File name: Pandora184s1_CapeElizabethME_20220804_L2Fit_fout2c1d20211002p1-8.txt File generation date: 20260323T200542.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 184 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora184_OF_v5d20201127.txt Instrument calibration file used: Pandora184s1_CF_v1d20211002.txt Level 1 file used: Pandora184s1_CapeElizabethME_20220804_L1_smca1c1d20211002p1-8.txt.bz2 Full location name: CEPTL - Cape Elizabeth Two Lights (State Park) Maine Short location name: CapeElizabethME Country of location: United States Location latitude [deg]: 43.5610 Location longitude [deg]: -70.2073 Location altitude [m]: 24 Local noon date: 20220804 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0031 305.1442 305.2853 305.4263 305.5673 305.7084 305.8494 305.9904 306.1314 306.2724 306.4133 306.5543 306.6952 306.8362 306.9771 307.1180 307.2589 307.3998 307.5407 307.6816 307.8224 307.9633 308.1041 308.2450 308.3858 308.5266 308.6674 308.8082 308.9490 309.0897 309.2305 309.3712 309.5120 309.6527 309.7934 309.9341 310.0748 310.2155 310.3561 310.4968 310.6375 310.7781 310.9187 311.0593 311.1999 311.3405 311.4811 311.6217 311.7623 311.9028 312.0433 312.1839 312.3244 312.4649 312.6054 312.7459 312.8864 313.0268 313.1673 313.3077 313.4482 313.5886 313.7290 313.8694 314.0098 314.1502 314.2905 314.4309 314.5712 314.7116 314.8519 314.9922 315.1325 315.2728 315.4131 315.5533 315.6936 315.8338 315.9741 316.1143 316.2545 316.3947 316.5349 316.6751 316.8152 316.9554 317.0955 317.2357 317.3758 317.5159 317.6560 317.7961 317.9362 318.0763 318.2163 318.3564 318.4964 318.6364 318.7764 318.9164 319.0564 319.1964 319.3364 319.4763 319.6163 319.7562 319.8962 320.0361 320.1760 320.3159 320.4557 320.5956 320.7355 320.8753 321.0151 321.1550 321.2948 321.4346 321.5744 321.7142 321.8539 321.9937 322.1334 322.2732 322.4129 322.5526 322.6923 322.8320 322.9717 323.1113 323.2510 323.3906 323.5303 323.6699 323.8095 323.9491 324.0887 324.2282 324.3678 324.5074 324.6469 324.7864 324.9260 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220804T104305.3Z 8251.446589 78 1 46.38 2 78.95 76.74 144.12 26.52 0.00 1 0.00 1 0 17 4.202e-01 1.122e-02 2.213e-01 3.878e-03 6.054043e-01 2.144216e-03 7.419937e-03 -6.000000e+00 2.497750e-01 232.41 -2.00 3.57 -2.00 321.34 0.00e+00 4.600843e-03 1.093270e-03 4.461303e-03 -6.000000e+00 1.133037e-02 288.18 -2.00 20.00 -2.00 320.72 0.00e+00 5.027 0.002 302.00 328.00 3 1.5961e+00 7.6946e-03 6.3371e-02 -6.0000e+00 6.2752e-01 9.5506e-02 1.0461e-02 4.2135e-02 -6.0000e+00 6.7764e-01 -1.9224e-01 9.8886e-03 2.1538e-02 -6.0000e+00 4.0251e-01 7.3011e-02 4.6594e-03 6.0868e-03 -6.0000e+00 1.6940e-01 3.8758e-04 -2.4374e-04 1.1799e-04 1.2447e-04 -6.0000e+00 