File name: Pandora184s1_CapeElizabethME_20210625_L2Fit_fout2c1d20210422p1-8.txt File generation date: 20260323T185949.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 184 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora184_OF_v4d20201127.txt Instrument calibration file used: Pandora184s1_CF_v1d20210422.txt Level 1 file used: Pandora184s1_CapeElizabethME_20210625_L1_smca1c1d20210422p1-8.txt.bz2 Full location name: CEPTL - Cape Elizabeth Two Lights (State Park) Maine Short location name: CapeElizabethME Country of location: United States Location latitude [deg]: 43.5610 Location longitude [deg]: -70.2073 Location altitude [m]: 24 Local noon date: 20210625 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0138 305.1549 305.2959 305.4370 305.5780 305.7190 305.8600 306.0010 306.1420 306.2830 306.4239 306.5649 306.7058 306.8468 306.9877 307.1286 307.2695 307.4104 307.5513 307.6922 307.8330 307.9739 308.1147 308.2555 308.3964 308.5372 308.6780 308.8187 308.9595 309.1003 309.2410 309.3818 309.5225 309.6632 309.8039 309.9446 310.0853 310.2260 310.3667 310.5073 310.6480 310.7886 310.9292 311.0698 311.2104 311.3510 311.4916 311.6322 311.7727 311.9133 312.0538 312.1943 312.3348 312.4753 312.6158 312.7563 312.8968 313.0372 313.1777 313.3181 313.4586 313.5990 313.7394 313.8798 314.0202 314.1605 314.3009 314.4412 314.5816 314.7219 314.8622 315.0025 315.1428 315.2831 315.4234 315.5637 315.7039 315.8441 315.9844 316.1246 316.2648 316.4050 316.5452 316.6854 316.8255 316.9657 317.1058 317.2459 317.3861 317.5262 317.6663 317.8063 317.9464 318.0865 318.2265 318.3666 318.5066 318.6466 318.7866 318.9266 319.0666 319.2066 319.3466 319.4865 319.6265 319.7664 319.9063 320.0462 320.1861 320.3260 320.4659 320.6057 320.7456 320.8854 321.0252 321.1651 321.3049 321.4447 321.5845 321.7242 321.8640 322.0037 322.1435 322.2832 322.4229 322.5626 322.7023 322.8420 322.9817 323.1213 323.2610 323.4006 323.5402 323.6799 323.8195 323.9591 324.0986 324.2382 324.3778 324.5173 324.6569 324.7964 324.9359 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20210625T150220.7Z 7846.626629 1803 1 46.23 2 29.00 125.93 144.55 287.36 0.00 1 0.00 1 0 25 1.210e-02 8.851e-03 5.116e-03 2.604e-03 1.693444e-01 1.360569e-03 2.050188e-03 -6.000000e+00 7.185758e-03 233.04 -2.00 3.57 -2.00 316.07 0.00e+00 4.677578e-04 1.454297e-04 1.410724e-04 -6.000000e+00 3.155871e-04 285.93 -2.00 20.00 -2.00 315.32 0.00e+00 1.143 0.000 302.00 328.00 3 5.5550e+00 3.5668e-03 1.4619e-02 -6.0000e+00 1.8057e-02 6.2092e-02 3.9680e-03 8.9453e-03 -6.0000e+00 1.9498e-02 -7.4587e-03 2.2779e-03 4.3248e-03 -6.0000e+00 1.1595e-02 -2.7331e-03 1.0331e-03 1.1817e-03 -6.0000e+00 4.8538e-03 5.4478e-04 3.0788e-04 7.7686e-05 1.4843e-05 -6.0000e+00 3.4461e-04 4.5822e-03 2.1304e-05 11 8 0 10 0 0 99.94 23.04 0.50 0.00458 0.00690 19 5 1 5 0 2432.910 26.83 20.00 23.04 22.87 7.2 969.26 -1370 70 -1329 -38 -5104 -928 -1352 95 2697 390 -2245 -2832 -757 -1245 758 -175 650 2885 382 1487 1774 329 2098 49 680 493 887 -323 -735 -308 725 -472 1118 -264 -2917 -3693 -2199 -2736 -499 -824 -1328 -793 -115 -371 -320 -101 -270 -101 226 -797 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695 879 412 334 -504 -425 951 454 15 169 -724 -337 139 991 338 254 950 -664 112 -1788 -1504 SU 20210625T150510.5Z 7846.628594 1806 1 48.56 2 28.58 126.97 145.01 288.04 0.00 1 0.00 1 0 17 1.633e-02 1.134e-02 9.634e-03 4.606e-03 1.721942e-01 2.402891e-03 2.078800e-03 -6.000000e+00 9.696055e-03 233.04 -2.00 3.57 -2.00 316.44 0.00e+00 5.402471e-04 2.771878e-04 1.198105e-04 -6.000000e+00 4.258443e-04 285.93 -2.00 20.00 -2.00 315.69 0.00e+00 1.138 0.000 302.00 328.00 3 6.3865e+00 6.3155e-03 1.4694e-02 -6.0000e+00 2.4365e-02 7.5494e-02 7.0393e-03 9.1082e-03 -6.0000e+00 2.6311e-02 -5.4723e-03 4.0358e-03 4.4030e-03 -6.0000e+00 1.5646e-02 -6.4608e-03 1.8427e-03 1.2165e-03 -6.0000e+00 6.5488e-03 2.3545e-04 -1.1759e-05 1.3837e-04 1.4720e-05 -6.0000e+00 4.6508e-04 4.1744e-03 -4.0370e-05 12 8 8 10 0 0 99.61 23.04 1.17 0.00417 0.00409 13 4 1 5 0 3734.370 26.83 19.98 23.04 23.19 7.2 971.07 4584 -490 2695 1452 -1234 -4707 1766 3006 2290 -1127 1483 -256 -3130 -3053 -1309 -3298 617 3952 297 149 -253 -28 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99.60 23.04 0.72 0.00399 0.00614 9 4 1 5 0 3320.710 26.83 20.00 23.04 23.76 7.2 975.77 3994 1108 -716 -1846 -3773 774 -1353 678 155 133 -40 -4272 -3353 -729 1392 -778 1409 1299 254 1985 1055 225 245 1831 -311 1619 -85 -1119 -1938 -1824 1384 1170 1558 -649 -2176 -4384 -3124 -2429 -598 35 -974 -146 402 -379 -793 971 371 -967 -598 -693 286 -991 1145 1285 649 805 1175 607 746 -187 487 2040 2220 1349 -316 -244 -63 -928 -1162 1797 1053 256 939 1371 95 -230 -1180 -2970 -2032 -915 -1642 -804 -2030 -1813 -824 -144 430 1469 1168 658 702 -518 -1498 -380 -1182 -213 67 1131 516 -98 -74 -975 -1856 -606 -1210 -18 -747 -1055 -415 966 838 1309 1065 -416 -263 -1062 -350 -393 -81 498 239 724 810 1237 464 1156 -1097 -668 641 -207 19 -25 -104 -588 336 669 123 -141 854 -69 94 -1218 -1022 826 258 -173 -430 -798 144 -260 140 36 32 -10 -1165 -960 -226 428 -265 487 503 102 803 439 94 102 776 -141 741 -40 -498 -802 -716 530 472 663 -290 -940 -1851 -1369 -1208 -346 23 -656 -102 287 -275 -574 685 283 -719 -426 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