File name: Pandora184s1_CapeElizabethME_20220401_L2Fit_fout2c1d20211002p1-8.txt File generation date: 20260323T193835.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 184 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora184_OF_v5d20201127.txt Instrument calibration file used: Pandora184s1_CF_v1d20211002.txt Level 1 file used: Pandora184s1_CapeElizabethME_20220401_L1_smca1c1d20211002p1-8.txt.bz2 Full location name: CEPTL - Cape Elizabeth Two Lights (State Park) Maine Short location name: CapeElizabethME Country of location: United States Location latitude [deg]: 43.5610 Location longitude [deg]: -70.2073 Location altitude [m]: 24 Local noon date: 20220401 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0031 305.1442 305.2853 305.4263 305.5673 305.7084 305.8494 305.9904 306.1314 306.2724 306.4133 306.5543 306.6952 306.8362 306.9771 307.1180 307.2589 307.3998 307.5407 307.6816 307.8224 307.9633 308.1041 308.2450 308.3858 308.5266 308.6674 308.8082 308.9490 309.0897 309.2305 309.3712 309.5120 309.6527 309.7934 309.9341 310.0748 310.2155 310.3561 310.4968 310.6375 310.7781 310.9187 311.0593 311.1999 311.3405 311.4811 311.6217 311.7623 311.9028 312.0433 312.1839 312.3244 312.4649 312.6054 312.7459 312.8864 313.0268 313.1673 313.3077 313.4482 313.5886 313.7290 313.8694 314.0098 314.1502 314.2905 314.4309 314.5712 314.7116 314.8519 314.9922 315.1325 315.2728 315.4131 315.5533 315.6936 315.8338 315.9741 316.1143 316.2545 316.3947 316.5349 316.6751 316.8152 316.9554 317.0955 317.2357 317.3758 317.5159 317.6560 317.7961 317.9362 318.0763 318.2163 318.3564 318.4964 318.6364 318.7764 318.9164 319.0564 319.1964 319.3364 319.4763 319.6163 319.7562 319.8962 320.0361 320.1760 320.3159 320.4557 320.5956 320.7355 320.8753 321.0151 321.1550 321.2948 321.4346 321.5744 321.7142 321.8539 321.9937 322.1334 322.2732 322.4129 322.5526 322.6923 322.8320 322.9717 323.1113 323.2510 323.3906 323.5303 323.6699 323.8095 323.9491 324.0887 324.2282 324.3678 324.5074 324.6469 324.7864 324.9260 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220401T130616.9Z 8126.546028 126 1 2.90 2 61.69 112.64 66.67 110.31 0.00 1 0.00 1 0 17 1.629e-02 7.572e-03 6.189e-03 1.588e-03 3.206944e-01 8.148544e-04 3.858491e-03 -6.000000e+00 9.493013e-03 227.17 -2.00 3.57 -2.00 317.59 0.00e+00 1.196504e-03 1.266419e-04 2.304438e-04 -6.000000e+00 4.104984e-04 276.89 -2.00 20.00 -2.00 316.98 0.00e+00 2.098 0.000 302.00 328.00 3 1.6631e+00 2.1536e-03 2.6802e-02 -6.0000e+00 2.3591e-02 2.5096e-02 2.4222e-03 1.6573e-02 -6.0000e+00 2.5618e-02 -8.6596e-03 1.5063e-03 8.2312e-03 -6.0000e+00 1.5213e-02 -2.8282e-03 7.6131e-04 2.4998e-03 -6.0000e+00 6.4479e-03 8.1785e-03 7.3002e-05 4.6871e-05 2.7131e-05 -6.0000e+00 