File name: Pandora260s1_CameronLA_20240810_L2Fit_fout2c4d20240619p1-8.txt File generation date: 20241203T184441.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v4d20240619.txt Level 1 file used: Pandora260s1_CameronLA_20240810_L1_smca1c4d20240619p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20240810 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0227 305.1633 305.3039 305.4444 305.5849 305.7254 305.8660 306.0064 306.1469 306.2874 306.4279 306.5683 306.7088 306.8492 306.9896 307.1300 307.2704 307.4108 307.5511 307.6915 307.8319 307.9722 308.1125 308.2528 308.3931 308.5334 308.6737 308.8140 308.9542 309.0945 309.2347 309.3750 309.5152 309.6554 309.7956 309.9357 310.0759 310.2161 310.3562 310.4963 310.6365 310.7766 310.9167 311.0568 311.1968 311.3369 311.4770 311.6170 311.7570 311.8971 312.0371 312.1771 312.3171 312.4570 312.5970 312.7369 312.8769 313.0168 313.1567 313.2966 313.4365 313.5764 313.7163 313.8562 313.9960 314.1358 314.2757 314.4155 314.5553 314.6951 314.8349 314.9746 315.1144 315.2541 315.3939 315.5336 315.6733 315.8130 315.9527 316.0924 316.2321 316.3717 316.5114 316.6510 316.7906 316.9302 317.0698 317.2094 317.3490 317.4886 317.6281 317.7676 317.9072 318.0467 318.1862 318.3257 318.4652 318.6047 318.7441 318.8836 319.0230 319.1624 319.3018 319.4412 319.5806 319.7200 319.8594 319.9987 320.1381 320.2774 320.4167 320.5560 320.6953 320.8346 320.9739 321.1132 321.2524 321.3917 321.5309 321.6701 321.8093 321.9485 322.0877 322.2269 322.3660 322.5052 322.6443 322.7834 322.9226 323.0617 323.2007 323.3398 323.4789 323.6179 323.7570 323.8960 324.0350 324.1741 324.3131 324.4520 324.5910 324.7300 324.8689 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240810T123521.3Z 8988.524552 67 1 54.31 2 78.73 78.68 144.97 65.27 0.00 1 0.00 1 0 25 3.452e-01 9.089e-03 1.555e-01 1.639e-03 5.940487e-01 8.586421e-04 6.518709e-03 -6.000000e+00 1.960471e-01 229.59 -2.00 3.24 -2.00 320.34 0.00e+00 -7.064323e-04 3.330220e-04 2.446893e-03 -6.000000e+00 9.110918e-03 294.65 -2.00 20.00 -2.00 319.56 0.00e+00 4.937 0.001 302.00 328.00 3 1.7451e+00 2.6803e-03 5.8185e-02 -6.0000e+00 4.8769e-01 -1.1188e-01 3.4818e-03 3.3398e-02 -6.0000e+00 5.2626e-01 4.2313e-02 3.2685e-03 1.4643e-02 -6.0000e+00 3.1543e-01 -2.3741e-02 1.6622e-03 4.8997e-03 -6.0000e+00 1.3810e-01 3.9009e-04 1.7217e-04 4.2903e-05 4.1027e-05 -6.0000e+00 8.8282e-03 3.4891e-03 0.0000e+00 11 8 0 10 0 0 35.83 25.03 0.64 0.00349 0.00478 153 16 1 5 0 354.920 33.50 19.97 25.03 31.05 0.4 968.66 -47813 -33030 -123933 900000 -95540 11735 -47786 -74248 54327 22274 -28696 248266 -33300 40028 -39517 -13467 196214 79561 -12860 43521 7254 -12024 3733 8571 -22904 -15401 1445 45919 6105 56361 -3881 8103 -6747 -10935 -18807 -22366 7375 -1968 2347 8738 -963 -460 -1288 -1125 -125 5995 -14 -2057 2446 4113 105 -306 -3337 -439 2168 3037 -1283 3459 -1359 629 -1742 -804 1868 3318 2972 883 824 -2909 -125 1108 631 1124 1404 1013 -617 -1452 -1675 -4184 -3996 -2087 -1433 -526 -1576 -1878 -505 -168 230 1565 1648 1582 2838 403 -464 -424 -856 -90 110 1548 929 -257 -925 -1081 -1918 -1431 -449 -1363 -1064 -875 -433 669 1350 1029 854 323 -52 -670 -16 -396 400 307 572 411 695 755 8 271 -1264 -516 62 -319 -306 -737 -536 -756 -133 86 -150 814 678 376 180 -338 -489 -183 -132 -1367 900000 -733 30 -244 -581 139 89 -202 397 -330 243 -669 -215 439 636 -286 591 150 -304 84 207 -846 -573 48 954 180 1036 -152 337 -382 -729 -1328 -1569 420 -146 207 901 -127 -66 -198 -163 -20 921 -2 -326 425 673 20 -66 -814 -115 596 871 -403 1058 -427 189 -542 -268 685 1254 1228 367 330 -1224 -55 557 364 637 806 563 -352 -751 -789 -1962 -1993 -1201 -893 -375 -1183 -1506 -426 -152 206 1447 1547 1460 2604 352 -385 -346 -757 -85 119 1786 1143 -331 -1148 -1309 -2102 -1602 -504 -1661 -1353 -1113 -591 943 2112 1655 1404 521 -79 -1024 -24 -613 617 506 961 673 1098 1159 13 407 -1852 -738 97 -536 -541 -1343 -1022 -1515 -271 179 -325 1780 1515 828 378 -703 -970 SS 20240810T124105.8Z 8988.528539 70 1 54.32 2 77.51 79.34 143.89 66.67 0.00 1 0.00 1 0 25 1.418e-01 8.902e-03 4.632e-02 1.206e-03 5.471922e-01 6.216683e-04 6.022400e-03 -6.000000e+00 8.050023e-02 229.59 -2.00 3.24 -2.00 319.89 0.00e+00 4.496866e-04 2.058415e-04 1.869731e-03 -6.000000e+00 3.688776e-03 294.65 -2.00 20.00 -2.00 319.06 0.00e+00 4.490 0.001 302.00 328.00 3 1.6534e+00 1.8405e-03 5.2589e-02 -6.0000e+00 2.0023e-01 -8.5352e-02 2.2732e-03 2.8860e-02 -6.0000e+00 2.1608e-01 2.1539e-02 1.9729e-03 1.3373e-02 -6.0000e+00 1.2943e-01 -1.5231e-02 1.0350e-03 3.7387e-03 -6.0000e+00 5.6533e-02 6.7368e-04 1.6601e-04 3.1662e-05 3.8243e-05 -6.0000e+00 3.5807e-03 3.4608e-03 0.0000e+00 11 8 0 10 0 0 23.02 25.01 0.57 0.00346 0.00471 204 21 1 5 0 266.240 33.75 20.08 25.01 31.47 0.4 971.48 6666 -63992 -94430 27507 -53864 -963 -31747 -41955 8416 -34240 -38300 4948 -36565 -2753 -25544 -12340 33429 12737 -11482 8991 -4064 -7046 -11797 3350 -15691 -4875 -1286 8250 -3731 16243 -8570 -2475 -5107 -4356 -12001 -12736 -2863 -6071 732 1873 458 1619 -632 366 -698 3411 -807 -557 1467 1383 620 339 -849 459 2078 1974 215 1555 -1046 544 -768 531 1613 2563 2634 839 879 -2032 48 1579 1202 1079 1420 1002 -168 -968 -2309 -4059 -3808 -2039 -1894 -959 -1761 -2052 -793 179 498 1296 1911 1531 2136 676 -767 -661 -642 -432 -78 1193 850 85 -678 -1297 -1919 -1229 -547 -1585 -904 -776 -323 607 977 1067 814 385 42 -670 -125 -185 333 448 273 409 788 768 210 264 -1008 -448 342 -301 -109 -723 -578 -582 -67 4 -121 847 538 311 -30 -315 -536 31 -730 -1611 139 -558 -6 -276 -469 66 -463 -563 51 -693 -47 -682 -350 677 349 -439 299 -162 -291 -529 143 -894 -268 -71 407 -198 719 -560 -180 -442 -420 -1216 -1239 -274 -706 98 279 80 303 -128 76 -148 711 -179 -125 334 329 162 100 -256 149 715 710 82 597 -403 202 -293 215 729 1199 1333 422 423 -1009 25 930 751 721 961 657 -104 -586 -1283 -2214 -2189 -1249 -1361 -731 -1513 -1760 -715 173 479 1291 1924 1520 2104 625 -675 -605 -590 -426 -88 1439 1095 114 -874 -1631 -2185 -1420 -640 -2019 -1133 -1033 -436 892 1516 1698 1319 607 66 -989 -188 -276 523 717 448 657 1278 1211 318 404 -1498 -648 510 -486 -185 -1325 -1057 -1113 -131 8 -252 1784 1161 661 -60 -632 -1027 SS 20240810T124619.3Z 8988.532167 73 1 54.33 2 76.39 79.95 142.89 67.88 0.00 1 0.00 1 0 25 1.005e-01 8.792e-03 1.906e-02 9.296e-04 5.087063e-01 4.760072e-04 5.596146e-03 -6.000000e+00 5.709054e-02 229.59 -2.00 3.24 -2.00 319.48 0.00e+00 5.382924e-04 1.365137e-04 1.472791e-03 -6.000000e+00 2.616018e-03 294.65 -2.00 20.00 -2.00 318.61 0.00e+00 4.147 0.001 302.00 328.00 3 1.5440e+00 1.3662e-03 4.8455e-02 -6.0000e+00 1.4200e-01 -7.8276e-02 1.6364e-03 2.6078e-02 -6.0000e+00 1.5324e-01 1.7327e-02 1.3155e-03 1.2318e-02 -6.0000e+00 9.1789e-02 -1.3285e-02 7.0002e-04 3.3699e-03 -6.0000e+00 4.0094e-02 1.0785e-03 1.6430e-04 2.4585e-05 3.3323e-05 -6.0000e+00 2.5393e-03 3.1977e-03 0.0000e+00 11 8 0 10 0 0 59.47 25.03 0.54 0.00320 0.00443 264 28 1 5 0 205.760 33.50 20.02 25.03 31.89 0.4 974.59 -21461 -52913 -49831 -14395 -42301 -14819 -32772 -32268 -4149 -29302 -27869 -10970 -27181 -12280 -13870 -9268 8679 7978 -5046 2714 611 -3596 -4466 -607 -7747 -3695 -1156 4988 -5319 3547 -3785 -886 -2289 -2902 -9372 -10467 -3070 -3698 -1804 854 -448 402 26 754 438 2441 -97 -686 550 993 -152 473 -358 1091 1309 2021 599 919 -307 -55 -314 974 1963 3370 2541 414 199 -1803 460 965 808 1250 1065 1211 382 -943 -1638 -3714 -3289 -2155 -1929 -1033 -1670 -1948 -794 -12 753 1144 1622 1647 1495 597 -792 -846 -755 -686 -199 1095 797 -11 -586 -1362 -1903 -1391 -396 -1419 -920 -817 -396 717 1043 1117 787 461 35 -541 -103 -177 258 468 370 310 849 787 206 373 -937 -417 267 -102 -75 -562 -504 -674 -72 101 -139 757 523 247 140 -411 -700 -233 -935 -935 -189 -663 -169 -484 -547 -62 -624 -606 -214 -752 -365 -517 -396 346 350 -274 145 35 -216 -279 -40 -603 -296 -94 372 -417 257 -336 -89 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