File name: Pandora184s1_CapeElizabethME_20220925_L2Fit_fout2c1d20211002p1-8.txt File generation date: 20260323T201719.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 184 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora184_OF_v5d20201127.txt Instrument calibration file used: Pandora184s1_CF_v1d20211002.txt Level 1 file used: Pandora184s1_CapeElizabethME_20220925_L1_smca1c1d20211002p1-8.txt.bz2 Full location name: CEPTL - Cape Elizabeth Two Lights (State Park) Maine Short location name: CapeElizabethME Country of location: United States Location latitude [deg]: 43.5610 Location longitude [deg]: -70.2073 Location altitude [m]: 24 Local noon date: 20220925 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0031 305.1442 305.2853 305.4263 305.5673 305.7084 305.8494 305.9904 306.1314 306.2724 306.4133 306.5543 306.6952 306.8362 306.9771 307.1180 307.2589 307.3998 307.5407 307.6816 307.8224 307.9633 308.1041 308.2450 308.3858 308.5266 308.6674 308.8082 308.9490 309.0897 309.2305 309.3712 309.5120 309.6527 309.7934 309.9341 310.0748 310.2155 310.3561 310.4968 310.6375 310.7781 310.9187 311.0593 311.1999 311.3405 311.4811 311.6217 311.7623 311.9028 312.0433 312.1839 312.3244 312.4649 312.6054 312.7459 312.8864 313.0268 313.1673 313.3077 313.4482 313.5886 313.7290 313.8694 314.0098 314.1502 314.2905 314.4309 314.5712 314.7116 314.8519 314.9922 315.1325 315.2728 315.4131 315.5533 315.6936 315.8338 315.9741 316.1143 316.2545 316.3947 316.5349 316.6751 316.8152 316.9554 317.0955 317.2357 317.3758 317.5159 317.6560 317.7961 317.9362 318.0763 318.2163 318.3564 318.4964 318.6364 318.7764 318.9164 319.0564 319.1964 319.3364 319.4763 319.6163 319.7562 319.8962 320.0361 320.1760 320.3159 320.4557 320.5956 320.7355 320.8753 321.0151 321.1550 321.2948 321.4346 321.5744 321.7142 321.8539 321.9937 322.1334 322.2732 322.4129 322.5526 322.6923 322.8320 322.9717 323.1113 323.2510 323.3906 323.5303 323.6699 323.8095 323.9491 324.0887 324.2282 324.3678 324.5074 324.6469 324.7864 324.9260 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220925T110411.4Z 8303.461243 60 1 47.59 2 84.93 96.16 79.46 94.47 0.00 1 0.00 1 0 25 6.233e-01 8.566e-02 5.060e-01 6.965e-02 9.822800e-01 4.170972e-02 1.113318e-02 -6.000000e+00 3.731552e-01 227.97 -2.00 3.57 -2.00 321.82 0.00e+00 -6.498727e-03 1.252937e-02 4.743536e-03 -6.000000e+00 1.800683e-02 284.68 -2.00 20.00 -2.00 321.13 0.00e+00 9.708 0.018 302.00 328.00 3 -1.4336e-01 1.3195e-01 1.1463e-01 -6.0000e+00 9.3002e-01 2.4055e+00 1.5382e-01 6.7523e-02 -6.0000e+00 1.0124e+00 -2.2022e+00 8.8604e-02 2.5443e-02 -6.0000e+00 6.0272e-01 6.6871e-01 5.0403e-02 1.1314e-02 -6.0000e+00 2.5825e-01 1.0140e-05 -6.2268e-04 1.9132e-03 1.1474e-04 -6.0000e+00 1.8077e-02 -2.5233e-03 3.0466e-05 12 8 8 10 0 0 91.58 22.28 0.96 -0.00252 -0.00720 30 8 1 5 0 1586.180 26.41 19.99 22.28 18.47 19.8 966.08 900000 900000 38058 -2201 93859 173424 -22977 117666 102564 900000 -34683 900000 -36148 124730 28067 326956 54344 900000 -38418 900000 -36083 66230 -29615 900000 -34453 195343 50575 176914 -72948 12906 58464 900000 38587 -23737 -19248 39618 