4.6650e-04 -2.5503e-03 5.4808e-05 12 9 1 12 1 1 99.84 22.58 0.38 -0.00255 -0.00200 29 143 1 5 0 90.990 26.62 20.00 22.58 15.14 15.4 1029.91 900000 1953 -3070 -2196 -5831 -4086 -6368 -32 -2675 -1400 -7475 -2816 -4738 -377 -64 899 61 385 1399 1638 1877 329 963 439 -388 -591 -873 -1714 -2916 -2347 -436 60 566 -1039 -3694 -4222 -3680 -2700 -576 -27 264 -672 248 291 1019 426 436 180 234 -287 616 1131 846 1038 1289 865 1025 388 149 322 351 1115 1870 1936 1244 -247 -852 -1045 -326 1148 779 1136 383 504 187 -409 -1466 -2224 -2116 -1582 -1560 -1244 -2035 -1524 -1288 -223 350 1102 952 1216 408 42 -782 -481 -663 -54 323 902 305 140 -533 -1044 -1184 -686 -600 -1299 -728 -502 -225 593 721 759 665 280 -146 -523 -273 -126 271 555 304 529 751 548 628 -41 -77 133 464 15 45 -566 -266 -433 200 203 236 358 364 -35 -157 -605 -919 900000 157 -275 -192 -483 -308 -498 -3 -249 -139 -807 -296 -560 -50 -10 156 12 76 289 351 414 74 217 104 -98 -143 -215 -453 -735 -574 -109 17 154 -306 -1089 -1200 -1088 -904 -226 -12 125 -343 131 156 546 230 234 96 122 -152 338 664 534 692 827 572 691 264 100 213 236 791 1437 1607 994 -206 -667 -792 -255 988 693 1066 366 468 164 -351 -1149 -1654 -1609 -1332 -1384 -1226 -2046 -1609 -1441 -265 410 1331 1161 1441 487 46 -797 -502 -673 -60 375 1158 399 185 -717 -1298 -1375 -795 -742 -1726 -950 -686 -324 855 1105 1197 1030 412 -211 -709 -363 -172 393 806 456 786 1083 807 880 -55 -105 180 624 22 65 -867 -417 -705 324 346 415 612 626 -63 -270 -1000 -1485 SS 20220401T151410.7Z 8126.634846 206 1 13.03 2 43.69 146.29 47.70 140.30 0.00 1 0.00 1 0 17 1.134e-02 7.782e-03 1.503e-03 7.186e-04 2.192514e-01 3.692584e-04 2.675178e-03 -6.000000e+00 6.605011e-03 227.18 -2.00 3.57 -2.00 316.31 0.00e+00 7.913187e-04 4.149928e-05 1.294513e-04 -6.000000e+00 2.855846e-04 276.90 -2.00 20.00 -2.00 315.73 0.00e+00 1.381 0.000 302.00 328.00 3 2.4088e+00 9.5764e-04 1.7905e-02 -6.0000e+00 1.6414e-02 2.6298e-02 1.0699e-03 1.1289e-02 -6.0000e+00 1.7824e-02 -5.6054e-03 6.2033e-04 5.5708e-03 -6.0000e+00 1.0584e-02 -4.1176e-03 2.8967e-04 1.6238e-03 -6.0000e+00 4.4867e-03 9.2353e-03 1.8077e-04 2.1331e-05 1.9116e-05 -6.0000e+00 3.2453e-04 -3.3721e-03 5.3762e-05 12 9 1 12 1 1 99.98 22.60 0.34 -0.00337 -0.00201 123 126 1 5 0 103.650 26.62 20.00 22.60 18.78 15.7 1060.30 900000 439 -165 -1581 -2710 -3303 -2490 -1181 286 -1832 -2344 -3242 -1382 -1013 642 699 166 793 1454 1594 2005 845 1301 1101 1064 642 480 -794 -1041 -770 308 655 975 -205 -3256 -3682 -3059 -2458 -696 -124 -443 -642 -297 -97 126 498 14 -184 -176 -559 280 774 843 1099 747 704 889 454 100 52 531 1254 1704 1842 1154 -232 -782 -918 -322 1133 765 1051 725 754 442 -278 -1283 -1890 -1946 -1221 -1550 -1192 -1992 -1744 -1101 -210 174 732 912 884 438 