File name: Pandora184s1_CapeElizabethME_20220523_L2Fit_fout2c1d20211002p1-8.txt File generation date: 20260323T194902.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 184 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora184_OF_v5d20201127.txt Instrument calibration file used: Pandora184s1_CF_v1d20211002.txt Level 1 file used: Pandora184s1_CapeElizabethME_20220523_L1_smca1c1d20211002p1-8.txt.bz2 Full location name: CEPTL - Cape Elizabeth Two Lights (State Park) Maine Short location name: CapeElizabethME Country of location: United States Location latitude [deg]: 43.5610 Location longitude [deg]: -70.2073 Location altitude [m]: 24 Local noon date: 20220523 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0031 305.1442 305.2853 305.4263 305.5673 305.7084 305.8494 305.9904 306.1314 306.2724 306.4133 306.5543 306.6952 306.8362 306.9771 307.1180 307.2589 307.3998 307.5407 307.6816 307.8224 307.9633 308.1041 308.2450 308.3858 308.5266 308.6674 308.8082 308.9490 309.0897 309.2305 309.3712 309.5120 309.6527 309.7934 309.9341 310.0748 310.2155 310.3561 310.4968 310.6375 310.7781 310.9187 311.0593 311.1999 311.3405 311.4811 311.6217 311.7623 311.9028 312.0433 312.1839 312.3244 312.4649 312.6054 312.7459 312.8864 313.0268 313.1673 313.3077 313.4482 313.5886 313.7290 313.8694 314.0098 314.1502 314.2905 314.4309 314.5712 314.7116 314.8519 314.9922 315.1325 315.2728 315.4131 315.5533 315.6936 315.8338 315.9741 316.1143 316.2545 316.3947 316.5349 316.6751 316.8152 316.9554 317.0955 317.2357 317.3758 317.5159 317.6560 317.7961 317.9362 318.0763 318.2163 318.3564 318.4964 318.6364 318.7764 318.9164 319.0564 319.1964 319.3364 319.4763 319.6163 319.7562 319.8962 320.0361 320.1760 320.3159 320.4557 320.5956 320.7355 320.8753 321.0151 321.1550 321.2948 321.4346 321.5744 321.7142 321.8539 321.9937 322.1334 322.2732 322.4129 322.5526 322.6923 322.8320 322.9717 323.1113 323.2510 323.3906 323.5303 323.6699 323.8095 323.9491 324.0887 324.2282 324.3678 324.5074 324.6469 324.7864 324.9260 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220523T101939.7Z 8178.430321 157 1 45.64 2 79.07 71.87 59.09 158.94 0.00 1 0.00 1 0 17 3.918e-01 9.759e-03 2.597e-01 5.536e-03 6.561630e-01 3.112986e-03 7.738097e-03 -6.000000e+00 2.329964e-01 231.50 -2.00 3.57 -2.00 321.38 0.00e+00 1.334339e-03 1.575109e-03 4.477651e-03 -6.000000e+00 1.051556e-02 282.65 -2.00 20.00 -2.00 320.84 0.00e+00 5.082 0.002 302.00 328.00 3 2.1892e+00 1.0955e-02 6.5864e-02 -6.0000e+00 5.8528e-01 9.2560e-02 1.5453e-02 4.6177e-02 -6.0000e+00 6.3367e-01 -1.1908e-01 1.5895e-02 2.3187e-02 -6.0000e+00 3.7485e-01 3.9724e-02 7.4281e-03 6.2585e-03 -6.0000e+00 1.5876e-01 1.8795e-04 1.2310e-04 1.6788e-04 1.2033e-04 -6.0000e+00 