File name: Pandora184s1_CapeElizabethME_20220409_L2Fit_fwvt1c1d20211002p1-8.txt File generation date: 20260323T194122.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 184 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora184_OF_v5d20201127.txt Instrument calibration file used: Pandora184s1_CF_v1d20211002.txt Level 1 file used: Pandora184s1_CapeElizabethME_20220409_L1_smca1c1d20211002p1-8.txt.bz2 Full location name: CEPTL - Cape Elizabeth Two Lights (State Park) Maine Short location name: CapeElizabethME Country of location: United States Location latitude [deg]: 43.5610 Location longitude [deg]: -70.2073 Location altitude [m]: 24 Local noon date: 20220409 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1613 1762 Nominal wavelengths inside fitting window [nm]: 492.0074 492.1289 492.2503 492.3718 492.4932 492.6146 492.7360 492.8573 492.9787 493.1000 493.2214 493.3427 493.4639 493.5852 493.7065 493.8277 493.9489 494.0701 494.1913 494.3125 494.4337 494.5548 494.6759 494.7970 494.9181 495.0392 495.1602 495.2813 495.4023 495.5233 495.6443 495.7653 495.8862 496.0072 496.1281 496.2490 496.3699 496.4908 496.6116 496.7325 496.8533 496.9741 497.0949 497.2157 497.3364 497.4572 497.5779 497.6986 497.8193 497.9400 498.0606 498.1813 498.3019 498.4225 498.5431 498.6637 498.7842 498.9048 499.0253 499.1458 499.2663 499.3868 499.5072 499.6277 499.7481 499.8685 499.9889 500.1093 500.2296 500.3500 500.4703 500.5906 500.7109 500.8312 500.9514 501.0717 501.1919 501.3121 501.4323 501.5525 501.6726 501.7928 501.9129 502.0330 502.1531 502.2732 502.3932 502.5133 502.6333 502.7533 502.8733 502.9933 503.1133 503.2332 503.3531 503.4730 503.5929 503.7128 503.8327 503.9525 504.0723 504.1921 504.3119 504.4317 504.5515 504.6712 504.7909 504.9106 505.0303 505.1500 505.2697 505.3893 505.5089 505.6285 505.7481 505.8677 505.9873 506.1068 506.2263 506.3458 506.4653 506.5848 506.7042 506.8237 506.9431 507.0625 507.1819 507.3013 507.4206 507.5400 507.6593 507.7786 507.8979 508.0172 508.1364 508.2557 508.3749 508.4941 508.6133 508.7324 508.8516 508.9707 509.0898 509.2090 509.3280 509.4471 509.5662 509.6852 509.8042 509.9232 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220409T103918.1Z 8134.443960 135 1 47.05 2 85.30 83.90 110.92 353.76 0.00 1 0.00 1 0 22 4.825e-03 4.778e-03 3.874e-04 3.869e-04 5.970226e+03 2.401677e+01 4.110174e+02 -6.000000e+00 2.583481e+02 277.77 -2.00 20.00 -2.00 505.33 0.00e+00 1.308915e-03 1.045697e-05 7.458349e-05 -6.000000e+00 1.328551e-04 277.77 -2.00 20.00 -2.00 500.64 0.00e+00 1.139620e+00 7.521798e-03 4.800139e-02 -6.000000e+00 9.518917e-02 227.79 -2.00 3.57 -2.00 502.21 0.00e+00 10.282 0.021 489.00 513.00 1 4.2545e+00 5.7395e-04 1.5651e-02 -6.0000e+00 7.2747e-03 -1.1485e-02 1.4767e-04 1.3846e-03 -6.0000e+00 1.9013e-03 5.7489e-03 6.4208e-04 3.4872e-05 5.7764e-05 -6.0000e+00 4.5257e-04 -2.8609e-03 3.6259e-05 12 8 8 10 0 0 99.85 22.49 1.60 -0.00286 0.00159 84 23 1 4 0 559.970 26.51 20.01 22.49 11.35 15.3 997.89 -1273 -1175 -852 -374 19 574 714 722 599 622 363 179 -224 -356 -537 -504 -203 150 47 169 238 242 308 518 530 498 593 231 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-178 -402 -112 -279 -320 -232 -192 -250 75 279 660 738 1221 1031 601 350 411 142 356 494 312 192 300 333 289 396 167 -164 -181 -345 -583 -221 -239 -226 -146 183 105 183 310 293 138 156 -143 -470 -564 -538 -572 SQ 20220409T105036.5Z 8134.451811 138 1 9.14 2 83.26 85.83 111.10 356.37 0.00 1 0.00 1 0 15 4.265e-03 4.234e-03 1.013e-03 1.012e-03 4.382650e+03 6.100298e+01 3.063599e+02 -6.000000e+00 2.283950e+02 277.77 -2.00 20.00 -2.00 505.30 0.00e+00 1.070777e-03 2.738118e-05 6.030139e-05 -6.000000e+00 