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5901 7840 6134 7722 -10936 8570 -9450 8069 5823 3071 233 8372 -10942 -2517 -6995 7219 -11398 4180 -10820 8981 13686 13693 10540 10165 6392 1991 12035 2629 5625 -924 8957 6550 -5917 9314 5370 5710 247 -14523 6849 -10510 -9419 -14421 1385 -6661 14397 -5387 9645 -10334 19535 -6291 2498 -11526 10533 -3697 6028 -6853 17899 -14633 17533 -5209 12636 -13785 17446 -4614 1845 -7106 -1707 1881 -1589 -2166 -9555 -8316 11533 1052 9094 1567 710 2489 -12585 5057 SS 20220925T111720.7Z 8303.470378 63 1 19.37 2 82.57 98.46 77.18 96.76 0.00 1 0.00 1 0 17 5.965e-01 2.449e-02 3.978e-01 1.346e-02 8.170868e-01 7.915848e-03 9.534030e-03 -6.000000e+00 3.529382e-01 227.97 -2.00 3.57 -2.00 322.09 0.00e+00 1.001207e-02 4.761956e-03 2.563968e-03 -6.000000e+00 1.636080e-02 284.68 -2.00 20.00 -2.00 321.60 0.00e+00 7.153 0.007 302.00 328.00 3 8.0652e-01 3.1797e-02 8.4709e-02 -6.0000e+00 8.7941e-01 7.4826e-01 4.4103e-02 4.7251e-02 -6.0000e+00 9.5601e-01 -9.9791e-01 3.9904e-02 2.6415e-02 -6.0000e+00 5.6537e-01 3.9671e-01 1.8112e-02 1.2532e-02 -6.0000e+00 2.4186e-01 8.3480e-05 -9.3484e-04 3.9332e-04 2.0938e-04 -6.0000e+00 1.7776e-02 -4.7063e-03 3.5282e-05 12 9 9 12 1 1 83.96 22.30 0.58 -0.00471 -0.01173 26 18 1 5 0 711.070 26.41 19.99 22.30 19.59 19.5 972.79 900000 -161575 -122396 -173390 -107892 18534 -147457 -192834 900000 -178370 -108659 -202524 900000 -144641 15985 -63352 65977 -59007 100209 15268 6550 900000 76229 16717 900000 259491 -18694 -1397 -100008 900000 900000 900000 -28002 21735 -10003 900000 -21325 900000 -21271 138692 -10489 106525 5758 80105 444 167090 -4089 121791 28808 21423 4241 31633 3998 37939 1408 41595 13072 37090 2132 4506 15540 6613 18415 21203 27379 17031 16390 16573 16390 7976 16914 12010 21121 11090 9642 2216 11741 -2009 16044 -7204 11834 4239 9853 -3021 9442 24 6470 -1517 7243 -2329 4790 -4048 2197 -6597 -3313 -4403 946 -5818 1491 -4691 -1613 -4100 -1909 -3930 -1604 -5373 -2393 -4159 -1105 -2852 -809 -565 -316 21 -63 -501 -825 -75 -711 904 591 1960 1668 3468 2199 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6.753141e-03 -6.000000e+00 1.427775e-01 227.96 -2.00 3.57 -2.00 320.67 0.00e+00 3.688178e-03 7.747482e-04 2.893459e-03 -6.000000e+00 6.354772e-03 284.68 -2.00 20.00 -2.00 320.04 0.00e+00 4.369 0.002 302.00 328.00 3 1.8523e+00 6.0048e-03 5.3914e-02 -6.0000e+00 3.5453e-01 8.1720e-02 7.7114e-03 3.3329e-02 -6.0000e+00 3.8421e-01 -8.2060e-02 7.1364e-03 1.7930e-02 -6.0000e+00 2.2908e-01 2.4648e-02 3.5221e-03 5.7874e-03 -6.0000e+00 9.7658e-02 5.7312e-04 -2.7842e-04 1.0558e-04 9.4415e-05 -6.0000e+00 6.9950e-03 -4.2442e-03 4.7121e-05 12 9 1 12 1 1 99.92 22.33 0.26 -0.00424 -0.00634 45 37 1 5 0 359.230 26.41 20.00 22.33 20.47 19.5 978.80 900000 -112056 -99319 -39223 -27553 -94854 -80718 -60778 -48467 -96218 -94786 -71720 -38135 -44770 -29119 -31648 -18028 -12165 -24034 -31076 -5877 -20178 -23152 -1388 -19514 7675 -21989 -17658 -20966 -7878 -11129 -5568 -17496 982 -7389 -3085 -2367 -3774 -4912 3409 559 2350 3469 2512 1394 1149 4244 2257 1002 2880 1942 1776 4323 1826 3037 1788 2200 904 -227 -1154 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