214 -712 -796 -446 -119 148 835 507 -29 -531 -1206 -1470 -732 -679 -1060 -767 -509 -190 592 840 846 751 290 -187 -323 -276 -119 415 561 555 476 670 587 615 190 -229 26 298 -30 148 -459 -348 -343 116 211 205 390 366 -51 -148 -607 -1031 900000 84 -33 -313 -490 -550 -412 -211 56 -392 -507 -704 -315 -259 183 221 56 273 513 579 676 316 485 387 393 247 187 -300 -404 -284 114 258 410 -83 -1443 -1560 -1340 -1104 -365 -76 -277 -426 -202 -67 87 340 10 -121 -113 -386 181 527 607 828 585 562 719 370 80 42 428 1060 1549 1645 1053 -203 -680 -759 -271 1045 722 1047 734 745 413 -257 -1078 -1483 -1535 -1047 -1495 -1169 -2118 -1943 -1293 -244 213 927 1164 1100 512 247 -753 -796 -455 -131 167 1034 674 -39 -680 -1437 -1778 -887 -819 -1370 -1034 -715 -260 848 1263 1295 1118 405 -259 -415 -347 -154 570 769 789 677 930 841 836 247 -283 32 378 -40 212 -632 -487 -496 176 336 317 615 583 -80 -241 -958 -1595 SS 20220401T155450.8Z 8126.663088 234 1 46.80 2 40.38 160.62 43.57 153.00 0.00 1 0.00 1 0 17 1.103e-02 7.569e-03 3.959e-04 1.781e-04 2.094625e-01 9.136001e-05 2.561307e-03 -6.000000e+00 6.429963e-03 227.18 -2.00 3.57 -2.00 316.53 0.00e+00 7.424489e-04 1.069414e-05 1.420535e-04 -6.000000e+00 2.780021e-04 276.91 -2.00 20.00 -2.00 315.93 0.00e+00 1.311 0.000 302.00 328.00 3 7.3734e-01 2.3765e-04 1.7055e-02 -6.0000e+00 1.5979e-02 2.2726e-02 2.6565e-04 1.0799e-02 -6.0000e+00 1.7352e-02 -4.6767e-03 1.5494e-04 5.3327e-03 -6.0000e+00 1.0304e-02 -4.7801e-03 7.3213e-05 1.5530e-03 -6.0000e+00 4.3680e-03 5.3668e-02 1.4869e-04 5.3299e-06 1.8673e-05 -6.0000e+00 3.1591e-04 -3.9569e-03 4.6414e-05 11 8 0 10 0 0 99.96 22.63 0.34 -0.00396 -0.00284 2329 649 1 5 0 19.910 26.73 20.00 22.63 19.85 16.1 1071.13 900000 447 -435 -1072 -3004 -2629 -2510 -577 -244 -929 -2884 -3062 -1849 -877 327 907 124 777 1114 1491 1703 892 1247 1076 930 637 359 -746 -915 -809 216 672 943 -230 -2987 -3697 -3227 -2342 -679 -335 -479 -682 -132 -166 187 339 145 -280 -369 -614 343 581 922 944 847 578 888 219 102 58 455 1016 1667 1784 1126 -297 -821 -1043 -261 1029 817 1012 810 806 484 -290 -1193 -1917 -1858 -1286 -1556 -1281 -1933 -1750 -1014 -236 166 794 883 917 446 161 -737 -679 -488 -149 84 888 509 -20 -582 -1215 -1445 -824 -758 -1149 -859 -501 -261 561 788 831 629 218 -232 -447 -185 -115 371 618 463 464 714 583 595 267 -249 79 372 53 136 -405 -333 -324 146 190 293 370 365 -112 -190 -668 -1050 900000 81 -83 -198 -510 -407 -388 -95 -45 -184 -584 -616 -392 -207 86 263 38 244 360 495 578 304 424 379 344 245 140 -281 -321 -270 72 238 356 -92 -1183 -1403 -1266 -1033 -349 -183 -292 -440 -87 -112 125 226 95 -179 -229 -375 213 382 638 684 635 442 688 171 78 44 352 825 1451 1652 1064 -268 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