File name: Pandora260s1_CameronLA_20241118_L2Fit_fout2c4d20240619p1-8.txt File generation date: 20241203T193613.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v4d20240619.txt Level 1 file used: Pandora260s1_CameronLA_20241118_L1_smca1c4d20240619p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20241118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0227 305.1633 305.3039 305.4444 305.5849 305.7254 305.8660 306.0064 306.1469 306.2874 306.4279 306.5683 306.7088 306.8492 306.9896 307.1300 307.2704 307.4108 307.5511 307.6915 307.8319 307.9722 308.1125 308.2528 308.3931 308.5334 308.6737 308.8140 308.9542 309.0945 309.2347 309.3750 309.5152 309.6554 309.7956 309.9357 310.0759 310.2161 310.3562 310.4963 310.6365 310.7766 310.9167 311.0568 311.1968 311.3369 311.4770 311.6170 311.7570 311.8971 312.0371 312.1771 312.3171 312.4570 312.5970 312.7369 312.8769 313.0168 313.1567 313.2966 313.4365 313.5764 313.7163 313.8562 313.9960 314.1358 314.2757 314.4155 314.5553 314.6951 314.8349 314.9746 315.1144 315.2541 315.3939 315.5336 315.6733 315.8130 315.9527 316.0924 316.2321 316.3717 316.5114 316.6510 316.7906 316.9302 317.0698 317.2094 317.3490 317.4886 317.6281 317.7676 317.9072 318.0467 318.1862 318.3257 318.4652 318.6047 318.7441 318.8836 319.0230 319.1624 319.3018 319.4412 319.5806 319.7200 319.8594 319.9987 320.1381 320.2774 320.4167 320.5560 320.6953 320.8346 320.9739 321.1132 321.2524 321.3917 321.5309 321.6701 321.8093 321.9485 322.0877 322.2269 322.3660 322.5052 322.6443 322.7834 322.9226 323.0617 323.2007 323.3398 323.4789 323.6179 323.7570 323.8960 324.0350 324.1741 324.3131 324.4520 324.5910 324.7300 324.8689 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241118T132201.5Z 9088.556962 264 1 54.44 2 82.58 117.44 63.03 288.65 0.00 1 0.00 1 0 17 3.997e-01 1.301e-02 1.920e-01 3.629e-03 6.290562e-01 2.028914e-03 7.050014e-03 -6.000000e+00 2.313851e-01 224.96 -2.00 3.24 -2.00 321.18 0.00e+00 9.589779e-04 1.028552e-03 4.387851e-03 -6.000000e+00 1.259700e-02 288.34 -2.00 20.00 -2.00 320.58 0.00e+00 7.163 0.004 302.00 328.00 3 1.0643e+00 7.1196e-03 8.0368e-02 -6.0000e+00 5.7272e-01 -1.8203e-02 1.0421e-02 4.2786e-02 -6.0000e+00 6.2486e-01 -2.9472e-02 1.1103e-02 1.9049e-02 -6.0000e+00 3.7004e-01 3.7629e-03 5.2419e-03 5.2076e-03 -6.0000e+00 1.6183e-01 9.2345e-05 1.4861e-05 1.0376e-04 7.2400e-05 -6.0000e+00 1.1016e-02 -1.4394e-03 0.0000e+00 12 9 8 11 32 0 72.27 24.87 0.67 -0.00144 -0.00133 75 8 1 5 0 725.790 33.50 20.01 24.87 29.71 0.4 955.00 900000 -160024 -243811 900000 -67082 900000 900000 147997 900000 -107154 -167738 900000 -100116 900000 900000 -66622 