File name: Pandora184s1_CapeElizabethME_20210812_L2Fit_fout2c1d20210422p1-8.txt File generation date: 20260323T190752.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 184 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora184_OF_v4d20201127.txt Instrument calibration file used: Pandora184s1_CF_v1d20210422.txt Level 1 file used: Pandora184s1_CapeElizabethME_20210812_L1_smca1c1d20210422p1-8.txt.bz2 Full location name: CEPTL - Cape Elizabeth Two Lights (State Park) Maine Short location name: CapeElizabethME Country of location: United States Location latitude [deg]: 43.5610 Location longitude [deg]: -70.2073 Location altitude [m]: 24 Local noon date: 20210812 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0138 305.1549 305.2959 305.4370 305.5780 305.7190 305.8600 306.0010 306.1420 306.2830 306.4239 306.5649 306.7058 306.8468 306.9877 307.1286 307.2695 307.4104 307.5513 307.6922 307.8330 307.9739 308.1147 308.2555 308.3964 308.5372 308.6780 308.8187 308.9595 309.1003 309.2410 309.3818 309.5225 309.6632 309.8039 309.9446 310.0853 310.2260 310.3667 310.5073 310.6480 310.7886 310.9292 311.0698 311.2104 311.3510 311.4916 311.6322 311.7727 311.9133 312.0538 312.1943 312.3348 312.4753 312.6158 312.7563 312.8968 313.0372 313.1777 313.3181 313.4586 313.5990 313.7394 313.8798 314.0202 314.1605 314.3009 314.4412 314.5816 314.7219 314.8622 315.0025 315.1428 315.2831 315.4234 315.5637 315.7039 315.8441 315.9844 316.1246 316.2648 316.4050 316.5452 316.6854 316.8255 316.9657 317.1058 317.2459 317.3861 317.5262 317.6663 317.8063 317.9464 318.0865 318.2265 318.3666 318.5066 318.6466 318.7866 318.9266 319.0666 319.2066 319.3466 319.4865 319.6265 319.7664 319.9063 320.0462 320.1861 320.3260 320.4659 320.6057 320.7456 320.8854 321.0252 321.1651 321.3049 321.4447 321.5845 321.7242 321.8640 322.0037 322.1435 322.2832 322.4229 322.5626 322.7023 322.8420 322.9817 323.1213 323.2610 323.4006 323.5402 323.6799 323.8195 323.9591 324.0986 324.2382 324.3778 324.5173 324.6569 324.7964 324.9359 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210812T105548.3Z 7894.455420 80 1 47.05 2 78.08 80.79 120.99 55.33 0.00 1 0.00 1 0 17 4.994e-01 2.480e-02 3.243e-01 1.608e-02 5.638458e-01 9.204860e-03 6.816401e-03 -6.000000e+00 3.027177e-01 232.11 -2.00 3.57 -2.00 321.15 0.00e+00 -3.305255e-03 4.318513e-03 5.154547e-03 -6.000000e+00 1.432520e-02 288.35 -2.00 20.00 -2.00 320.49 0.00e+00 4.688 0.002 302.00 328.00 3 4.0566e+00 3.1956e-02 6.3943e-02 -6.0000e+00 7.6187e-01 1.3881e-01 4.2412e-02 5.3465e-02 -6.0000e+00 8.2808e-01 -2.5031e-01 3.6597e-02 1.7522e-02 -6.0000e+00 4.9133e-01 1.0681e-01 1.7231e-02 7.7252e-03 -6.0000e+00 2.0434e-01 4.7588e-05 -4.9564e-04 5.2066e-04 5.4986e-05 -6.0000e+00 