File name: Pandora184s1_CapeElizabethME_20221106_L2Fit_fout2c1d20211002p1-8.txt File generation date: 20260323T202452.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 184 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora184_OF_v5d20201127.txt Instrument calibration file used: Pandora184s1_CF_v1d20211002.txt Level 1 file used: Pandora184s1_CapeElizabethME_20221106_L1_smca1c1d20211002p1-8.txt.bz2 Full location name: CEPTL - Cape Elizabeth Two Lights (State Park) Maine Short location name: CapeElizabethME Country of location: United States Location latitude [deg]: 43.5610 Location longitude [deg]: -70.2073 Location altitude [m]: 24 Local noon date: 20221106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0031 305.1442 305.2853 305.4263 305.5673 305.7084 305.8494 305.9904 306.1314 306.2724 306.4133 306.5543 306.6952 306.8362 306.9771 307.1180 307.2589 307.3998 307.5407 307.6816 307.8224 307.9633 308.1041 308.2450 308.3858 308.5266 308.6674 308.8082 308.9490 309.0897 309.2305 309.3712 309.5120 309.6527 309.7934 309.9341 310.0748 310.2155 310.3561 310.4968 310.6375 310.7781 310.9187 311.0593 311.1999 311.3405 311.4811 311.6217 311.7623 311.9028 312.0433 312.1839 312.3244 312.4649 312.6054 312.7459 312.8864 313.0268 313.1673 313.3077 313.4482 313.5886 313.7290 313.8694 314.0098 314.1502 314.2905 314.4309 314.5712 314.7116 314.8519 314.9922 315.1325 315.2728 315.4131 315.5533 315.6936 315.8338 315.9741 316.1143 316.2545 316.3947 316.5349 316.6751 316.8152 316.9554 317.0955 317.2357 317.3758 317.5159 317.6560 317.7961 317.9362 318.0763 318.2163 318.3564 318.4964 318.6364 318.7764 318.9164 319.0564 319.1964 319.3364 319.4763 319.6163 319.7562 319.8962 320.0361 320.1760 320.3159 320.4557 320.5956 320.7355 320.8753 321.0151 321.1550 321.2948 321.4346 321.5744 321.7142 321.8539 321.9937 322.1334 322.2732 322.4129 322.5526 322.6923 322.8320 322.9717 323.1113 323.2510 323.3906 323.5303 323.6699 323.8095 323.9491 324.0887 324.2282 324.3678 324.5074 324.6469 324.7864 324.9260 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221106T120814.8Z 8345.505726 231 1 46.30 2 83.46 119.56 118.18 311.13 0.00 1 0.00 1 0 25 5.507e-01 2.676e-02 4.613e-01 2.259e-02 6.914075e-01 1.294722e-02 9.297765e-03 -6.000000e+00 3.218676e-01 223.51 -2.00 3.57 -2.00 321.92 0.00e+00 2.120744e-03 7.159965e-03 1.169624e-02 -6.000000e+00 1.554899e-02 279.42 -2.00 20.00 -2.00 321.44 0.00e+00 7.964 0.010 302.00 328.00 3 1.1549e+00 4.9036e-02 1.0674e-01 -6.0000e+00 7.9258e-01 5.6032e-01 6.7744e-02 9.0072e-02 -6.0000e+00 8.6528e-01 -6.9363e-01 6.3270e-02 4.2321e-02 -6.0000e+00 5.1269e-01 2.7296e-01 2.9152e-02 8.8318e-03 -6.0000e+00 2.2308e-01 3.3719e-05 1.5925e-04 7.2391e-04 2.4365e-04 -6.0000e+00 