1.174639e-04 277.77 -2.00 20.00 -2.00 500.56 0.00e+00 9.571151e-01 1.979788e-02 3.537820e-02 -6.000000e+00 8.421191e-02 227.79 -2.00 3.57 -2.00 502.14 0.00e+00 7.774 0.009 489.00 513.00 1 4.9873e+00 1.5116e-03 1.1674e-02 -6.0000e+00 6.4349e-03 -5.3128e-03 3.9056e-04 1.0210e-03 -6.0000e+00 1.6834e-03 4.0270e-03 1.5980e-03 9.1407e-05 4.5217e-05 -6.0000e+00 4.0002e-04 4.3622e-03 -6.8064e-05 12 9 1 12 1 1 92.37 22.50 1.31 0.00436 0.01545 8 13 1 4 0 995.830 26.51 19.99 22.50 11.30 15.3 998.20 -989 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-158 -167 -150 -283 -21 -381 -93 421 548 365 463 403 308 135 -223 -406 -551 -560 -515 -198 -204 -335 -34 -110 -292 1 -100 -87 120 360 297 579 1065 906 240 234 352 13 300 409 211 198 193 252 209 408 189 -289 -164 -308 -608 -160 -210 -333 -129 135 89 93 263 249 184 21 -43 -377 -273 -601 -244 SQ 20220409T110051.2Z 8134.458926 141 1 12.69 2 81.40 87.58 111.19 358.74 0.00 1 0.00 1 0 15 3.784e-03 3.760e-03 1.278e-04 1.277e-04 3.696887e+03 7.595933e+00 2.617552e+02 -6.000000e+00 2.026277e+02 277.78 -2.00 20.00 -2.00 505.29 0.00e+00 8.727196e-04 3.452672e-06 4.881981e-05 -6.000000e+00 1.042112e-04 277.78 -2.00 20.00 -2.00 500.54 0.00e+00 7.737985e-01 2.498215e-03 2.990486e-02 -6.000000e+00 7.471069e-02 227.79 -2.00 3.57 -2.00 502.12 0.00e+00 6.311 0.005 489.00 513.00 1 1.4569e+00 1.9082e-04 9.4698e-03 -6.0000e+00 5.7089e-03 -7.6681e-03 4.9338e-05 8.5278e-04 -6.0000e+00 1.4934e-03 1.7233e-01 1.4308e-03 1.1601e-05 3.8428e-05 -6.0000e+00 3.5489e-04 4.9122e-03 -7.1089e-05 12 1 1 12 1 1 56.35 22.50 1.30 0.00491 0.01484 521 163 1 4 0 23.790 26.51 20.00 22.50 11.79 15.5 1002.66 -950 -956 -638 -320 42 479 617 564 447 429 380 206 -172 -297 -438 -421 -118 67 35 44 217 252 304 469 464 483 529 235 -278 -414 -482 -556 -254 21 -76 -23 243 99 -10 -57 -16 39 187 291 426 436 473 445 205 -236 -525 -859 -889 -698 -462 -329 -111 24 148 293 429 501 462 448 414 288 220 85 -297 -395 -227 -221 -123 -64 -201 -312 -182 -231 -455 -529 -490 -591 -491 -246 -227 -227 -228 -71 -135 14 256 500 360 343 449 368 62 -238 -497 -641 -637 -398 -208 -250 -354 -232 -247 -270 -105 -58 -160 -26 238 381 600 784 741 443 401 289 181 282 475 222 145 267 305 315 479 99 -111 -98 -243 -493 -156 -96 -294 -138 132 52 133 227 259 186 81 -209 -415 -397 -385 -441 -907 -919 -609 -317 43 480 631 586 466 443 387 208 -171 -301 -441 -424 -116 68 36 45 222 258 311 481 478 499 546 241 -280 -417 -474 -547 -253 22 -79 -24 253 102 -10 -57 -16 39 191 301 444 458 493 459 209 -235 -526 -840 -857 -674 -457 -325 -113 24 152 299 438 513 476 461 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286 98 154 533 -458 -569 -779 231 -104 SQ 20220409T140516.2Z 8134.586993 259 1 6.58 2 49.59 124.51 100.91 38.73 0.00 1 0.00 1 0 15 5.471e-03 5.468e-03 3.777e-03 3.767e-03 1.368902e+03 2.120067e+02 1.134564e+02 -6.000000e+00 2.929996e+02 277.79 -2.00 20.00 -2.00 505.24 0.00e+00 3.710253e-04 1.014052e-04 1.657378e-05 -6.000000e+00 1.506756e-04 277.79 -2.00 20.00 -2.00 500.32 0.00e+00 1.309234e-01 7.426188e-02 8.013849e-03 -6.000000e+00 1.080068e-01 227.80 -2.00 3.57 -2.00 501.93 0.00e+00 1.540 0.000 489.00 513.00 1 7.5746e+00 5.6752e-03 2.3506e-03 -6.0000e+00 8.2534e-03 1.4219e-02 1.4812e-03 2.4882e-04 -6.0000e+00 2.1586e-03 7.9515e-04 1.4497e-03 3.4565e-04 1.6430e-05 -6.0000e+00 5.1312e-04 -1.2229e-03 -2.0091e-05 12 9 9 12 1 1 999.00 22.58 1.00 -0.00122 0.00883 1 4 1 4 0 3202.730 26.62 20.00 22.58 14.66 15.5 1025.27 -1257 -520 -1295 -46 -764 712 1145 535 481 692 556 -217 -395 -438 -868 -229 -291 27 32 584 -529 245 -12 498 350 278 506 692 316 -1005 -632 -1109 352 195 -464 -336 1147 -195 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