File name: Pandora184s1_CapeElizabethME_20221006_L2Fit_fout2c1d20211002p1-8.txt File generation date: 20260323T201928.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 184 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora184_OF_v5d20201127.txt Instrument calibration file used: Pandora184s1_CF_v1d20211002.txt Level 1 file used: Pandora184s1_CapeElizabethME_20221006_L1_smca1c1d20211002p1-8.txt.bz2 Full location name: CEPTL - Cape Elizabeth Two Lights (State Park) Maine Short location name: CapeElizabethME Country of location: United States Location latitude [deg]: 43.5610 Location longitude [deg]: -70.2073 Location altitude [m]: 24 Local noon date: 20221006 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0031 305.1442 305.2853 305.4263 305.5673 305.7084 305.8494 305.9904 306.1314 306.2724 306.4133 306.5543 306.6952 306.8362 306.9771 307.1180 307.2589 307.3998 307.5407 307.6816 307.8224 307.9633 308.1041 308.2450 308.3858 308.5266 308.6674 308.8082 308.9490 309.0897 309.2305 309.3712 309.5120 309.6527 309.7934 309.9341 310.0748 310.2155 310.3561 310.4968 310.6375 310.7781 310.9187 311.0593 311.1999 311.3405 311.4811 311.6217 311.7623 311.9028 312.0433 312.1839 312.3244 312.4649 312.6054 312.7459 312.8864 313.0268 313.1673 313.3077 313.4482 313.5886 313.7290 313.8694 314.0098 314.1502 314.2905 314.4309 314.5712 314.7116 314.8519 314.9922 315.1325 315.2728 315.4131 315.5533 315.6936 315.8338 315.9741 316.1143 316.2545 316.3947 316.5349 316.6751 316.8152 316.9554 317.0955 317.2357 317.3758 317.5159 317.6560 317.7961 317.9362 318.0763 318.2163 318.3564 318.4964 318.6364 318.7764 318.9164 319.0564 319.1964 319.3364 319.4763 319.6163 319.7562 319.8962 320.0361 320.1760 320.3159 320.4557 320.5956 320.7355 320.8753 321.0151 321.1550 321.2948 321.4346 321.5744 321.7142 321.8539 321.9937 322.1334 322.2732 322.4129 322.5526 322.6923 322.8320 322.9717 323.1113 323.2510 323.3906 323.5303 323.6699 323.8095 323.9491 324.0887 324.2282 324.3678 324.5074 324.6469 324.7864 324.9260 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221006T111602.5Z 8314.469474 130 1 47.67 2 85.15 101.92 137.95 296.90 0.00 1 0.00 1 0 17 6.935e-01 1.008e-01 5.530e-01 8.703e-02 8.879342e-01 5.124946e-02 1.015538e-02 -6.000000e+00 4.160428e-01 226.64 -2.00 3.57 -2.00 321.52 0.00e+00 -1.963292e-02 1.253057e-02 2.331274e-03 -6.000000e+00 1.933483e-02 283.32 -2.00 20.00 -2.00 320.75 0.00e+00 10.030 0.019 302.00 328.00 3 1.9192e-01 1.4910e-01 1.1434e-01 -6.0000e+00 1.0327e+00 2.1772e+00 1.7423e-01 6.6521e-02 -6.0000e+00 1.1221e+00 -2.2088e+00 1.0314e-01 2.1817e-02 -6.0000e+00 6.6527e-01 7.0769e-01 5.7253e-02 1.7156e-02 -6.0000e+00 2.8549e-01 7.4431e-06 4.1324e-03 2.5754e-03 2.2336e-04 -6.0000e+00 2.0616e-02 -4.3270e-03 9.8602e-05 12 8 8 10 0 0 54.29 22.35 1.31 -0.00433 0.02673 22 6 1 5 0 2166.480 26.41 20.00 22.35 20.10 20.0 982.21 900000 113328 900000 14665 104855 39243 900000 250592 900000 -58401 98469 38450 900000 52670 900000 87778 123725 10699 900000 -47711 180921 200740 32160 34044 105928 56365 181047 39547 900000 -69397 41387 -19332 296056 65819 56548 -88224 31387 182381 15241 20627 -2813 46590 123713 115558 79 900000 -23129 87672 900000 59714 -2266 900000 65581 64200 -19568 900000 24428 155209 3553 66616 114646 150709 -38179 45971 15451 170040 -59905 28314 37452 -15073 18444 144581 5349 -11639 -29266 -50202 3634 4277 -1421 -16993 -23048 -9348 12133 -1482 45548 26259 10139 -1657 46806 33504 -3190 3520 24379 -30343 14374 -435 16329 -14633 20419 -9672 -6881 13990 55529 -10061 28112 -564 7837 -9359 21195 -5699 18824 6893 77 55 16120 5177 -4067 -8271 -456 -8602 9601 12895 -11733 -3719 -311 -6861 -7216 10395 -7120 4077 -2309 20 652 4320 -4772 2756 -3641 2236 2181 -1722 -4076 5906 2412 900000 10334 900000 2897 8879 4154 900000 21219 900000 -20192 8338 4884 900000 6318 900000 8052 10476 2038 900000 -14476 15319 16998 3631 4084 8969 5966 15330 3907 900000 -15670 3504 -3001 25068 5573 4788 -26486 2899 15443 2229 3334 -628 6455 10475 9785 14 900000 -4451 7424 900000 5056 -384 900000 6563 6919 -5121 900000 4325 13142 684 6153 9708 12761 -10580 6016 2854 14398 -22595 4577 6054 -4641 4401 12242 1441 -3405 -9011 -16617 643 757 -295 -4840 -8161 -3310 3829 -571 11570 8490 3980 -814 13871 10780 -1378 1341 7431 -16957 5842 -240 8849 -12391 13313 -8599 -5593 8292 19748 -6816 13806 -391 5309 -8163 15255 -6176 18171 8171 101 72 17335 6049 -5268 -11695 -629 -13257 12113 15067 -16889 -4818 -380 -8715 -9104 11795 -11153 6629 -4516 41 1464 10133 -13254 7514 -10883 6398 6205 -4870 -11009 13502 5556 SS 20221006T112835.0Z 8314.478183 133 1 46.78 2 82.94 104.13 139.82 300.20 0.00 1 0.00 1 0 17 4.898e-01 1.845e-02 3.787e-01 1.264e-02 8.307640e-01 7.402693e-03 9.213288e-03 -6.000000e+00 2.857467e-01 226.64 -2.00 3.57 -2.00 322.26 0.00e+00 7.695684e-03 4.647519e-03 3.255219e-03 -6.000000e+00 1.369372e-02 283.31 -2.00 20.00 -2.00 321.81 0.00e+00 7.469 0.008 302.00 328.00 3 5.4362e-01 3.0891e-02 9.2405e-02 -6.0000e+00 7.0937e-01 8.2284e-01 4.2447e-02 6.4732e-02 -6.0000e+00 7.7034e-01 -1.1794e+00 3.8795e-02 2.5892e-02 -6.0000e+00 4.5877e-01 4.8450e-01 1.7640e-02 1.2715e-02 -6.0000e+00 1.9628e-01 8.1878e-05 -1.0777e-03 3.7718e-04 1.5360e-04 -6.0000e+00 1.4345e-02 -2.5472e-03 7.9965e-06 12 8 8 10 0 0 51.11 22.36 0.42 -0.00255 -0.01065 94 26 1 5 0 497.620 26.41 20.00 22.36 21.42 19.9 991.56 -114198 900000 -82198 86685 -87920 -9697 -161910 -64976 -130930 900000 -78764 900000 -110742 