1.6288e-02 -3.6965e-04 -4.2296e-05 12 8 8 10 0 0 67.21 22.38 0.80 -0.00037 0.00083 36 10 1 5 0 1285.970 26.41 20.00 22.38 20.75 20.5 999.05 900000 900000 900000 900000 90888 -148166 900000 -231265 900000 -32921 -131201 46066 -144380 -101111 900000 900000 -43069 144139 58573 -33971 28441 110889 -27592 226249 -15883 -52399 900000 -96386 -1374 231719 -49634 -63853 -7129 -20261 -27043 7060 103099 56113 94549 9784 149566 -12248 22510 20847 28059 8539 54889 78235 18771 66667 24663 96580 -7386 55704 25321 52167 -5148 6518 1718 6703 32461 35614 5773 34172 2951 735 20566 16466 5520 -3393 27368 -8882 23 6505 7242 1957 19929 -6050 11531 -1937 2553 599 332 802 -1007 5096 708 12898 -2464 -4505 -2683 -1904 3079 -4386 376 -456 -4805 -931 -1425 730 209 -5541 -88 -6128 -621 -1973 -3221 -5561 -602 -26 1371 -1284 -510 -1182 -114 -2332 2090 2449 4065 1074 851 1824 1440 -1535 2392 2894 129 2542 972 839 515 -1495 -1471 -1194 -282 -206 339 251 2514 -444 -310 -876 -1378 900000 900000 900000 900000 1999 -3258 900000 -10595 900000 -724 -2885 1013 -4233 -2409 900000 900000 -947 3170 1288 -809 625 2439 -607 4975 -381 -1886 900000 -5203 -30 5096 -1885 -3319 -242 -851 -1189 212 2267 1234 2079 489 3289 -930 1260 1209 1515 563 2304 2659 1201 2799 1726 3669 -871 3786 2480 4067 -731 821 220 791 2985 3417 842 4236 537 137 3084 2633 1070 -821 5417 -2930 7 1745 1768 452 3550 -1397 2460 -558 831 229 142 365 -498 2532 388 6467 -1447 -2625 -1446 -954 1415 -2228 203 -288 -3699 -794 -1350 694 190 -4862 -67 -4865 -496 -1705 -2989 -5686 -645 -31 1818 -1884 -758 -1734 -158 -3185 2735 3333 5774 1644 1306 2687 2055 -2191 3172 3698 165 3298 1439 1416 968 -3089 -3221 -2780 -696 -538 906 683 6694 -1177 -774 -2070 -3161 SS 20221106T121844.2Z 8345.513012 234 1 2.02 2 81.82 121.50 119.49 313.56 0.00 1 0.00 1 0 17 4.225e-01 2.437e-02 3.976e-01 2.310e-02 5.909428e-01 1.301675e-02 7.563228e-03 -6.000000e+00 2.524152e-01 223.51 -2.00 3.57 -2.00 321.29 0.00e+00 1.224124e-02 6.337555e-03 4.117782e-03 -6.000000e+00 1.225973e-02 279.42 -2.00 20.00 -2.00 320.77 0.00e+00 6.591 0.005 302.00 328.00 3 1.0347e+00 4.4694e-02 7.3333e-02 -6.0000e+00 6.2848e-01 2.0302e-01 5.9664e-02 3.3981e-02 -6.0000e+00 6.9025e-01 -2.4713e-01 5.7588e-02 2.5883e-02 -6.0000e+00 4.0484e-01 9.0099e-02 2.7332e-02 1.4866e-02 -6.0000e+00 1.6911e-01 1.5686e-04 -8.1625e-04 7.4173e-04 2.2176e-04 -6.0000e+00 1.2756e-02 -1.8585e-03 -6.0286e-06 12 9 9 12 1 1 999.00 22.39 0.77 -0.00186 -0.00799 2 21 1 5 0 615.060 26.51 20.00 22.39 21.56 20.5 1004.17 900000 44977 -151581 -80274 900000 -135758 900000 -230256 900000 900000 -99062 -40237 900000 900000 900000 900000 900000 900000 24179 900000 -58230 102109 50469 103939 -100739 110063 -61503 900000 -34690 -28128 -19985 -20031 -60626 900000 -24336 91115 -39644 123613 2275 72892 -24460 17464 -21092 10587 19736 42693 18311 36349 20772 23668 5888 9039 3447 29686 2437 18252 7397 26446 13929 17470 11976 10273 20542 5395 -6348 21742 17127 -2601 18992 6247 8968 1695 19501 -8586 3018 -4322 -13160 -7399 6174 887 -9621 -2698 -524 -10671 -5318 -1875 1915 -2769 4767 -3492 -3150 -1555 271 -1217 -2687 -2053 1444 -1399 2872 -2208 -1446 -1677 5017 -282 2696 -330 545 433 -1755 599 2360 2464 300 -156 -323 -1265 -68 -31 -579 1065 1986 -470 132 -686 787 1248 -2169 1241 117 -687 -1571 -206 -410 499 -587 125 -376 1182 -428 1358 -112 -604 -764 900000 1010 -3405 -1803 900000 -3050 900000 -7523 900000 900000 -2225 -904 900000 900000 900000 900000 900000 900000 543 900000 -1784 2294 1134 2335 -4937 2472 -2135 900000 -921 -747 -628 -765 -4086 900000 -1257 2047 -2404 2777 123 2292 -2308 1177 -2227 856 1507 2685 1522 2613 1820 2127 688 1137 503 3601 411 2706 1246 3683 2159 2590 1937 1846 3784 1309 -1868 4835 3886 -725 4565 1937 3022 651 6308 -3530 1024 -1427 -4375 -2294 1817 323 -4581 -1376 -289 -6976 -3512 -1280 1333 -2102 3395 -2643 -2243 -1017 165 -755 -1847 -1614 1159 -1328 2891 -2403 -1494 -1586 4463 -260 2323 -313 543 463 -2085 774 3321 3699 466 -236 -466 -1759 -93 -44 -882 1681 3138 -744 200 -1020 1110 1692 -2950 1671 176 -1174 -2737 -379 -795 1014 -1290 288 -901 2842 -1052 3198 -255 -1307 -1599 SS 20221106T123449.5Z 8345.524184 242 1 44.51 2 79.38 124.53 121.40 317.44 0.00 1 0.00 1 0 17 2.015e-01 7.067e-03 6.826e-02 2.178e-03 4.939167e-01 1.139810e-03 5.942731e-03 -6.000000e+00 1.157524e-01 223.51 -2.00 3.57 -2.00 320.79 0.00e+00 2.783930e-03 4.773538e-04 2.440696e-03 -6.000000e+00 5.117827e-03 279.42 -2.00 20.00 -2.00 320.25 0.00e+00 5.218 0.003 302.00 328.00 3 6.3084e-01 3.6168e-03 5.8592e-02 -6.0000e+00 2.8501e-01 3.6509e-02 4.6847e-03 2.9269e-02 -6.0000e+00 3.1003e-01 -4.5314e-02 4.5297e-03 1.6165e-02 -6.0000e+00 1.8505e-01 8.8329e-03 2.2382e-03 5.4316e-03 -6.0000e+00 7.8710e-02 9.9667e-04 -2.9862e-04 6.7515e-05 8.5089e-05 -6.0000e+00 5.7232e-03 -1.6557e-03 -7.6459e-06 11 8 0 10 0 0 99.85 22.41 0.36 -0.00166 -0.00390 293 82 1 5 0 151.860 26.51 20.00 22.41 22.40 20.6 1010.60 -86468 -38332 -81942 -56010 -62970 -60752 -77839 -58210 -68281 -50053 -58628 -33811 -56963 -21936 -28434 -19950 -21536 -14750 -8285 -5309 -11538 -4475 -7682 -11250 -9914 -14397 -8878 -16863 -8711 -12519 -5556 -7946 -3703 -7156 -4964 -11719 -4742 -9337 -2906 -2752 -694 -919 2138 -279 3595 1292 4036 967 2041 -48 3908 1066 2884 2538 1856 1901 2069 -221 1666 -1660 46 752 3487 3465 2462 546 -107 -253 422 1890 1154 1761 755 904 -412 -454 -2438 -2531 -3381 -1015 -1514 -878 -1628 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