1.1405e-02 7.8630e-04 2.8906e-05 12 9 9 12 1 1 90.59 22.71 0.49 0.00079 0.00171 54 16 1 5 0 826.600 26.83 20.00 22.71 22.25 16.7 1069.23 900000 -199376 900000 -143807 11155 -187414 -56800 -148055 900000 -161827 28423 107660 900000 -72641 900000 -92471 -2746 -48330 1708 -35370 -48638 -26129 -48815 48768 2339 -56107 -44844 -64250 -321 -41698 -21150 -14878 -27109 3996 -18036 -32022 -13263 -19134 -21995 5107 -6222 -3671 -3947 -3050 -4548 8780 -3264 14238 -2133 9644 10321 10201 -60 15501 4216 10755 8994 10338 -972 7766 -3090 2359 3940 6695 -205 1987 -445 3655 -1051 3410 1087 3786 901 1832 -1832 -1302 -5843 -5193 -3579 -2844 -828 -1467 -1308 -2371 -1266 319 821 1628 194 784 545 -10 -1850 -787 -604 218 232 1017 418 -500 -101 -1892 -797 -1205 -908 -1490 10 -1065 304 334 1464 725 465 -601 -249 -942 -438 -634 273 578 1053 195 1423 936 446 -494 -1143 -324 83 -150 -285 -447 -523 -394 150 166 143 568 138 542 220 -431 -735 900000 -2061 900000 -970 60 -1769 -306 -1234 900000 -1984 153 581 900000 -677 900000 -1632 -23 -711 17 -538 -882 -384 -934 383 32 -1486 -1100 -1890 -5 -1002 -477 -379 -917 110 -619 -1240 -455 -816 -1186 255 -403 -254 -290 -230 -390 673 -289 1091 -201 864 1013 1128 -8 1973 646 1624 1436 1645 -170 1219 -550 430 799 1492 -53 500 -113 907 -297 1056 386 1389 342 660 -632 -403 -1746 -1529 -1131 -1046 -351 -721 -713 -1399 -789 209 566 1154 140 548 359 -6 -1115 -476 -400 165 203 1014 462 -569 -109 -1891 -720 -1076 -858 -1508 11 -1211 371 455 2188 1166 759 -966 -379 -1381 -636 -960 433 956 1737 314 2184 1395 642 -690 -1558 -450 127 -261 -546 -919 -1134 -824 333 388 346 1388 338 1284 494 -1009 -1669 SS 20220523T102537.5Z 8178.434462 160 1 46.77 2 78.04 72.83 58.71 160.54 0.00 1 0.00 1 0 17 2.871e-01 7.295e-03 1.938e-01 3.172e-03 6.125178e-01 1.740582e-03 7.206133e-03 -6.000000e+00 1.698246e-01 231.51 -2.00 3.57 -2.00 321.13 0.00e+00 2.675786e-03 8.197843e-04 3.363242e-03 -6.000000e+00 7.442723e-03 282.65 -2.00 20.00 -2.00 320.58 0.00e+00 4.678 0.002 302.00 328.00 3 1.6692e+00 5.8868e-03 5.9296e-02 -6.0000e+00 4.2559e-01 6.0475e-02 8.0799e-03 3.8818e-02 -6.0000e+00 4.6009e-01 -6.5483e-02 8.2007e-03 2.0962e-02 -6.0000e+00 2.7354e-01 1.5833e-02 3.9063e-03 6.5211e-03 -6.0000e+00 1.1534e-01 4.8220e-04 3.3877e-05 9.4778e-05 1.0968e-04 -6.0000e+00 8.1832e-03 7.0599e-04 5.8898e-07 11 8 0 10 0 0 53.42 22.70 0.35 0.00071 0.00096 140 39 1 5 0 334.030 26.83 20.00 22.70 22.15 16.7 1068.75 -144523 900000 -96885 6310 -68971 -90371 -120781 41783 -108966 -81287 -95680 -92425 -78622 -28776 6299 -15684 6935 4536 -14240 -26341 -26424 -29299 -9044 -24023 -24362 -20070 -15425 -22372 -21966 -30890 -12974 -23826 -13734 -11172 -10372 -12386 -12768 -9715 -4806 -696 3046 -3621 2293 2066 843 -948 1073 -237 -1264 1936 3323 3916 3618 2725 6496 3913 1220 3202 -272 -851 2449 2403 3336 1415 1051 1975 -333 -948 195 1374 1535 2485 930 1649 -956 -1592 -2039 -3945 -3855 -1803 -2156 -788 -2273 -787 -1293 57 -77 1044 1118 1392 571 -108 -1226 -590 -1018 -185 327 1324 715 110 -291 -1421 -1704 -1083 -367 -1202 -854 -356 124 548 1163 762 275 -77 -280 -791 -312 -821 750 463 478 432 712 676 200 -270 -969 -395 196 -251 -154 -570 -433 -644 -106 164 94 515 604 206 58 -421 -499 -968 900000 -549 20 -310 -483 -917 129 -950 -594 -861 -883 -796 -227 44 -168 68 51 -212 -474 -498 -577 -150 -500 -555 -468 -356 -547 -525 -842 -339 -831 -506 -443 -408 -487 -538 -464 -294 -49 240 -334 211 198 83 -98 111 -25 -143 225 418 549 562 465 1143 740 246 638 -55 -171 485 515 798 388 310 574 -97 -281 62 492 613 1044 399 674 -371 -562 -665 -1294 -1370 -732 -1030 -425 -1378 -503 -887 41 -59 819 882 1066 414 -74 -802 -386 -731 -151 306 1401 836 132 -334 -1499 -1652 -1030 -368 -1293 -966 -427 161 785 1827 1277 467 -128 -439 -1189 -464 -1276 1214 788 818 720 1139 1046 299 -389 -1359 -564 307 -444 -298 -1074 -856 -1351 -236 385 228 1260 1478 492 131 -903 -1037 SS 20220523T103103.6Z 8178.438237 163 1 46.90 2 77.10 73.70 58.38 162.01 0.00 1 0.00 1 0 17 2.226e-01 7.560e-03 9.479e-02 1.801e-03 5.736914e-01 9.825320e-04 6.808028e-03 -6.000000e+00 1.317180e-01 231.51 -2.00 3.57 -2.00 320.90 0.00e+00 2.959089e-03 4.248745e-04 2.965820e-03 -6.000000e+00 5.729971e-03 282.65 -2.00 20.00 -2.00 320.30 0.00e+00 4.360 0.002 302.00 328.00 3 1.1643e+00 3.1580e-03 5.4794e-02 -6.0000e+00 3.3010e-01 4.3685e-02 4.1619e-03 3.4917e-02 -6.0000e+00 3.5682e-01 -5.2703e-02 4.0682e-03 1.9007e-02 -6.0000e+00 2.1205e-01 1.2352e-02 1.9845e-03 6.1130e-03 -6.0000e+00 8.8973e-02 1.1283e-03 6.7800e-05 5.4468e-05 8.7300e-05 -6.0000e+00 6.3356e-03 3.2312e-04 2.9863e-05 11 8 0 10 0 0 81.62 22.70 0.37 0.00032 0.00083 240 67 1 5 0 195.400 26.83 20.00 22.70 22.16 16.7 1069.31 -15714 -77905 -52398 -84675 -64702 -43919 -67765 -58559 -82813 -71500 -79739 -59081 -67777 -34852 -43381 -7952 -21799 -18354 -28354 -7791 -20174 -5942 -26862 -14202 -28214 -14417 -28778 -17215 -24080 -15949 -19701 -2732 -11803 -3659 -14585 -8140 -17535 -3463 -8580 1446 -3197 3609 -3020 2856 330 5167 -77 1128 -527 2013 2357 2405 1706 4106 2334 1025 1875 567 724 334 1693 1611 3793 3668 2839 1188 222 -1208 589 1327 1668 1344 1603 810 314 -1773 -1764 -3816 -2787 -2316 -1008 -1160 -1319 -2169 -663 -344 722 1206 1584 1416 925 -118 -981 -1300 -792 -382 29 880 725 -17 -608 -1555 -1452 -1080 -810 -1003 -927 -290 -232 667 1005 904 439 88 -747 -724 -460 -152 395 642 431 727 627 866 229 111 -856 -36 -50 -7 -263 -567 -621 -341 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