900000 900000 22477 900000 900000 30919 25554 28499 -39628 16622 900000 900000 900000 900000 -3435 53739 -27021 -21182 -36468 -31924 900000 21329 56642 50837 4679 23088 -9941 5972 -3681 47864 641 2483 32602 41369 -4994 -4385 -14262 7261 14810 9101 -9298 9091 -2876 285 438 391 1558 2334 6017 8542 11534 -2643 3661 1322 -2543 -2657 1535 984 -1252 -2593 -2434 -8109 -7157 -4572 -3111 2414 -1000 -2805 489 -357 -2739 1130 1333 796 7413 -810 -1245 1352 -262 284 1029 2739 113 -476 -1714 -836 -1121 -2187 -193 -1370 -1132 -526 -406 603 859 870 1043 -396 936 -843 20 -410 543 269 235 1100 645 650 -421 573 -1075 -1080 303 46 -938 -816 -487 -186 -444 18 123 1160 498 -1 -351 -412 183 900000 -872 -3440 900000 -237 900000 900000 522 900000 -642 -1952 900000 -812 900000 900000 -799 900000 900000 159 900000 900000 229 207 251 -769 199 900000 900000 900000 900000 -62 663 -886 -747 -1479 -1182 900000 594 1378 1632 279 1254 -803 430 -296 2363 52 205 2093 2582 -549 -548 -2183 988 2032 1393 -1797 1494 -522 49 76 73 330 564 1545 2127 2705 -728 1015 437 -910 -1021 577 359 -435 -904 -771 -2657 -2494 -1840 -1336 1138 -552 -1687 304 -242 -2023 840 1008 597 4904 -541 -792 830 -178 222 851 2580 124 -548 -1922 -853 -1029 -1939 -181 -1400 -1212 -599 -461 755 1211 1244 1533 -579 1388 -1201 28 -592 825 407 363 1643 1007 989 -622 812 -1493 -1478 450 73 -1675 -1476 -927 -372 -955 40 275 2627 1160 -1 -771 -914 384 SS 20241118T133923.2Z 9088.569018 272 1 3.14 2 79.28 119.89 66.46 290.12 0.00 1 0.00 1 0 17 2.997e-01 1.693e-02 2.697e-01 1.222e-02 4.821649e-01 6.246888e-03 5.269583e-03 -6.000000e+00 1.694847e-01 224.95 -2.00 3.24 -2.00 319.93 0.00e+00 4.838849e-03 2.104920e-03 9.746413e-04 -6.000000e+00 7.902639e-03 288.34 -2.00 20.00 -2.00 319.22 0.00e+00 5.171 0.002 302.00 328.00 3 2.3291e+00 1.8426e-02 5.6264e-02 -6.0000e+00 4.1717e-01 -6.7486e-03 2.2689e-02 2.3355e-02 -6.0000e+00 4.5227e-01 6.3686e-03 1.9955e-02 1.3378e-02 -6.0000e+00 2.6950e-01 -7.9148e-03 1.0394e-02 6.3967e-03 -6.0000e+00 1.1806e-01 1.8691e-04 -2.7694e-04 3.3447e-04 5.9724e-05 -6.0000e+00 7.6033e-03 -2.6417e-03 0.0000e+00 12 9 9 12 33 1 999.00 24.87 0.67 -0.00264 -0.00472 2 5 1 5 0 1043.520 33.50 20.03 24.87 30.16 0.4 957.79 562 -119784 900000 -105111 -41576 900000 900000 98472 1356 -78732 -88999 58618 -52006 -65511 -14465 -32941 57240 113216 47614 -42527 49301 36907 -18892 24659 -15018 -15079 83351 129590 13080 58031 3729 -25166 -4507 -2105 21760 -359 13387 -10980 26725 11167 -3560 11749 -8284 1917 12111 26780 4401 -5295 -428 10812 2353 -5002 -7935 4436 2934 4675 -3857 5129 -1217 2092 -3710 -1830 3888 9123 6097 -1001 3073 -2675 -3428 -2263 1218 1218 299 1296 1793 -346 -4756 -4195 -8919 -2921 -2769 1289 526 -4934 -815 856 -2461 164 651 1306 1624 -1577 96 1215 -3407 828 1741 439 568 -68 177 1180 -1831 5 113 -1400 1480 678 -357 1593 297 -731 1293 1062 -288 -560 -134 1670 -597 -1583 792 240 -654 323 832 685 -1644 -2219 632 537 18 -743 -609 -937 373 410 -826 1345 878 -385 -626 430 -214 7 -3113 900000 -2618 -545 900000 900000 1173 16 -2063 -2650 698 -1363 -2497 -413 -1373 1091 1348 1191 -2786 1350 1143 -1035 940 -912 -970 2085 2006 623 1797 226 -2398 -403 -206 1633 -32 1100 -1334 2705 1609 -621 2085 -1731 378 2190 4720 901 -1210 -95 2224 568 -1451 -2586 1383 991 1605 -1491 1838 -456 745 -1426 -745 1680 4218 2881 -496 1381 -1261 -1701 -1274 754 806 203 846 1093 -195 -2525 -2115 -4913 -1754 -1946 918 421 -4417 -743 770 -2437 165 667 1312 1532 -1418 85 1026 -3184 781 1863 508 738 -87 229 1394 -2012 6 126 -1714 1842 903 -481 2300 451 -1206 2116 1685 -434 -840 -195 2463 -900 -2586 1310 393 -1048 498 1299 1030 -2421 -3198 954 855 29 -1327 -1131 -1719 719 846 -1705 2769 1858 -817 -1270 866 -415 SS 20241118T134429.6Z 9088.572565 275 1 54.37 2 78.32 120.63 67.46 290.57 0.00 1 0.00 1 0 17 7.321e-02 7.984e-03 1.093e-02 8.093e-04 4.575038e-01 4.055862e-04 5.040749e-03 -6.000000e+00 4.087183e-02 224.95 -2.00 3.24 -2.00 319.16 0.00e+00 1.007681e-03 1.043980e-04 9.713872e-04 -6.000000e+00 1.854120e-03 288.34 -2.00 20.00 -2.00 318.38 0.00e+00 4.781 0.001 302.00 328.00 3 7.8294e-01 1.1289e-03 5.2298e-02 -6.0000e+00 1.0080e-01 -2.3459e-02 1.3244e-03 2.2379e-02 -6.0000e+00 1.0924e-01 9.5434e-03 1.0240e-03 1.1050e-02 -6.0000e+00 6.5414e-02 -1.1247e-02 5.4960e-04 3.1876e-03 -6.0000e+00 2.8694e-02 1.3315e-03 -7.8956e-05 2.1534e-05 3.2103e-05 -6.0000e+00 1.8465e-03 -1.3633e-03 0.0000e+00 11 8 0 10 0 0 98.61 24.87 0.43 -0.00136 -0.00196 318 33 1 5 0 170.960 33.50 20.02 24.87 30.31 0.4 959.25 -31031 -31140 -26913 -9393 -28526 -17640 -26494 -17424 -10634 -20059 -29630 -10052 -18750 -8578 -8538 -5715 3423 1095 -4187 1057 -1001 -6065 -3478 -1854 -5689 -2675 -1569 -596 -2190 -503 -3004 -101 -1049 -2063 -6292 -8330 -3239 -4054 -967 669 136 276 122 902 578 1930 782 -72 576 -428 849 725 728 1991 1548 1395 630 841 -139 305 55 1533 2061 3100 2174 260 559 -1425 -35 680 656 899 722 763 361 -628 -1327 -3038 -2749 -2105 -2049 -1061 -1760 -1936 -946 -323 196 549 1393 1388 1180 415 -528 -748 -622 -513 -107 1058 964 -64 -506 -1000 -1308 -1034 -303 -1486 -1053 -780 -244 494 877 959 693 247 27 -465 17 -45 314 467 175 241 862 840 291 362 -767 -100 343 -153 -215 -438 -362 -515 -30 96 -148 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