1.4445e-02 -2.8077e-04 -4.7788e-05 12 8 8 10 0 0 99.56 22.91 0.79 -0.00028 -0.00401 14 4 1 5 0 3359.370 26.83 19.98 22.91 28.05 10.3 1009.66 -89425 -149257 900000 -149473 -88819 -172778 900000 -194443 8354 -109951 -124972 900000 10666 900000 900000 900000 900000 900000 5199 900000 -18969 900000 37552 163979 242934 29976 -59540 207596 -5756 63809 -56441 900000 -12163 43056 -476 12393 -9766 22283 19082 -6446 -5749 3299 -6145 28272 -7933 -1936 5783 23372 1560 18825 13322 61925 28232 20674 17966 13516 20370 12404 7158 8487 -2587 2220 11633 9605 11443 10736 7974 14835 7470 -4872 10921 -3866 6026 -6739 3765 -2303 -7878 -2026 -10487 -7740 -8572 3544 1559 -1325 -1626 -4972 1433 -1099 -51 2455 506 -2328 -4094 -2251 626 -2513 -1970 1876 594 -3862 -1545 1887 -2603 -4183 1194 2240 -3178 965 -1700 2731 1066 1073 1254 1358 -627 -531 -2442 1968 -1740 1266 -247 1660 1022 903 -58 2698 -2005 3050 -1755 1772 -472 -929 -1763 -739 -133 347 1042 2031 346 -357 -1025 -1122 -625 -1399 -3698 900000 -3898 -1390 -4957 900000 -8367 131 -2581 -3585 900000 167 900000 900000 900000 900000 900000 118 900000 -594 900000 694 2566 3801 768 -3811 3248 -197 1089 -3533 900000 -640 1409 -24 529 -556 1078 1167 -614 -622 352 -752 2494 -1004 -231 642 2194 186 1982 1611 5109 3574 3059 2914 2403 3506 2329 1385 1582 -545 477 2532 2364 2914 2973 2196 3853 2256 -1898 4050 -1761 2499 -3048 1420 -832 -2761 -656 -3971 -3294 -4279 1786 883 -825 -1086 -3680 1052 -856 -39 1802 356 -1566 -2659 -1441 423 -1994 -1782 1852 648 -4466 -1659 1790 -2387 -3888 1123 2222 -3511 1088 -2131 3615 1573 1672 1958 2044 -908 -732 -3420 2744 -2671 1980 -395 2549 1527 1306 -81 3534 -2657 3933 -2609 2831 -842 -1764 -3533 -1551 -295 811 2487 4885 847 -854 -2341 -2431 -1307 SS 20210812T110119.0Z 7894.459247 83 1 42.50 2 77.09 81.71 120.22 56.58 0.00 1 0.00 1 0 25 2.875e-01 1.353e-02 2.326e-01 8.172e-03 5.279784e-01 4.453258e-03 7.050269e-03 -6.000000e+00 1.703336e-01 232.11 -2.00 3.57 -2.00 320.93 0.00e+00 2.035639e-03 1.937959e-03 6.168563e-03 -6.000000e+00 7.578950e-03 288.35 -2.00 20.00 -2.00 320.24 0.00e+00 4.356 0.002 302.00 328.00 3 3.4210e+00 1.4786e-02 6.0430e-02 -6.0000e+00 4.2667e-01 9.5084e-02 1.8957e-02 5.0087e-02 -6.0000e+00 4.6070e-01 -1.3002e-01 1.6712e-02 1.9130e-02 -6.0000e+00 2.7459e-01 4.2855e-02 8.1816e-03 4.2970e-03 -6.0000e+00 1.1559e-01 1.2598e-04 -1.3574e-04 2.5513e-04 8.5305e-05 -6.0000e+00 8.1867e-03 -1.7480e-03 2.8996e-05 12 9 9 12 1 1 99.86 22.91 0.73 -0.00175 -0.00277 25 8 1 5 0 1627.230 26.83 20.01 22.91 28.43 10.3 1012.01 -95576 -115283 -64405 -37743 -28743 -107899 -61384 -145669 -103676 -107983 -31148 -46587 -77138 -75529 40620 -11709 18259 -800 -28544 -18727 12831 44264 4734 -27439 16339 24635 3589 