139e-03 -6.0000e+00 2.1496e-02 3.6154e-04 7.8095e-05 4.4966e-05 2.3258e-05 -6.0000e+00 1.3596e-03 7.6015e-04 0.0000e+00 12 8 8 10 0 0 99.82 24.96 0.68 0.00076 0.00135 32 3 1 5 0 1712.920 33.50 20.07 24.96 36.62 0.2 1008.32 17347 -14756 -21636 -474 -26503 7753 23441 -14714 3899 -10280 -15992 -2237 -11219 3395 -1585 -7197 13063 5960 -4799 4933 6213 -3188 -4509 1632 -6457 -1168 716 9540 234 9857 -744 736 -1322 -3214 -8537 -8273 -1299 -1859 1648 712 -948 525 -1014 -145 -378 2397 -969 208 1945 876 355 134 -427 1188 1116 785 -696 2210 -238 285 894 442 1195 2628 1773 654 1199 -2720 -356 1288 511 1070 807 792 49 -1089 -1500 -4369 -3146 -2186 -1282 -720 -1588 -2480 -925 -287 -330 903 1491 1156 2225 366 -879 -844 -568 -595 133 1637 717 10 -689 -684 -1171 -1339 -179 -1481 -838 -581 -642 485 1009 1055 560 502 199 -730 152 -250 410 375 449 242 581 658 659 558 -1070 -461 382 -96 -354 -691 -483 -653 -335 335 -170 811 700 132 222 -650 -670 564 -763 -1281 -22 -1435 280 766 -799 202 -672 -1121 -139 -879 275 -160 -892 1432 743 -646 696 900 -459 -668 245 -1132 -206 128 1648 37 1548 -128 140 -287 -777 -2087 -1893 -297 -495 515 249 -384 223 -456 -66 -174 1081 -452 95 871 400 173 66 -228 669 664 482 -415 1396 -151 176 556 273 809 1934 1295 494 834 -1911 -252 955 432 958 691 702 41 -836 -1112 -3121 -2259 -1761 -1099 -649 -1589 -2474 -963 -321 -370 1045 1745 1335 2522 388 -921 -836 -582 -639 151 2060 956 13 -908 -877 -1372 -1530 -219 -1874 -1099 -801 -888 713 1524 1677 893 763 295 -1012 213 -361 594 584 694 371 908 998 950 811 -1503 -622 542 -142 -542 -1120 -802 -1068 -577 587 -311 1497 1322 247 400 -1181 -1168 SS 20240715T130824.9Z 8962.547511 99 1 54.25 2 69.17 76.60 168.06 359.68 0.00 1 0.00 1 0 17 2.539e-02 9.016e-03 5.261e-03 1.119e-03 3.509092e-01 5.650297e-04 3.858384e-03 -6.000000e+00 1.444772e-02 230.08 -2.00 3.24 -2.00 317.80 0.00e+00 4.764657e-04 9.629619e-05 4.592122e-04 -6.000000e+00 6.597442e-04 294.31 -2.00 20.00 -2.00 316.87 0.00e+00 2.783 0.000 302.00 328.00 3 3.3377e+00 1.5138e-03 3.2552e-02 -6.0000e+00 3.5984e-02 8.9653e-03 1.7149e-03 1.6971e-02 -6.0000e+00 3.8814e-02 1.0258e-02 1.0816e-03 8.1955e-03 -6.0000e+00 2.3234e-02 -1.2280e-02 5.6293e-04 2.2567e-03 -6.0000e+00 1.0139e-02 7.5530e-04 1.7279e-04 2.9949e-05 2.1627e-05 -6.0000e+00 6.4126e-04 4.3462e-04 0.0000e+00 12 9 1 12 32 32 99.97 24.99 0.63 0.00043 0.00173 93 10 1 5 0 583.280 33.75 19.98 24.99 36.71 0.2 1008.55 2762 -9158 -9810 -1858 -11188 2385 3249 -4998 651 -2998 -11180 -3383 -7969 811 -421 -2842 5103 4310 -1216 3717 2611 -1453 -1439 3426 -2995 -209 733 2939 -221 3670 -660 1057 -689 -1062 -6024 -6050 -2741 -2209 -15 278 -475 180 -733 -702 -249 1384 -14 -151 570 -55 494 278 -289 984 1475 899 611 1267 256 169 -33 820 1654 2690 1583 342 557 -2180 -32 1120 642 1127 862 1088 298 -626 -1113 -3050 -2698 -2248 -1612 -983 -1923 -2149 -1260 -525 140 704 1042 971 1493 581 -945 -668 -603 -396 112 1177 1013 188 -387 -950 -1633 -1243 -265 -1273 -840 -689 -404 563 919 986 807 315 124 -470 -118 -299 387 552 431 330 707 744 443 553 -844 -387 327 -66 -15 -693 -453 -634 -178 187 -111 872 536 138 27 -537 -866 160 -686 -787 -134 -786 137 195 -368 52 -270 -1101 -312 -879 97 -55 -436 779 699 -221 674 497 -286 -287 698 -697 -50 179 672 -48 755 -153 267 -181 -304 -1733 -1630 -765 -708 -6 118 -229 85 -364 -357 -126 694 -7 -76 282 -28 259 160 -167 600 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