File name: Pandora184s1_CapeElizabethME_20220417_L2Fit_fout2c1d20211002p1-8.txt File generation date: 20260323T194043.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 184 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora184_OF_v5d20201127.txt Instrument calibration file used: Pandora184s1_CF_v1d20211002.txt Level 1 file used: Pandora184s1_CapeElizabethME_20220417_L1_smca1c1d20211002p1-8.txt.bz2 Full location name: CEPTL - Cape Elizabeth Two Lights (State Park) Maine Short location name: CapeElizabethME Country of location: United States Location latitude [deg]: 43.5610 Location longitude [deg]: -70.2073 Location altitude [m]: 24 Local noon date: 20220417 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0031 305.1442 305.2853 305.4263 305.5673 305.7084 305.8494 305.9904 306.1314 306.2724 306.4133 306.5543 306.6952 306.8362 306.9771 307.1180 307.2589 307.3998 307.5407 307.6816 307.8224 307.9633 308.1041 308.2450 308.3858 308.5266 308.6674 308.8082 308.9490 309.0897 309.2305 309.3712 309.5120 309.6527 309.7934 309.9341 310.0748 310.2155 310.3561 310.4968 310.6375 310.7781 310.9187 311.0593 311.1999 311.3405 311.4811 311.6217 311.7623 311.9028 312.0433 312.1839 312.3244 312.4649 312.6054 312.7459 312.8864 313.0268 313.1673 313.3077 313.4482 313.5886 313.7290 313.8694 314.0098 314.1502 314.2905 314.4309 314.5712 314.7116 314.8519 314.9922 315.1325 315.2728 315.4131 315.5533 315.6936 315.8338 315.9741 316.1143 316.2545 316.3947 316.5349 316.6751 316.8152 316.9554 317.0955 317.2357 317.3758 317.5159 317.6560 317.7961 317.9362 318.0763 318.2163 318.3564 318.4964 318.6364 318.7764 318.9164 319.0564 319.1964 319.3364 319.4763 319.6163 319.7562 319.8962 320.0361 320.1760 320.3159 320.4557 320.5956 320.7355 320.8753 321.0151 321.1550 321.2948 321.4346 321.5744 321.7142 321.8539 321.9937 322.1334 322.2732 322.4129 322.5526 322.6923 322.8320 322.9717 323.1113 323.2510 323.3906 323.5303 323.6699 323.8095 323.9491 324.0887 324.2282 324.3678 324.5074 324.6469 324.7864 324.9260 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220417T125245.4Z 8142.536637 306 1 10.40 2 58.98 106.03 116.30 276.60 0.00 1 0.00 1 0 17 2.451e-02 7.473e-03 1.147e-02 2.236e-03 3.435183e-01 1.144148e-03 4.120544e-03 -6.000000e+00 1.433162e-02 228.45 -2.00 3.57 -2.00 318.02 0.00e+00 1.238563e-03 2.009533e-04 3.999245e-04 -6.000000e+00 6.204504e-04 278.68 -2.00 20.00 -2.00 317.37 0.00e+00 1.933 0.000 302.00 328.00 3 3.5622e+00 3.0677e-03 2.6541e-02 -6.0000e+00 3.5700e-02 4.2379e-02 3.4683e-03 1.7862e-02 -6.0000e+00 3.8706e-02 -1.1077e-02 2.2315e-03 8.8901e-03 -6.0000e+00 2.3005e-02 -2.0420e-03 1.1444e-03 2.6535e-03 -6.0000e+00 9.6751e-03 1.3463e-03 -4.9351e-05 6.6285e-05 2.9047e-05 -6.0000e+00 