1.1963e-02 -4.5575e-04 -8.7404e-06 12 8 8 10 0 0 37.04 22.60 0.40 -0.00046 -0.00229 143 40 1 5 0 324.250 26.73 20.01 22.60 26.72 19.0 1039.67 -189260 72211 -150364 83625 -167583 99673 -180937 2537 -139943 900000 -133513 -8648 -152124 4196 -106896 42087 -70692 56826 -47282 14414 -28158 29640 -51138 37630 -40361 -8481 -29675 -7126 -27888 -21098 -26110 -12830 7950 5751 -11271 -17313 -1165 -7847 11458 506 13460 3029 8311 -2265 7485 776 8629 -1076 12157 175 10748 905 9485 249 11146 1546 5070 257 7150 -76 5663 517 8477 3141 5735 -37 2413 -1979 3232 786 5207 1378 3363 -187 591 -883 -2318 -5767 -2469 -2754 -1778 -586 -1118 -2428 -1130 759 1097 2473 919 1888 170 -130 -2297 -458 -2436 -158 -684 1047 -68 110 -1294 -695 -3029 -807 -2124 -1419 -1915 239 -509 687 336 974 104 445 -1067 -210 -817 106 48 636 17 1244 1028 1193 683 260 -546 32 370 -7 -112 -384 -300 -372 298 72 263 409 526 22 -146 -681 -601 -2683 273 -1942 316 -2429 377 -2907 10 -2020 900000 -2065 -42 -3712 27 -2682 289 -1725 430 -1105 193 -600 357 -1406 453 -1138 -184 -816 -154 -728 -537 -799 -410 240 196 -453 -720 -44 -364 532 31 842 229 631 -199 668 69 796 -112 1154 20 1195 124 1312 41 1757 280 914 49 1249 -14 1011 105 1795 789 1503 -10 634 -550 919 261 1852 541 1303 -72 209 -287 -704 -1786 -801 -1045 -784 -293 -622 -1465 -719 507 774 1786 680 1350 117 -83 -1429 -281 -1664 -121 -609 1049 -76 125 -1425 -695 -2845 -731 -2074 -1468 -2105 275 -640 949 514 1577 171 710 -1640 -306 -1190 159 76 1060 29 2028 1623 1818 1006 370 -757 45 574 -12 -216 -792 -650 -853 659 170 635 1005 1295 53 -334 -1628 -1388 SS 20220804T104859.0Z 8251.450683 81 1 46.03 2 77.91 77.71 143.67 28.75 0.00 1 0.00 1 0 17 3.213e-01 8.369e-03 1.208e-01 2.779e-03 5.634107e-01 1.518356e-03 6.800574e-03 -6.000000e+00 1.907958e-01 232.41 -2.00 3.57 -2.00 321.07 0.00e+00 3.506472e-03 7.120435e-04 3.330828e-03 -6.000000e+00 8.464646e-03 288.18 -2.00 20.00 -2.00 320.44 0.00e+00 4.628 0.002 302.00 328.00 3 1.5263e+00 5.1926e-03 5.7416e-02 -6.0000e+00 4.7833e-01 2.8505e-02 6.9313e-03 3.6467e-02 -6.0000e+00 5.1614e-01 -1.0559e-01 6.4812e-03 1.8634e-02 -6.0000e+00 3.0754e-01 3.8529e-02 3.1091e-03 5.2786e-03 -6.0000e+00 1.2954e-01 6.4082e-04 -3.8125e-04 8.4313e-05 9.5759e-05 -6.0000e+00 9.1477e-03 -1.1459e-03 5.0046e-06 11 8 0 10 0 0 34.01 22.60 0.40 -0.00115 -0.00401 190 53 1 5 0 242.210 26.73 20.00 22.60 27.19 18.9 1043.93 -21105 -120856 -32229 -106897 -96605 -127448 -78442 -135329 -96809 -97777 -90673 -104260 -74764 -73748 -49677 -45559 -30817 -50213 -13420 -31416 -392 -20054 -23866 -24927 -21705 -15681 -16065 -13067 -22274 -12373 -20071 -4114 -16709 695 -35 -1452 -300 -3044 1917 1541 2808 8457 2650 7908 2980 8274 1060 6023 -1396 5296 1044 5936 508 6349 2362 