File name: Pandora260s1_CameronLA_20241126_L2Fit_fout2c4d20240619p1-8.txt File generation date: 20241203T194845.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v4d20240619.txt Level 1 file used: Pandora260s1_CameronLA_20241126_L1_smca1c4d20240619p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20241126 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0227 305.1633 305.3039 305.4444 305.5849 305.7254 305.8660 306.0064 306.1469 306.2874 306.4279 306.5683 306.7088 306.8492 306.9896 307.1300 307.2704 307.4108 307.5511 307.6915 307.8319 307.9722 308.1125 308.2528 308.3931 308.5334 308.6737 308.8140 308.9542 309.0945 309.2347 309.3750 309.5152 309.6554 309.7956 309.9357 310.0759 310.2161 310.3562 310.4963 310.6365 310.7766 310.9167 311.0568 311.1968 311.3369 311.4770 311.6170 311.7570 311.8971 312.0371 312.1771 312.3171 312.4570 312.5970 312.7369 312.8769 313.0168 313.1567 313.2966 313.4365 313.5764 313.7163 313.8562 313.9960 314.1358 314.2757 314.4155 314.5553 314.6951 314.8349 314.9746 315.1144 315.2541 315.3939 315.5336 315.6733 315.8130 315.9527 316.0924 316.2321 316.3717 316.5114 316.6510 316.7906 316.9302 317.0698 317.2094 317.3490 317.4886 317.6281 317.7676 317.9072 318.0467 318.1862 318.3257 318.4652 318.6047 318.7441 318.8836 319.0230 319.1624 319.3018 319.4412 319.5806 319.7200 319.8594 319.9987 320.1381 320.2774 320.4167 320.5560 320.6953 320.8346 320.9739 321.1132 321.2524 321.3917 321.5309 321.6701 321.8093 321.9485 322.0877 322.2269 322.3660 322.5052 322.6443 322.7834 322.9226 323.0617 323.2007 323.3398 323.4789 323.6179 323.7570 323.8960 324.0350 324.1741 324.3131 324.4520 324.5910 324.7300 324.8689 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241126T135517.5Z 9096.580064 193 1 54.40 2 77.77 123.26 37.43 163.22 0.00 1 0.00 1 0 17 1.549e-01 8.334e-03 2.389e-02 9.762e-04 5.364616e-01 4.939759e-04 5.903606e-03 -6.000000e+00 8.637947e-02 224.75 -2.00 3.24 -2.00 319.71 0.00e+00 8.572796e-04 1.531516e-04 1.424922e-03 -6.000000e+00 3.912338e-03 287.73 -2.00 20.00 -2.00 318.99 0.00e+00 4.583 0.001 302.00 328.00 3 1.2414e+00 1.4240e-03 5.2510e-02 -6.0000e+00 2.1297e-01 -7.2967e-02 1.7314e-03 2.6755e-02 -6.0000e+00 2.3089e-01 1.9964e-02 1.5082e-03 1.3246e-02 -6.0000e+00 1.3824e-01 -1.4688e-02 7.9440e-04 3.7513e-03 -6.0000e+00 6.0599e-02 9.3951e-04 1.0136e-05 2.5659e-05 4.1831e-05 -6.0000e+00 3.9074e-03 1.4098e-03 0.0000e+00 11 8 0 10 0 0 16.89 24.96 0.51 0.00141 0.00149 286 30 1 5 0 190.180 33.50 20.00 24.96 18.96 0.9 876.71 -53320 -74622 -63661 -18468 -64526 -33620 -44599 -43319 -28196 -39291 -52428 -43931 -34386 -28010 -21811 -8725 7934 5867 -10956 3051 -4817 -7545 -9045 -3600 -10714 -9713 -3372 2353 -5829 521 -5794 -7 -4841 -4044 -10401 -10523 -2399 -6531 -1883 415 419 558 -251 -182 499 2552 119 71 1175 1672 368 607 551 1796 1908 2184 787 1528 -428 423 300 1179 1721 3383 2391 631 723 -1564 -31 1057 815 1263 904 893 467 -908 -2046 -3454 -2939 -1709 -2099 -1012 -1637 -2196 -1038 -32 297 829 1407 1490 1305 578 -682 -621 -883 -343 -162 1243 788 -40 -600 -786 -1687 -1317 -645 -1558 -1040 -777 -71 563 991 1083 761 442 142 -487 51 -310 168 340 130 209 825 848 28 319 -802 -127 423 25 -161 -484 -306 -581 -209 19 -232 669 623 117 -88 -244 -537 -548 -1137 -958 -178 -891 -326 -522 -577 -376 -655 -1038 -853 -740 -715 -652 -277 241 200 -483 125 -223 -361 -452 -188 -661 -638 -217 140 -358 31 -416 -1 -471 -439 -1172 -1128 -256 -852 -263 70 81 117 -56 -42 117 596 29 17 297 438 107 181 180 633 721 859 327 641 -180 171 123 517 781 1709 1322 347 379 -841 -18 628 553 850 621 592 311 -552 -1138 -2020 -1672 -1120 -1514 -828 -1413 -2024 -946 -31 307 839 1439 1498 1307 540 -642 -568 -816 -359 -184 1509 1026 -52 -784 -943 -1933 -1527 -759 -1894 -1315 -1042 -96 798 1485 1746 1251 707 215 -725 73 -465 266 549 216 340 1289 1347 43 469 -1196 -185 634 41 -276 -856 -564 -1079 -411 39 -473 1375 1309 243 -180 -476 -1039 SS 20241126T140033.2Z 9096.583718 196 1 54.27 2 76.82 124.05 37.15 165.30 0.00 1 0.00 1 0 17 1.062e-01 8.189e-03 1.364e-02 7.772e-04 5.050818e-01 3.899798e-04 5.560676e-03 -6.000000e+00 5.923235e-02 224.75 -2.00 3.24 -2.00 319.38 0.00e+00 7.607389e-04 1.083879e-04 1.183474e-03 -6.000000e+00 2.682788e-03 287.73 -2.00 20.00 -2.00 318.63 0.00e+00 4.276 0.001 302.00 328.00 3 1.1344e+00 1.1009e-03 4.8993e-02 -6.0000e+00 1.4604e-01 -6.8249e-02 1.3111e-03 2.4820e-02 -6.0000e+00 1.5833e-01 1.5835e-02 1.0722e-03 1.2281e-02 -6.0000e+00 9.4791e-02 -1.1501e-02 5.7159e-04 3.4883e-03 -6.0000e+00 4.1554e-02 1.4414e-03 -3.0505e-06 2.0442e-05 3.6603e-05 -6.0000e+00 2.6794e-03 1.4786e-03 0.0000e+00 11 8 0 10 0 0 40.06 24.96 0.47 0.00148 0.00146 369 39 1 5 0 147.050 33.50 20.00 24.96 19.13 0.9 878.03 -37464 -35633 -36642 -39975 -39224 -36943 -30119 -33027 -24898 -21419 -30469 -27291 -29172 -19809 -10801 -10181 2224 449 -6024 2073 -58 -7035 -4276 -4183 -7005 -6299 -4255 461 -4963 -3590 -4516 -1503 -2497 -2263 -7311 -9560 -4497 -4618 -1965 783 -16 1198 -353 923 1322 1459 681 -340 769 722 1028 1230 515 1998 2159 966 767 952 88 248 -49 935 1907 3105 2151 667 737 -1302 268 1036 1122 1265 633 860 161 -810 -1080 -3532 -2735 -2096 -2162 -1058 -1773 -2022 -973 -273 195 546 1443 1305 983 549 -597 -701 -515 -174 -371 1237 944 -51 -580 -1025 -1593 -1156 -596 -1613 -788 -838 -260 620 930 1066 700 448 103 -401 143 -219 335 240 7 169 860 827 314 454 -642 -92 437 -38 -134 -461 -288 -625 -209 72 -190 682 523 75 -155 -258 -577 -528 -586 -667 -751 -660 -580 -475 -616 -496 -459 -741 -681 -893 -691 -425 -478 103 23 -361 122 -4 -474 -288 -309 -583 -558 -385 39 -418 -301 -434 -164 -317 -291 -960 -1217 -587 -705 -359 171 -4 297 -94 251 361 406 194 -99 227 220 339 454 193 801 926 436 361 454 42 114 -23 465 978 1772 1248 382 429 -771 153 678 782 940 482 630 111 -543 -656 -2105 -1692 -1495 -1692 -882 -1566 -1898 -960 -274 207 572 1524 1358 1014 526 -570 -649 -506 -183 -426 1519 1243 -67 -766 -1248 -1842 -1348 -709 -1997 -1012 -1142 -361 893 1418 1675 1118 721 156 -594 205 -327 505 388 12 276 1354 1266 480 667 -952 -132 650 -61 -228 -809 -505 -1147 -392 141 -383 1392 1056 150 -306 -501 -1072 SS 20241126T140618.1Z 9096.587710 199 1 53.47 2 75.80 124.94 36.88 167.60 0.00 1 0.00 1 0 17 2.844e-01 1.327e-02 1.034e-01 3.141e-03 4.712642e-01 1.597926e-03 5.302522e-03 -6.000000e+00 1.597163e-01 224.75 -2.00 3.24 -2.00 319.81 0.00e+00 1.110777e-03 5.100641e-04 1.720162e-03 -6.000000e+00 7.254146e-03 287.73 -2.00 20.00 -2.00 319.10 0.00e+00 3.986 0.001 302.00 328.00 3 3.8927e+00 4.6301e-03 4.6075e-02 -6.0000e+00 3.9364e-01 -5.7792e-02 5.6566e-03 2.4508e-02 -6.0000e+00 4.2712e-01 2.8623e-02 4.9351e-03 1.1969e-02 -6.0000e+00 2.5473e-01 -1.7561e-02 2.5928e-03 3.3208e-03 -6.0000e+00 1.1203e-01 1.2301e-04 3.7436e-05 8.6210e-05 3.8362e-05 -6.0000e+00 7.2903e-03 1.0711e-03 0.0000e+00 12 9 8 11 32 0 99.98 24.96 0.44 0.00107 0.00135 29 3 1 5 0 1843.450 33.50 19.95 24.96 19.30 0.9 878.64 900000 -79572 -92977 93837 -67177 -38645 900000 -38534 72157 -17347 -19509 -21133 -45969 -11342 -9019 -9846 193772 95840 -12866 52582 36521 -105 4036 9181 -21658 -15057 4694 103592 28710 54510 -1363 13349 -12275 -12180 -17117 -11570 20174 -2340 9002 7340 1255 4744 -4827 -2955 -2162 8580 -749 866 7483 -3814 651 -2195 -3293 1772 4594 544 -3015 6310 654 88 979 -363 829 1735 3587 2233 4809 -4147 2110 346 546 -34 18 291 156 -2549 -949 -6562 -4361 -1679 -3665 157 -614 -2440 -524 -169 -1492 543 1503 546 4900 -401 -1163 -1984 -1220 291 1407 2798 775 706 -1534 -1581 -930 -1514 -497 -1886 -764 -626 -654 1273 1412 1305 788 686 650 -445 705 -499 -847 298 133 -74 192 836 637 434 -1003 -559 735 91 -968 -977 -595 -585 -685 178 -22 942 402 223 -56 -344 165 900000 -1617 -2355 402 -1296 -532 900000 -649 464 -303 -358 -414 -1379 -299 -284 -374 1068 1526 -658 1481 1264 -5 198 467 -1631 -1134 302 2410 1336 1969 -97 948 -1289 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