7719 -21098 -15464 -16233 -1124 -1156 14135 -1054 10241 -15218 -8446 5117 5094 9668 -9085 5807 -664 -8492 307 1494 674 -11447 7373 -515 1622 -1867 2079 -4890 9470 4003 7174 4640 -1716 -1765 3613 3790 9103 3392 3753 2862 1043 794 5956 1012 1227 4457 -365 254 -3084 27 -1162 -3401 -2769 -3414 1601 -36 -760 108 417 -136 1106 1968 2792 -221 -2307 -4218 85 -1080 -1083 -2172 151 838 -1393 -1141 -1758 -1885 -4019 244 -1754 -1616 -856 639 1001 479 1202 1270 -1214 122 -1266 -843 57 1003 1108 1975 877 -79 2204 1636 -511 -649 -1082 408 -150 -91 -1039 -340 -630 291 -16 639 412 249 129 114 -750 -894 -1143 -1991 -727 -326 -229 -1648 -612 -4116 -2178 -2582 -361 -675 -1788 -2134 441 -254 331 -19 -972 -611 316 802 130 -1113 462 678 125 252 -887 -627 -741 -51 -60 686 -59 497 -1014 -612 393 469 967 -1185 686 -86 -1206 40 217 100 -1961 1093 -90 305 -397 459 -1227 2143 986 1721 1120 -435 -457 956 1118 2822 1173 1268 940 350 287 2321 461 591 2089 -172 111 -1256 10 -416 -1334 -1244 -1793 908 -23 -517 78 320 -111 924 1640 2245 -172 -1701 -2989 57 -800 -910 -2112 163 976 -1682 -1305 -1849 -1835 -3988 247 -1934 -1876 -1048 831 1427 749 1963 2072 -1952 183 -1823 -1203 84 1553 1803 3222 1415 -125 3282 2347 -719 -883 -1507 612 -251 -166 -2022 -686 -1344 654 -39 1558 1027 625 315 265 -1668 -1935 SS 20210812T110713.8Z 7894.463354 86 1 47.04 2 76.03 82.70 119.37 57.89 0.00 1 0.00 1 0 17 2.578e-01 8.112e-03 1.873e-01 3.995e-03 4.932944e-01 2.144034e-03 6.025853e-03 -6.000000e+00 1.527309e-01 232.11 -2.00 3.57 -2.00 320.62 0.00e+00 2.414508e-03 8.673216e-04 2.906413e-03 -6.000000e+00 6.795606e-03 288.35 -2.00 20.00 -2.00 319.93 0.00e+00 4.047 0.001 302.00 328.00 3 2.7717e+00 6.8473e-03 5.0095e-02 -6.0000e+00 3.8258e-01 1.5011e-03 8.7373e-03 3.1830e-02 -6.0000e+00 4.1308e-01 -1.7839e-02 7.7649e-03 1.5363e-02 -6.0000e+00 2.4621e-01 -2.9027e-03 3.8456e-03 3.9616e-03 -6.0000e+00 1.0365e-01 3.4165e-04 -1.3909e-04 1.2239e-04 6.9782e-05 -6.0000e+00 7.3404e-03 -1.9470e-03 2.8722e-05 11 8 0 10 0 0 98.44 22.92 0.52 -0.00195 -0.00299 64 18 1 5 0 734.950 26.83 19.98 22.92 28.87 10.3 1016.06 -90587 -29471 -44566 -54200 -31356 -48443 -27534 98683 -67626 66721 -92759 188274 -47858 1051 -42116 -1597 -19748 12481 -33845 3153 -31959 -8185 -25375 10425 -25153 8573 -17200 4427 2321 -1288 -17428 6390 1159 -2822 -12640 -1461 -6308 -2177 -6869 -2095 278 -2943 455 1891 -3654 -2682 -2296 5287 -443 -3035 3676 2544 1713 2760 2326 1701 887 100 640 -1894 3806 2781 3572 1919 3395 1372 1755 -403 2008 1889 1604 1566 2019 277 828 -1491 -1925 -1892 -1680 -1659 -1104 -1914 -1308 -2373 -911 -400 830 1465 1458 581 -44 638 -1141 -1225 -336 -364 -188 544 155 -329 -981 -1667 -1697 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