6.9679e-04 4.5187e-04 -1.5375e-05 12 9 1 12 1 1 99.41 22.55 0.36 0.00045 0.00008 15 20 1 5 0 639.200 26.62 20.00 22.55 15.11 15.6 1026.27 -2061 -9828 -4951 -7880 -10083 -9227 -12007 -6137 294 -2336 -6472 -3947 -3192 -2074 2503 2811 -469 -432 317 2247 1659 3535 -1232 1636 -214 -1319 24 -243 -4020 -1016 -221 369 572 673 -3821 -4285 -3712 -2917 -720 -291 -1269 31 -479 360 165 907 845 163 150 -580 684 799 540 745 1310 899 1269 395 -147 -606 911 767 2252 2125 1346 -585 67 -1013 -230 1056 1151 900 844 23 824 -493 -1316 -2060 -1445 -1326 -1049 -1091 -1624 -1608 -948 -568 115 586 660 738 744 80 -609 -711 -479 -193 82 910 466 -236 -327 -1153 -1478 -789 -869 -1064 -837 -326 -318 670 885 1017 763 -83 -481 -552 -39 -57 306 343 396 471 894 605 694 504 -378 -14 230 131 -333 -368 -354 -332 0 237 280 668 459 -79 -264 -809 -852 -112 -662 -338 -545 -651 -549 -749 -399 20 -177 -523 -319 -285 -215 291 372 -70 -68 52 377 288 604 -223 302 -43 -279 5 -50 -811 -195 -44 81 139 174 -1005 -1088 -984 -879 -254 -110 -545 14 -226 172 79 435 403 77 71 -277 339 427 310 453 827 585 841 265 -97 -397 599 538 1559 1594 1048 -444 47 -700 -165 835 1008 835 790 21 699 -384 -934 -1520 -1091 -1025 -918 -1067 -1596 -1667 -1038 -663 131 688 779 913 860 85 -603 -735 -477 -212 100 1142 633 -325 -427 -1396 -1801 -957 -1047 -1368 -1124 -457 -471 984 1383 1637 1208 -125 -721 -777 -54 -81 461 511 605 711 1306 914 996 691 -499 -19 320 198 -502 -577 -569 -555 0 411 499 1210 838 -143 -456 -1345 -1471 SS 20220417T125639.6Z 8142.539348 309 1 22.46 2 58.30 106.83 116.99 277.27 0.00 1 0.00 1 0 17 2.043e-02 6.810e-03 3.919e-03 7.307e-04 3.363357e-01 3.732557e-04 4.041906e-03 -6.000000e+00 1.195280e-02 228.45 -2.00 3.57 -2.00 318.17 0.00e+00 1.182340e-03 6.838825e-05 4.066190e-04 -6.000000e+00 5.173067e-04 278.68 -2.00 20.00 -2.00 317.53 0.00e+00 1.896 0.000 302.00 328.00 3 2.0985e+00 1.0029e-03 2.6046e-02 -6.0000e+00 2.9774e-02 2.9922e-02 1.1363e-03 1.7548e-02 -6.0000e+00 3.2279e-02 -6.1618e-03 7.3931e-04 8.7283e-03 -6.0000e+00 1.9186e-02 -4.2964e-03 3.7985e-04 2.6040e-03 -6.0000e+00 8.0704e-03 6.1307e-03 2.1785e-05 2.1681e-05 2.7944e-05 -6.0000e+00 5.8095e-04 6.7689e-05 3.4760e-05 12 9 1 12 1 1 99.95 22.55 0.33 0.00007 0.00023 189 111 1 5 0 117.280 26.62 20.00 22.55 15.19 15.6 1027.55 -5413 -3296 -5208 -4919 -7680 -6707 -8859 -4898 -3502 -5022 -6846 -5337 -4865 -2219 -944 579 -680 272 710 1270 999 721 255 584 -10 116 -723 -1883 -2315 -1432 -820 -142 850 -221 -3536 -3962 -3660 -2532 -756 -284 -451 -419 20 89 277 825 544 111 -45 -355 738 963 1392 1297 1024 835 1059 154 141 30 422 1239 1838 2068 1430 -19 -455 -979 -4 1172 754 866 523 649 208 -457 -1078 -1771 -1659 -1228 -1424 -1150 -1785 -1611 -1033 -288 42 699 777 909 362 