57895 -6082 900000 -59673 32964 -17816 -25669 -39895 -72120 -45104 -65483 -19398 -68883 -20502 -43481 -38733 -68841 -14465 -16121 85422 50161 17343 -60538 131166 -10130 900000 9809 50003 53008 280162 45158 78063 18277 99107 -2415 79299 29124 127720 38501 63272 25749 65373 25764 61717 1412 36630 8188 34075 23158 17173 -2838 21056 8722 13185 11132 15392 5283 4772 8220 4919 8508 -58 -2266 -7044 6655 -8570 -3208 -3623 2581 -1926 2396 -1094 1791 665 5320 958 5588 -1073 1013 -2583 4972 -6332 1494 -2411 2460 -1674 1409 -859 -1221 -7316 1258 -3818 -531 -2266 -753 -3331 924 -1862 369 -1812 830 -841 -410 -2372 -732 -299 -323 1420 1696 3136 1669 1255 1358 -546 -203 775 1005 1160 -169 -178 -203 350 -509 633 220 776 193 -172 -1272 -1549 -2226 900000 -1434 1067 -1353 -119 -4319 -800 -2687 900000 -970 900000 -2386 713 -75 900000 -1714 406 -384 -606 -1064 -2744 -1262 -2272 -434 -2544 -459 -1168 -954 -2389 -340 -469 1052 954 446 -3185 1615 -363 900000 395 1511 1661 3449 1617 2010 859 2108 -146 2219 1434 2573 2112 2974 1902 3439 2076 3523 145 2542 724 2326 1892 1691 -391 2498 1191 1712 1520 2188 1041 1052 1842 1133 1781 -12 -427 -1284 1065 -1783 -758 -1030 804 -704 903 -454 767 303 2391 452 2449 -474 413 -1059 1959 -3149 811 -1615 1835 -1461 1239 -741 -959 -5494 836 -2806 -403 -1861 -659 -3326 1012 -2394 510 -2657 1179 -1175 -552 -3266 -1034 -446 -501 2154 2465 4305 2254 1648 1731 -693 -267 1149 1722 2241 -361 -408 -499 917 -1422 1797 634 2226 535 -449 -3114 -3625 SS 20221006T113936.0Z 8314.485834 136 1 28.49 2 81.01 106.11 141.40 303.28 0.00 1 0.00 1 0 25 4.737e-01 2.688e-02 3.987e-01 1.924e-02 6.860137e-01 1.076060e-02 8.315440e-03 -6.000000e+00 2.764739e-01 226.64 -2.00 3.57 -2.00 321.65 0.00e+00 1.197197e-02 5.532541e-03 2.870299e-03 -6.000000e+00 1.259335e-02 283.31 -2.00 20.00 -2.00 321.12 0.00e+00 6.063 0.004 302.00 328.00 3 2.7005e+00 3.8542e-02 7.0949e-02 -6.0000e+00 6.8386e-01 6.2900e-01 4.9565e-02 3.7714e-02 -6.0000e+00 7.4199e-01 -8.5798e-01 4.1329e-02 2.2234e-02 -6.0000e+00 4.4284e-01 3.6468e-01 1.9592e-02 1.1631e-02 -6.0000e+00 1.8922e-01 3.9642e-05 -2.0329e-03 5.7813e-04 1.9456e-04 -6.0000e+00 1.3633e-02 -3.6462e-03 3.4784e-05 12 9 9 12 1 1 92.43 22.36 0.71 -0.00365 -0.01892 10 5 1 5 0 2574.230 26.41 20.00 22.36 22.08 19.7 994.25 900000 -61537 21863 -94925 -97221 -59379 -112189 -158031 -119917 6160 -35625 -164987 -66125 -424 -50450 -66897 37584 155660 -49441 108103 107588 -31721 -24220 -20775 -1293 900000 83694 -16197 -58079 900000 -6432 7520 175025 26776 102984 53081 19344 57941 -1770 146729 70224 54536 69433 97499 678 58057 59895 2721 38402 17888 9987 60243 40020 46851 29391 45316 21619 28451 -552 9101 24565 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