3967 2 801 593 -1466 -2152 1455 1221 3247 2167 1256 -324 451 164 1780 505 2503 412 746 155 -1002 -3075 -3071 -3128 -2257 -998 -1562 -1012 -1119 388 401 829 1460 2311 1473 1247 -71 -384 -1475 -934 -793 21 558 580 -284 -833 -1877 -1901 -1515 -1522 -1966 -971 -482 -115 537 784 746 587 -47 -305 -665 -147 -286 146 365 353 566 1195 523 578 107 -819 -17 391 -245 123 -374 -326 -372 12 117 216 421 261 95 -79 -367 -692 -67 -1256 -153 -1185 -904 -1539 -599 -2034 -1121 -1253 -1139 -1618 -1032 -1272 -844 -898 -600 -1311 -264 -789 -8 -474 -600 -676 -615 -444 -471 -367 -669 -347 -687 -142 -757 29 -1 -60 -13 -158 127 123 254 788 277 814 329 883 124 686 -177 659 147 888 88 1129 466 804 1 175 128 -318 -479 337 319 929 669 388 -99 137 54 651 210 1083 184 320 62 -368 -1058 -1033 -1129 -936 -478 -859 -612 -725 264 293 639 1162 1840 1155 923 -50 -254 -984 -671 -649 19 591 674 -341 -959 -1997 -1861 -1461 -1560 -2162 -1116 -587 -150 774 1238 1250 993 -77 -475 -990 -217 -438 235 621 609 952 1932 823 873 156 -1164 -24 613 -432 236 -768 -637 -768 27 271 517 1023 640 228 -181 -793 -1454 SS 20220804T105425.1Z 8251.454457 84 1 45.84 2 76.94 78.60 143.22 30.76 0.00 1 0.00 1 0 17 1.601e-01 7.731e-03 1.008e-01 2.037e-03 5.321720e-01 1.099408e-03 6.235264e-03 -6.000000e+00 9.514060e-02 232.41 -2.00 3.57 -2.00 320.86 0.00e+00 2.088403e-03 4.828485e-04 2.478608e-03 -6.000000e+00 4.229911e-03 288.18 -2.00 20.00 -2.00 320.19 0.00e+00 4.311 0.001 302.00 328.00 3 1.4048e+00 3.6255e-03 5.2891e-02 -6.0000e+00 2.3852e-01 -3.9875e-03 4.7484e-03 3.2337e-02 -6.0000e+00 2.5750e-01 -5.3686e-02 4.3819e-03 1.6211e-02 -6.0000e+00 1.5329e-01 1.5590e-02 2.1374e-03 4.4918e-03 -6.0000e+00 6.4929e-02 1.0210e-03 -1.0797e-04 6.2087e-05 6.6006e-05 -6.0000e+00 4.5932e-03 -1.8048e-03 3.2461e-05 11 8 0 10 0 0 29.21 22.60 0.45 -0.00180 -0.00262 246 69 1 5 0 186.310 26.73 19.98 22.60 27.73 18.9 1047.54 900000 9113 -67740 2997 -62338 -50552 -4835 -49712 12384 -47200 -43672 -54790 -6305 -47092 -19804 -44185 -14627 -32728 -17191 -32777 -11590 -29936 -21360 -28122 -9779 -24565 -6432 -29780 -14729 -28346 -15057 -16506 -3943 -12773 -7672 -18687 -5252 -9516 -878 -1744 3175 -1122 4258 565 5367 3097 4112 1208 5205 2123 3128 3690 3536 3094 3720 3074 2487 604 395 1263 -692 1348 2436 3581 1383 1728 -781 952 -147 1846 708 1659 -309 1287 -1328 -705 -3417 -3274 -3541 -1473 -2669 -1148 -2383 -1405 -1019 411 423 1720 1583 1508 444 786 -693 -901 -987 -282 -238 997 470 -53 -673 -1316 -1470 -944 -911 -1113 -710 -627 202 724 981 863 833 -39 -225 -759 -384 -369 295 -27 640 307 963 392 511 -373 -583 -573 267 -238 99 -637 -288 -501 245 -45 369 333 581 23 -30 -454 -532 900000 35 -561 14 -506 -347 -22 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