232 -717 -538 -402 -103 136 893 367 -108 -553 -1114 -1344 -617 -712 -1001 -819 -495 -211 514 689 730 579 161 -204 -350 -180 -16 396 557 265 340 820 627 609 247 -350 116 378 1 115 -458 -372 -296 74 158 223 325 423 -114 -82 -601 -852 -292 -200 -343 -318 -466 -375 -514 -302 -239 -376 -535 -420 -423 -220 -109 75 -96 40 110 205 166 121 43 104 -2 23 -147 -375 -437 -262 -157 -30 195 -54 -876 -948 -915 -717 -252 -111 -181 -180 9 40 126 373 246 50 -20 -159 344 482 744 735 608 510 659 97 88 18 262 811 1307 1587 1137 -15 -329 -690 -3 943 618 750 459 551 181 -363 -780 -1218 -1172 -964 -1272 -1048 -1774 -1686 -1142 -338 48 824 921 1047 426 251 -718 -518 -404 -113 167 1122 499 -148 -726 -1350 -1650 -753 -858 -1288 -1104 -699 -314 754 1075 1173 914 240 -305 -491 -247 -23 596 824 404 513 1288 950 878 340 -463 152 526 2 171 -713 -594 -491 129 291 395 585 766 -203 -149 -1061 -1466 SS 20220417T130117.6Z 8142.542565 312 1 46.84 2 57.50 107.78 117.80 278.08 0.00 1 0.00 1 0 17 2.270e-02 6.684e-03 1.481e-03 2.556e-04 3.280916e-01 1.313084e-04 3.958751e-03 -6.000000e+00 1.328099e-02 228.45 -2.00 3.57 -2.00 318.36 0.00e+00 1.235827e-03 2.493534e-05 4.520390e-04 -6.000000e+00 5.748067e-04 278.68 -2.00 20.00 -2.00 317.70 0.00e+00 1.854 0.000 302.00 328.00 3 5.5274e-01 3.5423e-04 2.5463e-02 -6.0000e+00 3.3083e-02 1.8759e-02 4.0186e-04 1.7151e-02 -6.0000e+00 3.5866e-02 -5.2864e-03 2.6499e-04 8.5888e-03 -6.0000e+00 2.1318e-02 -5.3678e-03 1.3694e-04 2.5986e-03 -6.0000e+00 8.9671e-03 3.0523e-02 2.5907e-05 7.6977e-06 2.8665e-05 -6.0000e+00 6.4552e-04 1.1357e-04 3.0747e-05 11 8 0 10 0 0 99.98 22.55 0.31 0.00011 0.00031 2103 586 1 5 0 22.080 26.62 20.00 22.55 15.44 15.8 1030.21 -6355 -4724 -4789 -5844 -8524 -8393 -8438 -6056 -5679 -5384 -7321 -7611 -4963 -2936 -1226 -29 -570 614 950 1290 1406 460 836 708 476 84 -548 -1704 -1867 -1748 -355 286 818 -413 -3175 -3927 -3510 -2496 -742 -482 -495 -657 -72 -35 413 685 514 61 -29 -351 705 853 1253 1105 1011 711 945 217 88 99 582 1237 1954 2099 1373 -34 -434 -629 27 1169 788 1005 622 656 290 -393 -1177 -1775 -1626 -1123 -1418 -1047 -1807 -1666 -1015 -246 137 782 851 927 464 230 -636 -570 -441 -173 20 790 408 -152 -651 -1216 -1384 -680 -724 -1116 -807 -471 -192 577 675 710 566 117 -225 -398 -85 -35 346 485 366 390 696 527 555 215 -298 122 305 -7 104 -420 -301 -328 117 121 267 370 381 -91 -129 -534 -817 -300 -251 -271 -329 -495 -452 -462 -357 -375 -382 -542 -577 -406 -275 -132 -4 -75 85 137 193 217 72 131 117 84 15 -103 -314 -325 -297 -63 55 172 -93 -721 -863 -805 -649 -227 -174 -200 -285 -32 -16 189 313 234 27 -13 -158 329 428 672 628 546 395 535 124 55 61 361 737 1262 1462 992 -24 -285 -400 18 849 637 858 538 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